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Rapid mass transfer caused by capillary phase separation and itsmodeling

Research Project

Project/Area Number 21760615
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionCentral Research Institute of Electric Power Industry

Principal Investigator

KANDA Hideki  Central Research Institute of Electric Power Industry, エネルギー技術研究所, 主任研究員 (90371624)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords吸着 / 相転移 / 化学工学 / 反応・分離工学 / メゾスコピック系 / 表面・界面物性 / シミュレーション工学
Research Abstract

Nanoscopic interfacial equilibrium condition of binary Lennard-Jones liquid phases, capillary phase separation of binary Lennard-Jones liquids in nanopores, and mass transfer phenomenon caused by capillary phase separation in nanopores are examined. The larger the value of T^* or ε(AB), the larger is Tolman's length, the smaller is the interfacial tension, and the larger is the equilibrium bulk concentration. Moreover, in nanopores, the relation between the bulk concentration and rate of mass transfer was clarified. Curvature radius of the meniscus is smaller, the inner pressure of condensed liquid in pore is lower by stronger Laplace effect. Therefore, amplified pressure difference should be occurred in condensed phase nestled between the two different bulk conditions.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (14 results)

All 2010 2009

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (10 results)

  • [Journal Article] 分子シミュレーションを活用したナノ細孔内三態相平衡・液液相平衡の熱力学モデルの構築2010

    • Author(s)
      神田英輝
    • Journal Title

      日本吸着学会誌 24(1)

      Pages: 11-17

    • Related Report
      2010 Final Research Report
  • [Journal Article] 分子シミュレーションを活用したナノ細孔内三態相平衡・液液相平衡の熱力学モデルの構築2010

    • Author(s)
      神田英輝
    • Journal Title

      Adsorption News(日本吸着学会誌)

      Volume: 24(1) Pages: 11-17

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Triple point of Lennard-Jones fluid in nanopores with zero excess pore wall energy2009

    • Author(s)
      Hideki Kanda, Minoru Miyahara
    • Journal Title

      Adsorption Science and Technology 27

      Pages: 735-743

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Triple point of Lennard-Jones fluid in nanopores with zero excess pore wall energy2009

    • Author(s)
      神田英輝、宮原稔
    • Journal Title

      Adsorption Science & Technology 27

      Pages: 735-743

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Gibbs-Tolman-Koenig-Buff Kelvin凝縮モデルの提案とシクロヘキサン吸着等温線によるシリカ系ナノ細孔径評価2010

    • Author(s)
      神田英輝
    • Organizer
      第24回日本吸着学会研究発表会
    • Place of Presentation
      石巻専修大学
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Two Surfaces of Tension on Both Sides of an Equimolar Dividing Surface of Liquid-liquid Interface in Symmetric Binary Lennard-Jones System2010

    • Author(s)
      Hideki Kanda
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2010-09-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Two Surfaces of Tension on Both Sides of an Equimolar Dividing Surface of Liquid-liquid Interface in Symmetric Binary Lennard-Jones System2010

    • Author(s)
      Hideki Kanda
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science (NCSS2010)
    • Place of Presentation
      幕張メッセ
    • Year and Date
      2010-09-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液液相界面の分割面の両脇に存在する二つの張力面2010

    • Author(s)
      神田英輝
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2010-09-08
    • Related Report
      2010 Final Research Report
  • [Presentation] 液液相界面の分割面の両脇に存在する二つの張力面2010

    • Author(s)
      神田英輝
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2010-09-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Two Surfaces of Tension on Both Sides of an Equimolar Dividing Surface of Partially Miscible Lennard-Jones Mixture2010

    • Author(s)
      Hideki Kanda
    • Organizer
      The 10th International Conference on Fundamentals of Adsorption
    • Place of Presentation
      淡路夢舞台国際会議場
    • Year and Date
      2010-05-25
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 分子シミュレーションを活用したナノ細孔内三態相平衡・液液相平衡の熱力学モデルの構築(招待講演)2009

    • Author(s)
      神田英輝
    • Organizer
      第23回日本吸着学会研究発表会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2009-11-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 分子シミュレーションを活用したナノ細孔内三態相平衡・液液相平衡の熱力学モデルの構築2009

    • Author(s)
      神田英輝
    • Organizer
      第23回日本吸着学会研究発表会
    • Place of Presentation
      豊橋技術科学大学(愛知県)
    • Year and Date
      2009-11-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] ナノ細孔内における液液相平衡挙動のモンテカルロシミュレーションと熱力学モデル化2009

    • Author(s)
      神田英輝、牧野尚夫
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] ナノ細孔内における液液相平衡挙動のモンテカルロシミュレーションと熱力学モデル化2009

    • Author(s)
      神田英輝、牧野尚夫
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(広島県)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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