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Formation mechanism of nanoporous structures through the crystallization of amorphous oxides

Research Project

Project/Area Number 21760556
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionOsaka University

Principal Investigator

NAKAMURA Ryusuke  Osaka University, 産業科学研究所, 助教 (70396513)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsアモルファス / 酸化物 / ナノポーラス / TEM / 動径分布関数 / HAADF-STEM / 薄膜
Research Abstract

A high density of nanovoids between 2 and 13 nm in size were produced during the crystallization process as amorphous Al_2O_3 and WO_3 20~30 % lower in density than their crystalline phases were annealed. By contrast, no formation or growth of nanovoids was observed during the crystallization of amorphous TiO_2 and Cr_2O_3, which have a density 2% lower than its crystalline phase. These results suggest that large difference in density between the amorphous and crystalline oxides can be utilized to produce nanoporous structures.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (9 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (7 results)

  • [Journal Article] Nanovoid Formation through the Annealing of Amorphous Al_2O_3 and WO_3 Films2011

    • Author(s)
      R.Nakamura, T.Shudo, A.Hirata, M.Ishimaru, H.Nakajima
    • Journal Title

      Scripta Materialia 64

      Pages: 197-200

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanovoid Formation through the Annealing of Amorphous Al_2O_3 and WO_3 Films2011

    • Author(s)
      R.Nakamura, T.Shudo, A.Hirata, M.Ishimaru, H.Nakajima
    • Journal Title

      Scripta Materialia

      Volume: 64 Pages: 197-200

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] TEM analysis on nanovoid formation in annealed amorphous oxides2011

    • Author(s)
      Ryusuke Nakamura
    • Organizer
      The 12th the International Symposium on Eco-materials Processing and Design (ISEPD2011)
    • Place of Presentation
      Chiang Mai (Thailand)
    • Year and Date
      2011-01-09
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] アモルファス酸化タングステン薄膜の結晶化に伴うナノポーラス化2010

    • Author(s)
      酒道武浩
    • Organizer
      日本金属学会2010年秋期講演大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Final Research Report
  • [Presentation] Wを含むアモルファスアルミナ薄膜におけるナノボイドの形成挙動2010

    • Author(s)
      仲村龍介
    • Organizer
      日本金属学会2010年秋期講演大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Final Research Report
  • [Presentation] Wを含むアモルファスアルミナ薄膜におけるナノボイドの形成挙動2010

    • Author(s)
      仲村龍介
    • Organizer
      日本金属学会2010年秋期講演大会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] アモルファス酸化タングステン薄膜の結晶化に伴うナノポーラス化2010

    • Author(s)
      酒道武浩, 仲村龍介
    • Organizer
      日本金属学会2010年秋期講演大会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] アモルファス酸化物薄膜のアニールに伴うナノボイド形成2010

    • Author(s)
      酒道武浩
    • Organizer
      日本金属学会2010年春期講演大会
    • Place of Presentation
      筑波大学(茨城県)
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] アモルファス酸化物の構造緩和に伴うナノボイドの形成2009

    • Author(s)
      仲村龍介
    • Organizer
      日本金属学会2009年秋期講演大会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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