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Synthesis and Structure Control of Surface Modified Nanoparticles by Subcritical CO_2-Expanded Solutions

Research Project

Project/Area Number 21760621
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionFukuoka University

Principal Investigator

MATSUYAMA Kiyoshi  Fukuoka University, 工学部, 助教 (40299540)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsガス膨張液体 / 超臨界流体 / 二酸化炭素 / ナノ粒子 / 表面改質 / 超音波 / ナノ材料 / 亜臨界流体 / 微細構造 / 複合材料
Research Abstract

We report the surface modification of micron and nano sized particles by the pressure-induced phase separation (PIPS) of CO_2-expanded solutions. We developed an ultrasonic irradiation apparatus in high-pressure fluids in order to accelerate the dispersity of surface modified particles. Shock waves generated by collapsing cavitation bubbles induced with ultrasonic irradiation accelerated the deagglomeration and dispersion of particles. The surface modified particles were applied as the hollow microspheres, porous membrane of metal oxides, and metal oxide nanoparticles-polymer composite film.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2011 2010 2009

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (10 results) Book (2 results)

  • [Journal Article] Formation of Porous Glass via Core/Shell-Structured Poly(methylmethacrylate)/Powder Glass Prepared by Ultrasonic Irradiation in Liquid CO_22011

    • Author(s)
      K.Matsuyama, K.Mishima, T.Kato, K.Ohara
    • Journal Title

      J.Supercritical Fluids

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Porous Glass via Core/Shell-Structured Poly(methyl methacrylate)/Powder Glass Prepared by Ultrasonic Irradiation in Liquid CO_22010

    • Author(s)
      K.Matsuyama, K.Mishima T.Kato, K.Ohara
    • Journal Title

      J.Supercritical Fluids 57

      Pages: 198-206

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Hollow ZnO Microspheres Using Poly(methyl methacrylate) as a Template with Supercritical CO_2-Ethanol Solution2010

    • Author(s)
      K.Matsuyama, K.Mishima, T.Kato, K.Ohara
    • Journal Title

      Ind.Eng.Chem.Res. 49

      Pages: 8510-8517

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Particle Coating of Talc with TiO_2 Nanoparticles Using Ultrasonic Irradiation in Liquid CO_22010

    • Author(s)
      K.Matsuyama, K.Mishima
    • Journal Title

      Ind.Eng.Chem.Res. 49

      Pages: 1289-1296

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 高圧二酸化炭素を用いたマイクロ・ナノ粒子の表面改質2010

    • Author(s)
      松山清, 三島健司
    • Journal Title

      高圧力の科学と技術 20

      Pages: 50-56

    • NAID

      10026122194

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure Phase Behavior and FT-IR Study of Poly(methyl methacrylate)+Ethanol Systems with Addition of Supercritical CO_22010

    • Author(s)
      K Matsuyama, K Mishima
    • Journal Title

      J.Physics : Conference Series 215

      Pages: 12086-12086

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Phase Behavior and FT-IR Study of Poly(methyl methacrylate) + Ethanol Systems with Addition of Supercritical CO_22010

    • Author(s)
      K.Matsuyama, K.Mishima
    • Journal Title

      J.Physics : Conference Series

      Volume: 215

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Hollow ZnO Microspheres Using Poly(methylmethacrylate) as Template with Supercritical CO_2-Ethanol Solution2010

    • Author(s)
      K.Matsuyama, K.Mishima, T.Kato, K.Ohara
    • Journal Title

      Ind.Eng.Chem.Res.

      Volume: 49 Pages: 8510-8517

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Particle Coating of Talc with TiO_2 Nanoparticles Using Ultrasonic Irradiation in Liquid CO_22010

    • Author(s)
      松山清, 三島健司
    • Journal Title

      Ind.Eng.Chem.Res. Vol.49

      Pages: 1289-1296

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高圧二酸化炭素を用いたマイクロ・ナノ粒子の表面改質2010

    • Author(s)
      松山清, 三島健司
    • Journal Title

      高圧力の科学と技術 Vol.20

      Pages: 50-56

    • NAID

      10026122194

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fourier Transform Infrared Study of the Dissolution Mechanism of Poly(methyl methacrylate) in CO_2-Expanded Ethanol2009

    • Author(s)
      K.Matsuyama, K.Mishima
    • Journal Title

      ChemPhysChem 10

      Pages: 503-506

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Extraction of Silymarins from Milk Thistle Seeds Using Supercritical Carbon Dioxide with Methanol2009

    • Author(s)
      M.Honjo, K.Mishima, K.Matsuyama, H.Sekiguchi, S.Ando, K.Irie, M.Fujiwara
    • Journal Title

      Solv.Extr.Res.Dev.Japan 16

      Pages: 111-120

    • NAID

      40016726030

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Poly(methyl methacrylate)-TiO_2 Nanoparticle Composites by Pseudo-dispersion Polymerization of Methyl Methacrylate in Supercritical CO_22009

    • Author(s)
      K.Matsuyama, K.Mishima
    • Journal Title

      J.Supercritical Fluids 49

      Pages: 256-264

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Poly(methyl methacrylate)-TiO_2 Nanoparticle Composites by Pseudo-dispersion Polymerization of Methyl Methacrylate in Supercritical CO_22009

    • Author(s)
      松山清, 三島健司
    • Journal Title

      J.Supercritical Fluids Vol.49

      Pages: 256-264

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高圧CO_2中で音波キャビテーションを利用した粒子の複合化と多孔質材料の合成2011

    • Author(s)
      松山清, 三島健司
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-22
    • Related Report
      2010 Final Research Report
  • [Presentation] 亜臨界二酸化炭素中での超音波を利用した微粒子の複合化2010

    • Author(s)
      松山清, 三島健司
    • Organizer
      第51回高圧討論会
    • Place of Presentation
      仙台
    • Year and Date
      2010-10-21
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素を用いたZnO中空微粒の作製2010

    • Author(s)
      松山清, 三島健司
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      京都
    • Year and Date
      2010-09-06
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素を用いたZnO中空微粒子の作製2010

    • Author(s)
      松山清, 三島健司
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液体二酸化炭素中での超音波キャビテーションを利用した微粒子の複合化2010

    • Author(s)
      松山清, 三島健司
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島
    • Year and Date
      2010-03-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Binary Solid-Liquid-Gas Equilibrium of α-Lipoic Acid/CO_2 and Hydrogenated Colza Oil/CO_2 Systems2009

    • Author(s)
      M.Honjo, K.Mishima, K.Mastuyama, K.Irie, K.Mishima, M.Fujiwara
    • Organizer
      5th International Symposium of Molecular Thermodynamics and Molecular Simulation
    • Place of Presentation
      金沢
    • Year and Date
      2009-10-03
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界CO_2中での酸化チタン表面へのメタクリル酸メチルのグラフト重合2009

    • Author(s)
      松山清, 三島健司
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      東広島
    • Year and Date
      2009-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] High-Pressure Phase Behavior and FT-IR study of Poly(methyl methacrylate)+Ethanol Systems with Addition of Supercritical CO_22009

    • Author(s)
      K.Matsuyama, K.Mishima
    • Organizer
      5th International Conference on High Pressure Science and Technology
    • Place of Presentation
      東京国際交流会館(東京都)
    • Year and Date
      2009-08-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formation of Fluoropolymer/CaCO_3 Hybrid Core-Shell Microcapsules by Rapid Expansion of Supercritical Solution (RESS)2009

    • Author(s)
      K.Mishima, K.Matsuyama
    • Organizer
      5th International Conference on High Pressure Science and Technology
    • Place of Presentation
      東京
    • Year and Date
      2009-07-27
    • Related Report
      2010 Final Research Report
  • [Presentation] High-Pressure Phase Behavior and FT-IR study of Poly(methyl methacrylate)+Ethanol Systems with Addition of Supercritical CO_22009

    • Author(s)
      K.Matsuyama, K.Mishima
    • Organizer
      5th International Conference on High Pressure Science and Technology
    • Place of Presentation
      東京
    • Year and Date
      2009-07-27
    • Related Report
      2010 Final Research Report
  • [Book] 若手研究者の大きな可能性を秘めた研究開発2010

    • Author(s)
      吉田昌弘, 松山清, 他29名
    • Publisher
      化学工学会九州支部若手ケミカルエンジニア連絡
    • Related Report
      2010 Final Research Report
  • [Book] 若手研究者の大きな可能性を秘めた研究開発2009

    • Author(s)
      吉田昌弘、松山清, 他29名
    • Total Pages
      116
    • Publisher
      化学工学会九州支部若手ケミカルエンジニア連絡会
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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