Synthesis of mufti-functionaIized layered zeoIite by modification of interlayer of zeolitic lamellar precursor and its catalytic application

• Project/Area Number: 21760625
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Catalyst/Resource chemical process
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: IMAI Hiroyuki Tokyo Institute of Technology, 資源化学研究所, 助教 (70514610)
• Project Period (FY): 2009 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: 酸触媒反応 / 酸化触媒反応 / ゼオライト / 層問拡張 / 層問機能化 / 触媒・化学プロセス / 層間拡張 / 層間機能化 / 層状前駆体 / シラン化合物 / ゼオライト層状前駆体 / 触媒活性点の層間導入 / 層間距離自在制御

Research Abstract

The purpose of this study was the synthesis of novel structured zeolite by inserting various types of metal-containing organic compounds into the interlayer of zeolitic lamellar materials and the functionalization of the zeolites. The pore size (distance between interlayers) and hydrophilicity of FER-type zeolite, which is one of the layered zeolitic materials, was successfully controlled by inserting various types of Si-containing compounds as a pillar regent into the interlayer of the zeolitic lamellar precursor on the basis of the number of atoms. MWW-type zeolite, which is another layered zeolitic material, was successfully interlayer-expanded by inserting metal-containing compounds (Sn-compound etc) into the interlayer. MWW-type zeolite with the novel structure showed specific catalytic properties; substrates were able to react in the confined space surrounded by the layers to turn to products with specific sizes.

Research Products

• [Journal Article] Enhancement of catalytic properties of interlayer-expanded zeolite Al-MWW via the control of the interlayer silylation conditions (2011)
  • Author(s): Satoshi Inagaki
  • Journal Title: Microporous Mesoporous Materials Volume: (In press)
  • Peer Reviewed
• [Journal Article] Enhancement of catalytic properties of interlayer-expanded zeolite Al-MWW via the control of the interlayer silylation conditions
  • Author(s): Satoshi Inagaki, Hiroyuki Imai, Sho Tsujiuchi, Hikaru Yakushiji, Toshiyuki Yokoi, Takashi Tatsumi
  • Journal Title: in press
• [Presentation] Interlayer expansion of Ti-MWW-influence of the precursor synthesis method on the structural characteristics and catalytic performance (2010)
  • Author(s): Filipa Madeira
  • Organizer: PACIFICHEM2010
  • Place of Presentation: Honolulu, Hawaii
  • Year and Date: 2010-12-17
• [Presentation] Effect of the solvent at the intercalation-silylation treatment on the structural and catalytic properties of the resultant IEZ-MWW catalysts (2010)
  • Author(s): Shun Mizuno
  • Organizer: PACIFICHEM2010
  • Place of Presentation: Honolulu, Hawaii
  • Year and Date: 2010-12-17
• [Presentation] アルキルシラン化合物を用いたFER型ゼオライトの層間拡張処理の検討 (2010)
  • Author(s): 今井裕之, Jacques Plevert, 横井俊之, 野村淳子, 辰巳敬,
  • Organizer: 第26回ゼオライト研究発表会
  • Place of Presentation: タワーホール船堀(東京)
  • Year and Date: 2010-12-03
• [Presentation] アルキルシラン化合物を用いたFER型ゼオライトの層間拡張処理の検討 (2010)
  • Author(s): 今井裕之
  • Organizer: 第26回ゼオライト研究発表会
  • Place of Presentation: タワーホール船堀,東京
  • Year and Date: 2010-12-03
• [Presentation] 層間拡張型MWW型ゼオライトの調製手法の改良 (2010)
  • Author(s): 水野駿
  • Organizer: 第26回ゼオライト研究発表会
  • Place of Presentation: タワーホール船堀,東京
  • Year and Date: 2010-12-03
• [Presentation] スズ含有MWW型ゼオライトの合成と触媒活性評価 (2010)
  • Author(s): 今井裕之
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨大学,甲府
  • Year and Date: 2010-09-17
• [Presentation] Ti-IEZ-MWWの調製と触媒特性 (2010)
  • Author(s): 吉岡真人
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨大学,甲府
  • Year and Date: 2010-09-17
• [Presentation] Catalytic performance of modified Ti-MWW zeolites for cyclohexene epoxidation (2010)
  • Author(s): Filipa Madeira
  • Organizer: Pre-conference of TOCAT6/APCAT5
  • Place of Presentation: 東京大学,東京
  • Year and Date: 2010-07-16
• [Presentation] Hydrophobicity enhancement and oxidation activity improvement of Ti-MWW (2010)
  • Author(s): H.Zhao
  • Organizer: Pre-conference of TOCAT6/APCAT5
  • Place of Presentation: 東京大学,東京
  • Year and Date: 2010-07-16
• [Presentation] Interlayer Expansion of Ferrierite Lamellar Precursor with Alkylsilicon Compounds (2010)
  • Author(s): Hiroyuki Imai, Jacques Plevert, Toshiyuki Yokoi, Junko N.Kondo, Takashi Tatsumi
  • Organizer: 16th International Zeolite Conference joint with the 7th International Mesostructured Materials Symposium
  • Place of Presentation: Sorrento(Italy)
  • Year and Date: 2010-07-07
• [Presentation] Interlayer Expansion of Ferrierite Lamellar Precursor with Alkylsilicon Compounds (2010)
  • Author(s): Hiroyuki Imai
  • Organizer: 16^<th> International Zeolite Conference joint with the 7^<th> International Mesostructured Materials Symposium
  • Place of Presentation: Sorrento, Italy
  • Year and Date: 2010-07-07
• [Presentation] Zr含有MWW型ゼオライトの合成 (2010)
  • Author(s): 水野駿
  • Organizer: 第15回JPIJSポスターセッション
  • Place of Presentation: タワーホール船堀,東京
  • Year and Date: 2010-05-20
• [Presentation] Al含有層間拡張型MWWゼオライトの合成条件の検討 (2010)
  • Author(s): 水野駿, 薬師寺光, 今井裕之, 横井俊之, 辰巳敬
  • Organizer: 日本化学会第90回春季年会
  • Place of Presentation: 近畿大学(大阪)
  • Year and Date: 2010-03-27
• [Presentation] Sn化合物をピラーに用いた層間拡張型ゼオライトの合成 (2010)
  • Author(s): 薬師寺光, 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第105回触媒討論会
  • Place of Presentation: 京都テルサ(京都)
  • Year and Date: 2010-03-25
• [Presentation] Sn含有有機化合物をピラー剤に用いた層間拡張型ゼオライトの合成 (2009)
  • Author(s): 薬師寺光, 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第25回ゼオライト研究発表会
  • Place of Presentation: 西日本総合展示場(小倉)
  • Year and Date: 2009-11-26
• [Presentation] Synthesis of interlayer-expanded Ti-containing MWW-type zeolite by postsynthesis method (2009)
  • Author(s): 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第12回日韓触媒シンポジウム
  • Place of Presentation: 秋田キャッスルホテル(秋田)
  • Year and Date: 2009-10-15
• [Presentation] 層間拡張MWW型ゼオライトへのポスト処理によるTiの導入と触媒特性 (2009)
  • Author(s): 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学(宮崎)
  • Year and Date: 2009-09-29
• [Presentation] ポスト法によるAl含有層間拡張型MWW型ゼオライトの調製とその触媒活性評価 (2009)
  • Author(s): 薬師寺光, 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学(宮崎)
  • Year and Date: 2009-09-29
• [Presentation] Interlayer silylation of MWW-type zeolite in acidic aqueous solution (2009)
  • Author(s): 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: ZMPC2009ポストシンポジウム
  • Place of Presentation: 洞爺湖万世閣(北海道)
  • Year and Date: 2009-08-08
• [Presentation] Synthesis of MWW-type zeolite containing aluminum in the absence of alkali cations (2009)
  • Author(s): Hiroyuki Imai, Toshiyuki Yokoi, Junko N.Kondo, Takashi Tatsumi
  • Organizer: ZMPC-2009
  • Place of Presentation: 早稲田大学(東京)
  • Year and Date: 2009-08-04
• [Presentation] MWW層状前駆体への有機基修飾 (2009)
  • Author(s): 薬師寺光, 今井裕之, 横井俊之, 野村淳子, 辰巳敬
  • Organizer: 第14回JPIJSポスターセッション
  • Place of Presentation: タワーホール船堀(東京)
  • Year and Date: 2009-05-20
• [Remarks] ホームページ等