Development of Novel Recycling System for Organic Synthesis via Ionic Polymer-Gel
| Project/Area Number |
21790028
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kinki University |
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Principal Investigator |
HAMAMOTO Hiromi Kinki University, 薬学部, 講師 (40365896)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 合成化学 / 高分子構造・物性 / 高分子合成 / 触媒・化学プロセス / 有機化学 / 高分子構造 ・ 物性 / 触媒 ・ 化学プロセス |
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| Research Abstract |
The use of a novel reaction medium provided by functionalized polymers could often bring a new strategy in the design of reagent or catalyst recycling systems. We have developed heterogeneous catalytic oxidation systems utilizing ionic polyacrylamide based polymer gel. These systems are effective for severaltransition metal-catalyzed oxidation systems using clean oxidants. In addition, the recovered catalyst could be used for consecutive reactions. Further applications of this system for oxidative halodecarboxylation of rich arenecarboxylic acids were also investigated.
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Report
(3 results)
Research Products
(45 results)
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[Presentation]2009
Author(s)
三木康義, 堂下正嗣, 太田千晶, 服部翔, 梅本味左子, 梅本英彰, 濱本博三
Organizer
第35回反応と合成の進歩シンポジウム
Place of Presentation
金沢
Year and Date
2009-11-16
Related Report
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