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New fillers development for highly thermo-conductive insulating polymeric composites

Research Project

Project/Area Number 21760536
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

ZHI Chunyi  National Institute for Materials Science, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (50469764)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
KeywordsBNナノ材料 / 高熱伝導体 / 複合材料 / BN nanotubes / Surface modification / Thermo-conductive composites / 窒化ホウ素ナノチューブ / 高い熱伝導率 / 絶縁性材料 / 表面機能化
Research Abstract

1. An general method was developed to chemically activate BN nanotubes. The activated BN nantubes can be further modified based on hydroxyl group chemistry.
2. Various highly thermo-conductive insulating polymeric composites based on BN nanotubes were fabricated. The matrixes were epoxy, polystyrene, PMMA etc. A method was developed to embed high fraction of BN nanotubes in matrix. By this technique, more than 30 wt.% BN nanotubes can be embedded, and the thermal conductivity of matrixes can be improved up to 21-fold.
3. As fundamental research, for the first time, the density and specific heat capacity of BN nanotubes were measured, which is useful for prediction of properties of BN nanotube composites.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (17 results)

All 2011 2010 2009

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Specific heat capacity and density of multi-walled boron nitride nanotubes by chemical vapor deposition2011

    • Author(s)
      C.Y.Zhi, Y.Bando, C.C.Tang, D.Golberg
    • Journal Title

      Solid State Communications 151

      Pages: 183-183

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric and thermal properties of epoxy/boron nitride nanotube composites2010

    • Author(s)
      C.Y.Zhi, Y.Bando, T.Terao, C.C.Tang, D.Golberg
    • Journal Title

      Pure and Applied Chemistry 82

      Pages: 2175-2175

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Alignment of boron nitride nanotubes in polymeric composite films for thermal conductivity improvement2010

    • Author(s)
      T.Terao, C.Y.Zhi, Y.Bando, M.Mitome, C.C.Tang, D.Golberg
    • Journal Title

      Journal of Physical Chemistry C 114

      Pages: 4340-4340

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric and thermal properties of epoxy/boron nitride nanotube composites2010

    • Author(s)
      C.Y.Zhi, Y.Bando, T.Terao, C.Tang, D.Golberg
    • Journal Title

      Pure Appl.Chem.

      Volume: 82 Pages: 2175-2183

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alignment of BN nanotubes in polymeric composite films for thermal conductivity improvement2010

    • Author(s)
      T.Terao, C.Y.Zhi, Y.Bando, M.Mitome, C.C.Tang, D.Golberg
    • Journal Title

      J.Phys.Chem.C

      Volume: 114 Pages: 4340-4344

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Specific heat capacity and density of multi-walled boron nitride nanotubes by chemical vapor deposition2010

    • Author(s)
      C.Y.Zhi, Y.Bando, C.Tang, D.Golberg
    • Journal Title

      SOLID STATE COMMUNICATIONS

      Volume: 151 Pages: 183-186

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Towards thermoconductive, electrically Insulating polymeric composites with boron nitride nanotubes as fillers2009

    • Author(s)
      C.Y.Zhi, Y.Bando, T.Terao, C.C.Tang, H.Kuwahara, D.Golberg
    • Journal Title

      Adv.Mater. 19

      Pages: 1857-1857

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Large-scale fabrication of boron nitride nanosheets and their utilization in polymeric composites with improved thermal and mechanical properties.2009

    • Author(s)
      C.Y.Zhi, Y.Bando, C.C.Tang, H.Kuwahara, D.Golberg
    • Journal Title

      Advanced Materials 21

      Pages: 2889-2889

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemically activated BN nanotubes Chem.2009

    • Author(s)
      C.Y.Zhi, Y.Bando, T.Terao, C.C.Tang, H.Kuwahara, D.Golberg
    • Journal Title

      Asian J. 4

      Pages: 1536-1536

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Large-Scale Fabrication of Boron Nitride Nanosheets and Their Utilization in Polymeric Composites with Improved Thermal and Mechanical Properties2009

    • Author(s)
      Chunyi Zhi, Yoshio Bando, Chengchun Tang, Hiroaki Kuwahara, Dimitri Golberg
    • Journal Title

      Advanced Materials 21

      Pages: 2889-2893

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Towards Thermoconductive, Electrically Insulating Polymeric Composites with Boron Nitride Nanotubes as Fillers2009

    • Author(s)
      Chunyi Zhi, Yoshio Bando, Takeshi Terao, Chengchun Tang, Hiroaki Kuwahara, Dimitri Golberg
    • Journal Title

      Advanced Functional Materials 19

      Pages: 1857-1862

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemically Activated Boron Nitride Nanotubes2009

    • Author(s)
      Chunyi Zhi, Yoshio Bando, Takeshi Terao, Chengchun Tang, Hiroaki Kuwahara, Dimitri Golberg
    • Journal Title

      Chemistry-An Asian Journal 4

      Pages: 1536-1540

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Novel Boron Nitride nanofillers for polymeric composites2010

    • Author(s)
      C.Y.Zhi, Y.Bando, D.Golberg
    • Organizer
      X International Conference on Nanostructured Materials
    • Place of Presentation
      Rome, Italy.
    • Related Report
      2010 Final Research Report
  • [Presentation] Novel Boron Nitride nanofillers for polymeric composites2010

    • Author(s)
      C.Y.Zhi, Y.Bando, D.Golberg
    • Organizer
      X International Conference on Nanostructured Materials
    • Place of Presentation
      Rome, Italy
    • Related Report
      2010 Annual Research Report
  • [Presentation] A Universal Method for Obtaining Chemically Activated BN Nanotubes though Boron Site Chemistry2009

    • Author(s)
      Chunyi Zhi
    • Organizer
      Villa Conference on Interactions Among Nanostructures
    • Place of Presentation
      Ritz Carlton-St.Thomas, US Virgin Islands
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] A Universal Method for Obtaining Chemically Activated BN Nanotubes though Boron Site Chemistry2009

    • Author(s)
      C.Y.Zhi, Y.Bando, D.Golberg
    • Organizer
      Villa Conference on Interactions Among Nanostructures
    • Place of Presentation
      Ritz Carlton-St.Thomas, US Virgin Islands.
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 超薄窒化ホウ素ナノシート及びその製造方法ならびに該シートを含有する光素材2009

    • Inventor(s)
      Zhi Chunyi 板東義雄 Tang Chengchun, Dmitri Golberg, 桑原広明
    • Industrial Property Rights Holder
      独立行政法人物質・材料研究機構
    • Industrial Property Number
      2009-234651
    • Filing Date
      2009-10-08
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2021-04-07  

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