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Characteristics of oxidative reactions of condensed tannins and related polyphenols.

Research Project

Project/Area Number 21780168
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Wood science
Research InstitutionForestry and Forest Products Research Institute

Principal Investigator

HASHIDA Kou  独立行政法人森林総合研究所, バイオマス化学研究領域, 主任研究員 (40353809)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords抽出成分 / 微量成分 / 樹木タンニン類 / 酸化 / ピロガロール / プロピルアミン / アミノ化 / フラバノール / 求核反応
Research Abstract

To clarify the characteristics of oxidative reactions of condensed tannins, reaction behaviors of condensed tannins and related polyphenols with n^-propylamine were studied. By the investigations using polyphenolic model compounds, monomeric and dimeric flavanols and natural condensed tannnins, it was revealed that the pyrogaloll nucleus reacts with n^-propylamine in the presence of molecular oxygen to form aminated products. In contrast, the catechol nucleus did not cause a clear amination with n^-propylamine.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (8 results)

All 2012 2011 2010

All Presentation (8 results)

  • [Presentation] フラバノール類とn^-プロピルアミンとの反応挙動II-エピガロカテキンのアミノ化反応挙動-2012

    • Author(s)
      橋田光、久保智史、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      北海道大学農学部(札幌)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] フラバノール類とn-プロピルアミンとの反応挙動II-エピガロカテキンのアミノ化反応挙動-2012

    • Author(s)
      橋田光、久保智史、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      北海道大学農学部(札幌)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 縮合型タンニンとn^-プロピルアミンとの反応挙動2012

    • Author(s)
      橋田光、久保智史、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      北海道大学農学部(札幌)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 縮合型タンニンとn-プロピルアミンとの反応挙動2012

    • Author(s)
      橋田光、久保智史、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      北海道大学農学部(札幌)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] フラバノール類とn^-プロピルアミンとの反応挙動2011

    • Author(s)
      橋田光、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      京都大学農学部(京都)
    • Year and Date
      2011-03-18
    • Related Report
      2011 Final Research Report
  • [Presentation] フラバノール類とn-プロピルアミンとの反応挙動2011

    • Author(s)
      橋田光、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      京都大学農学部(京都市)
    • Year and Date
      2011-03-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 多価フェノール核とn^-プロピルアミンとの反応挙動2010

    • Author(s)
      橋田光、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      宮崎市民プラザ(宮崎)
    • Year and Date
      2010-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 多価フェノール核とnプロピルアミンとの反応挙動2010

    • Author(s)
      橋田光、牧野礼、大原誠資
    • Organizer
      日本木材学会
    • Place of Presentation
      宮崎市民プラザ(宮崎県)
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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