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Tolerance limit of tar concentration in wood gas to an anode in a solid oxide fuel cell

Research Project

Project/Area Number 21760719
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

NAMIOKA Tomoaki  Tokyo Institute of Technology, 大学院・総合理工学研究科, 講師 (90376955)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsバイオマスガス化燃料電池発電システム / タール / Metal-dusting corrosion / バイオマスガス化燃料電池発電 / 電極劣化 / スカンジア安定化ジルコニア / 固体酸化物型燃料電池 / バイオマスガス化 / 炭素析出 / Metal dusting / Ni / ScSZ / 高効率発電
Research Abstract

Anode deterioration behavior by tar in wood gas in a SOFC was observed with a SEM and a SEM-EDS. It was found that Ni particles disappearance took place at lower tar concentration than carbon deposition took place. Therefore, we suggested that disappearance of Ni be the criterion for judgment of anode deterioration. Based on the definition of anode deterioration, tolerance limit of tar concentration in wood gas was determined as follows; <1 g/Nm3 at 1073 K, and 3 g/Nm3 at 1173 K. The tolerance limit at 1173 K for the fuel cell is one to two orders of magnitude higher than the tolerance limit for ICEs. This mitigation would be one of the advantages of installing SOFCs instead of ICEs for power plants fueled by wood gas.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (11 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (9 results)

  • [Journal Article] Behavior and mechanisms of Ni/ScSZ cermet anode deterioration by trace tar in wood gas in a solid oxide fuel cell2011

    • Author(s)
      Tomoaki Namioka, Taichi Naruse, Ryosuke Yamane
    • Journal Title

      International Journal of Hydrogen Energy in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Behavior and mechanisms of Ni/ScSZ cermet anode deterioration by trace tar in wood gas in a solid oxide fuel cell2011

    • Author(s)
      Tomoaki Namioka, Taichi Naruse, Ryosuke Yamane
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: (In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Influence of model tar concentration in fuel gas and effect of operating conditions on Ni/ScSZ anode deterioration in a solid oxide fuel cell2010

    • Author(s)
      Tomoaki Namioka, Yuki Nagai, Taichi Naruse
    • Organizer
      The Second International Symposium on Gasification and Its Application
    • Place of Presentation
      Fukuoka, Japan
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Relationship between anode potential behaviors and morphological deterioration derived from toluene contamination in hydrogen Ni/ScSZ cermet anode in SOFC2010

    • Author(s)
      Tomoaki Namioka, Yuki Nagai, Taichi Naruse, Ryosuke Yamane
    • Organizer
      Fuel Cells Science & Technology Conference
    • Place of Presentation
      Zaragoza, Spain
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] SOFC燃料ガス中タール分によるNi/ScSZ サーメットアノードの劣化挙動2010

    • Author(s)
      永井悠葵、成瀬太一、波岡知昭、吉川邦夫、脇慶子
    • Organizer
      日本エネルギー学会大会
    • Place of Presentation
      新宿
    • Related Report
      2010 Final Research Report
  • [Presentation] Tolerance limit of toluene content in wood gas for Ni/ScSZ anode SOFC2010

    • Author(s)
      Tomoaki Namioka, Taichi Naruse, Ryosuke Yamane, Kunio Yoshikawa, Keiko Waki
    • Organizer
      The 18th European Biomass Conference and Exhibition
    • Place of Presentation
      Lyon, France
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] SOFC燃料ガス中タール分によるNi/ScSZサーメットアノードの劣化挙動2010

    • Author(s)
      永井悠葵、成瀬太一、波岡知昭、吉川邦夫、脇慶子
    • Organizer
      第19回日本エネルギー学会大会
    • Place of Presentation
      工学院大学(新宿)
    • Related Report
      2010 Annual Research Report
  • [Presentation] SOFC燃料ガス中タール分によるNi/ScSZ サーメットアノードの劣化挙動2009

    • Author(s)
      永井悠葵、成瀬太一、波岡知昭、吉川邦夫、脇慶子
    • Organizer
      第19回SOFC研究発表会
    • Place of Presentation
      九段下
    • Related Report
      2010 Final Research Report
  • [Presentation] Influences of trace tar in biomass gasified gas on power generation and carbon deposition on Ni/ScSZ cermet anode in SOFC2009

    • Author(s)
      Tomoaki Namioka, Taichi Naruse, Ryosuke Yamane, Kunio Yoshikawa, Keiko Waki
    • Organizer
      International Symposium on Low Carbon Technology
    • Place of Presentation
      Beijing, China
    • Related Report
      2010 Final Research Report
  • [Presentation] Influences of trace tar in biomass gasified gas on power generation and carbon deposition on Ni/ScSZ cermet anode in SOFC2009

    • Author(s)
      Tomoaki Namioka, et.al.
    • Organizer
      International Symposium on Low Carbon Technology, 2009
    • Place of Presentation
      Beijing
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ni/ScSZアノードの劣化に及ぼすバイオマスガス化ガス中タール濃度の影響2009

    • Author(s)
      永井悠葵, 他
    • Organizer
      SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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