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Formation of functional hierarchical structures from aqueous dispersions of cellulose nanofibrils

Research Project

Project/Area Number 21780163
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Wood science
Research InstitutionThe University of Tokyo

Principal Investigator

SAITO Tsuguyuki  The University of Tokyo, 大学院・農学生命科学研究科, 助教 (90533993)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywordsセルロース / ナノ材料 / 自己組織化 / 生体模倣 / ナノファイバー / 階層構造
Research Abstract

We have so far dispersed cellulose nanofibrils into water by using a surface carboxylation method of the nanofibrils, namely the TEMPO-mediated oxidation; the dispersed nanofibrils spontaneously align into a nematic-like order. In the present study, we have constructed a wide range of bulk materials, such as hydrogels, aerogels, and films, by controlling the integration mode of the self-aligned cellulose nanofibrils. These bulk materials consisted of aligned cellulose nanofibrils and exhibited outstanding properties.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (55 results)

All 2011 2010 2009 Other

All Journal Article (32 results) (of which Peer Reviewed: 28 results) Presentation (15 results) Book (3 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] TEMPO-Oxidized Cellulose Nanofibrils Dispersed in Organic Solvents2011

    • Author(s)
      Okita, Y., Fujisawa, S., Saito, T., Isogai, A.
    • Journal Title

      Biomacromolecules 12

      Pages: 518-522

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] TEMPO-Oxidized Cellulose Nanofibrils Dispersed in Organic Solvents2011

    • Author(s)
      Okita, Y.; Fujisawa, S.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: 12 Pages: 518-522

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Wood Cellulose Nanofibrils Prepared by TEMPO Electro-Mediated Oxidation2011

    • Author(s)
      Isogai, T.; Saito, T.; Isogai, A.
    • Journal Title

      Cellulose

      Volume: 18 Pages: 421-431

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of TEMPO-Oxidized Cellulose Nanofibril Films with Free Carboxyl Groups2011

    • Author(s)
      Fujisawa, S.; Okita, Y.; Fukuzumi, H.; Saito, T.; Isogai, A.
    • Journal Title

      Carbohydr.Polym.

      Volume: 84 Pages: 579-583

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TEMPO-Oxidized Cellulose Nanofibers2011

    • Author(s)
      Isogai, A.; Saito, T.; Fukuzumi H.
    • Journal Title

      Nanoscale

      Volume: 3 Pages: 71-85

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelastic Evaluation of Average Fiber Length of Cellulose Nanofibers Prepared by TEMPO-mediated Oxidation2011

    • Author(s)
      Ishii, D.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: 12 Pages: 584-550

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Bleached Wood Pulp by TEMPO/NaClO/NaClO_2 System : Effect of the Oxidation Conditions on Carboxylate Content and Degree of Polymerization2010

    • Author(s)
      Saito, T.,Hirota, M.,Tamura, N., Isogai, A.
    • Journal Title

      Wood Science 56

      Pages: 227-232

    • NAID

      10026544898

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] バイオ系ナノファイバー:TEMPO触媒酸化による天然セルロースのシングルナノファイバー化と材料物性の発現2010

    • Author(s)
      齋藤継之
    • Journal Title

      Nanofiber 1

      Pages: 35-38

    • Related Report
      2010 Final Research Report
  • [Journal Article] Entire Surface Oxidation of Various Cellulose Microfibrils by TEMPO-Mediated Oxidation2010

    • Author(s)
      Okita, Y., Saito, T.,Isogai, A.
    • Journal Title

      Biomacromolecules 11

      Pages: 1696-1700

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Bleached Wood Pulp by TEMPO/NaClO/NaClO_2 System : Effect of the Oxidation Conditions on Carboxylate Content and Degree of Polymerization2010

    • Author(s)
      Saito, T.; Hirota, M.; Tamura, N.; Isogai, A.
    • Journal Title

      J.Wood Science

      Volume: 56 Pages: 227-232

    • NAID

      10026544898

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water dispersion of cellulose II nanocrystals prepared by TEMPO-mediated oxidation of mercerized cellulose at pH 4.82010

    • Author(s)
      Hirota, M.; Tamura, N.; Saito, T.; Isogai, A.
    • Journal Title

      Cellulose

      Volume: 17 Pages: 279-288

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of curdlan and other polysaccharides by 4-acetamide-TEMPO/NaClO/NaClO_2 under acid conditions2010

    • Author(s)
      Tamura, N.; Hirota, M.; Saito, T.; Isogai, A.
    • Journal Title

      Carbohydr.Polym.

      Volume: 81 Pages: 592-598

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison study of TEMPO-analogous compounds on oxidation efficiency of wood cellulose for preparation of cellulose nanofibrils2010

    • Author(s)
      Iwamoto, S.; Kai, W.; Isogai, T.; Saito, T.; Isogai, A.; Iwata, T.
    • Journal Title

      Polym.Degrad.Stabil.

      Volume: 95 Pages: 1394-1398

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Side reactions of 4-acetamido-TEMPO as catalyst in cellulose oxidation systems2010

    • Author(s)
      Patel, I.; Opietnik, M.; Bohmdorfer, S.; Becker, M.; Potthast, A.; Saito, T.; Isogai, A.; Rosenau, T.
    • Journal Title

      Holzforschung

      Volume: 64 Pages: 549-554

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Entire Surface Oxidation of Various Cellulose Microfibrils by TEMPO-Mediated Oxidation2010

    • Author(s)
      Okita, Y.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: 11 Pages: 1696-1700

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Papermaking of Disintegrated Fibers of TEMPO-Mediated Oxidized Pulps2010

    • Author(s)
      Ishizuka, M.; Saito, T.; Enomae, T.; Isogai, A.
    • Journal Title

      Japan Tappi J.

      Volume: 64 Pages: 437-447

    • NAID

      10026214727

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CaCO_3/Chitin-Whisker Hybrids : Formation of CaCO_3 Crystals in Chitin-Based Liquid-Crystalline Suspension2010

    • Author(s)
      Yamamoto, Y.; Nishimura, T.; Saito, T.; Kato, T.
    • Journal Title

      Polym.J.

      Volume: 42 Pages: 583-586

    • NAID

      10027041522

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TEMPO Electro-Mediated Oxidation of Some Polysaccharides Including Regenerated Cellulose Fiber2010

    • Author(s)
      Isogai, T.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: 11 Pages: 1593-1599

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enlargement of Individual Cellulose Microfibrils in Transgenic Poplars Overexpressing Xyloglucanase2010

    • Author(s)
      Yamamoto, M.; Saito, T.; Isogai, A.; Kurita, M.; Kondo, T.; Taniguchi, T.; Kaida, R.; Baba, K.; Hayashi, T.
    • Journal Title

      J.Wood Science

      Volume: 57 Pages: 71-75

    • NAID

      10029035704

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal Stabilization of TEMPO-Oxidized Cellulose2010

    • Author(s)
      Fukuzumi, H.; Saito, T.; Okita, Y.; Isogai, A.
    • Journal Title

      Polym.Degrad.Stabil.

      Volume: 95 Pages: 1502-1508

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of TEMPO-Mediated Oxidation of Pulp Fibers on Filtration and Ion-exchange Properties of Handsheets2010

    • Author(s)
      Ishizuka, M.; Saito, T.; Enomae, T.; Isogai, A.
    • Journal Title

      Japan Tappi J.

      Volume: 64 Pages: 955-968

    • NAID

      10026493356

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Glucose/Glucuronic Acid Alternating Copoysaccharide Prepared from TEMPO-Oxidized Native Celluloses by Surface Peeling2010

    • Author(s)
      Hirota, M.; Furihata, K.; Saito, T.; Kawada, T.; Isogai, A.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 7670-7672

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Topochemical Synthesis and Catalysis of Metal Nanoparticles Exposed on Crystalline Cellulose Nanofibers2010

    • Author(s)
      Koga, H.; Okunaga E.; Hidaka M.; Umemura Y.; Saito T.; Isogai A.; Kitaoka T.
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 8576-8569

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] バイオ系ナノファイバー:TEMPO触媒酸化による天然セルロースのシングルナノファイバー化と材料物性の発現2010

    • Author(s)
      齋藤継之
    • Journal Title

      Nanofiber

      Volume: 1 Pages: 35-38

    • Related Report
      2010 Annual Research Report
  • [Journal Article] TEMPO酸化ナノファイバーの構造解析に関する研究2010

    • Author(s)
      齋藤継之
    • Journal Title

      繊維学会誌

      Volume: 66 Pages: 240-242

    • Related Report
      2010 Annual Research Report
  • [Journal Article] 環境適合型新規バイオ系ナノ先端部材:TEMPO酸化セルロースナノファイバー2010

    • Author(s)
      磯貝明; 齋藤継之
    • Journal Title

      バイオプラジャーナル

      Volume: 39 Pages: 12-17

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Individual chitin nano-whiskers prepared from partially deacetylated α-chitin by fibril surface cationization2010

    • Author(s)
      Fan, Y., Saito, T., Isogai, A.
    • Journal Title

      Carbohydr.Polym. 79

      Pages: 1046-1051

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Individualization of Nano-Sized Plant Cellulose Fibrils by Direct Surface Carboxylation Using TEMPO Catalyst under Neutral Conditions2009

    • Author(s)
      Saito, T., Hirota, M., Tamura, N., Fukuzumi, H., Kimura, S., Heux, L., Isogai, A.
    • Journal Title

      Biomacromolecules 10

      Pages: 1992-1996

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TEMPO-Mediated Oxidation of β-Chitins to Prepare Individual Nanofibrils2009

    • Author(s)
      Fan, Y., Saito, T., Isogai, A.
    • Journal Title

      Garbohydr.Polym. 77

      Pages: 832-838

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Carboxylation of Porous Regenerated Cellulose Beads by 4-Acetamide-TEMP0/NaClO/NaClO_2 System2009

    • Author(s)
      Hirota, M., Tamura, N., Saito, T., Isogai, A.
    • Journal Title

      Cellulose 16

      Pages: 841-851

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Regenerated Cellulose with NaClO_2 Catalyzed by TEMPO and NaClO under Acid-Neutral Conditions2009

    • Author(s)
      Hirota, M., Tamura, N., Saito, T., Isogai, A.
    • Journal Title

      Carbohydr.Polym. 78

      Pages: 330-335

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TEMPO-Mediated Oxidation of Softwood Thermomechanical Pulp2009

    • Author(s)
      Okita, Y., Saito, T., Isogai, A.
    • Journal Title

      Holzforschung 63

      Pages: 529-535

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Self-aligned materials of TEMPO-oxidized cellulose nanofibrils and pulp fibers2011

    • Author(s)
      Saito, T., Uematsu, T., Kimura, S., Enomae, T., Isogai, A.
    • Organizer
      241th American Chemical Society National Meeting, CELL Division No.127
    • Place of Presentation
      Anaheim, California, USA
    • Year and Date
      2011-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Self-aligned materials of TEMPO-oxidized cellulose nanofibrils and pulpfibers2011

    • Author(s)
      Saito, T.; Uematsu, T.; Kimura, S.; Enomae, T.; Isogai, A.
    • Organizer
      241th American Chemical Society National Meetings
    • Place of Presentation
      Anaheim, California, USA.
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 自己配列したTEMPO酸化ミクロフィブリル及びパルプ繊維の自立構造体2010

    • Author(s)
      齋藤継之, 木村聡, 江前敏晴, 磯貝明
    • Organizer
      セルロース学会第17回年次大会 P29
    • Place of Presentation
      香川県,徳島文理大学
    • Year and Date
      2010-07-15
    • Related Report
      2010 Final Research Report
  • [Presentation] 自己配列したTEMPO酸化ミクロフィブリル及びパルプ繊維の自立構造体2010

    • Author(s)
      齋藤継之;木村聡;江前敏晴;磯貝明
    • Organizer
      セルロース学会第17回年次大会
    • Place of Presentation
      香川県,徳島文理大学
    • Year and Date
      2010-07-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水中分散したTEMPO酸化ミクロフィブリル及びパルプ繊維の自己配列構造2010

    • Author(s)
      齋藤継之, 木村聡, 江前敏晴, 磯貝明
    • Organizer
      第77回紙パルプ研究発表会 14(最優秀発表賞受賞)
    • Place of Presentation
      東京都,タワーホール船堀
    • Year and Date
      2010-06-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 水中分散したTEMPO酸化ミクロフィブリル及びパルプ繊維の自己配列構造2010

    • Author(s)
      齋藤継之;木村聡;江前敏晴;磯貝明
    • Organizer
      第77回紙パルプ研究発表会
    • Place of Presentation
      東京都,タワーホール船堀
    • Year and Date
      2010-06-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Size measurements of cellulose microfibrils individually dispersed by TEMPO-mediated oxidation2010

    • Author(s)
      Saito, T., Shinoda, R., Okita, Y., Isogai, A.
    • Organizer
      239th American Chemical Society National Meetings
    • Place of Presentation
      San Francisco, California, USA
    • Year and Date
      2010-03-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Individualization of nano-sized plant cellulose fibrils by TEMPO-mediated oxidation2009

    • Author(s)
      齋藤継之
    • Organizer
      The 2nd International Conference on Bio-based Polymers 2009
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2009-11-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] TEMPO触媒酸化セルロースの構造解析とナノ材料への展開2009

    • Author(s)
      齋藤継之
    • Organizer
      日本農学アカデミー第11回シンポジウム
    • Place of Presentation
      東京都,東京大学農学部3号館
    • Year and Date
      2009-11-07
    • Related Report
      2010 Final Research Report
  • [Presentation] TEMPO触媒酸化セルロースの構造解析とナノ材料への展開2009

    • Author(s)
      齋藤継之
    • Organizer
      日本農学アカデミー 第11回シンポジウム
    • Place of Presentation
      東京都, 東京大学農学部3号館
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] TEMPO触媒酸化による天然セルロースのナノファイバー化と物性発現2009

    • Author(s)
      齋藤継之, 范一民, 福住早花, 沖田祐介, 磯貝明
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本県, 熊本大学
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Dispersion of native cellulose nanofibrils by TEMPO-mediated oxidation and expression of the material properties2009

    • Author(s)
      齋藤継之
    • Organizer
      The 2009 Japanese-Sino Fiber Symposium
    • Place of Presentation
      Nagano, Japan
    • Year and Date
      2009-09-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] α及びβキチンのシングルミクロフィブリル化2009

    • Author(s)
      齋藤継之, 范一民, 磯貝明
    • Organizer
      セルロース学会第16回年次大会
    • Place of Presentation
      北海道, 北海道大学
    • Year and Date
      2009-07-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] TEMPO触媒酸化によるセルロースのナノファイバー化2009

    • Author(s)
      齋藤継之
    • Organizer
      生物材料の会 第8回林産会総会
    • Place of Presentation
      東京都, 東京大学弥生講堂
    • Year and Date
      2009-06-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Cellulose nanofibers prepared by TEMPO-mediated oxidation under acid conditions2009

    • Author(s)
      Saito, T., Fukuzumi, H., Hirota, M., Isogai, A.
    • Organizer
      15th International Symposium on Wood, Fibre and Pulping Chemistry
    • Place of Presentation
      Oslo, Norway
    • Year and Date
      2009-06-15
    • Related Report
      2009 Annual Research Report
  • [Book] 機能性繊維の最新技術(分担執筆・第3章"セルロースシングルナノファイバー")2009

    • Author(s)
      磯貝明, 齋藤継之
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Book] 機能性繊維の最新技術(分担執筆・第3章"α・βキチンナノファイバー")2009

    • Author(s)
      齋藤継之, 范一民, 磯貝明
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Book] セルロースシングルナノファイバー(機能性繊維の最新技術2009,第3章)

    • Author(s)
      磯貝明, 齋藤継之
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] セルロースナノファイバー分散液の製造方法、セルロースナノファイバー分散液、セルロースナノファイバー成形体、及びセルロースナノファイバー複合体2010

    • Inventor(s)
      磯貝明, 齋藤継之, 藤澤秀次
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Number
      2010-159853
    • Filing Date
      2010-07-14
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 物理ゲルの製造方法および物理ゲル2010

    • Inventor(s)
      磯貝明, 齋藤継之
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Number
      2010-137566
    • Filing Date
      2010-06-16
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 物理ゲルの製造方法および物理ゲル2010

    • Inventor(s)
      磯貝明;齋藤継之
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Number
      2010-137566
    • Filing Date
      2010-06-16
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] セルロースナノファイバー分散液の製造方法、セルロースナノファイバー分散液、セルロースナノファイバー成形体、及びセルロースナノファイバー複合体2010

    • Inventor(s)
      磯貝明;齋藤継之;藤澤秀次
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Number
      2010-159853
    • Filing Date
      2010-07-14
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] セルロースナノファイバー分散液の製造方法、セルロースナノファイバー分散液、セルロースナノファイバー成形体、およびセルロースナノファイバー複合体2009

    • Inventor(s)
      磯貝明, 齋藤継之, 沖田祐介
    • Industrial Property Rights Holder
      東京大学
    • Industrial Property Number
      2009-124408
    • Filing Date
      2009-05-22
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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