| Project/Area Number |
21760625
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
IMAI Hiroyuki Tokyo Institute of Technology, 資源化学研究所, 助教 (70514610)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 酸触媒反応 / 酸化触媒反応 / ゼオライト / 層問拡張 / 層問機能化 / 触媒・化学プロセス / 層間拡張 / 層間機能化 / 層状前駆体 / シラン化合物 / ゼオライト層状前駆体 / 触媒活性点の層間導入 / 層間距離自在制御 |
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| Research Abstract |
The purpose of this study was the synthesis of novel structured zeolite by inserting various types of metal-containing organic compounds into the interlayer of zeolitic lamellar materials and the functionalization of the zeolites. The pore size (distance between interlayers) and hydrophilicity of FER-type zeolite, which is one of the layered zeolitic materials, was successfully controlled by inserting various types of Si-containing compounds as a pillar regent into the interlayer of the zeolitic lamellar precursor on the basis of the number of atoms. MWW-type zeolite, which is another layered zeolitic material, was successfully interlayer-expanded by inserting metal-containing compounds (Sn-compound etc) into the interlayer. MWW-type zeolite with the novel structure showed specific catalytic properties; substrates were able to react in the confined space surrounded by the layers to turn to products with specific sizes.
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