Development of multifunctionalized solid acid catalysts for novel and efficient organic reactions
| Project/Area Number |
21760626
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
MOTOKURA Ken Tokyo Institute of Technology, 大学院・総合理工学研究科, 講師 (90444067)
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | 触媒反応 / 不均一系触媒 / 触媒化学 / 固体酸触媒 / 多機能触媒 / 有機合成 / 新規触媒反応 / 多様能触媒 / 新規反応 |
|---|
| Research Abstract |
Solid acid and base catalysts having tunable acidity and acid-base interactions were developed. Solid acid-supported organic amine catalysts showed high activity for Michael reactions using nitroalkanes and thiols. Furthermore, transformation reactions of atmospheric pressure of CO, to cyclic carbonates were achieved using heterogeneous catalysts having both acid site and aminopyridinium halides. Solid acid catalysts possessing silyl cation were found to be an excellent catalyst for allylsilylations.
|
Report
(3 results)
Research Products
(33 results)
