| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Research Abstract |
We developed efficient synthetic methods of heterocyclic compounds by means of consecutive bond formation approaches based on each of the following reactions : 1) syntheses of highly substituted pyrroles and furans via Au-catalyzed Claisen rearrangement reactions, 2) syntheses of oxazoles and furans concomitantly with incorporation of allyl gropes or oxygen functional gropes via Pd-catalyzed cyclization-allylation sequences or metal-free oxidative cyclization reactions, and 3) syntheses of dihydroquinolines and iminoquinolinones via hetero en-yne metatheses.
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