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A neutron scattering study on dynamical structure in β-pyrochlore oxide

Research Project

Project/Area Number 21840020
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Condensed matter physics I
Research InstitutionThe University of Tokyo

Principal Investigator

KOFU Maiko  The University of Tokyo, 物性研究所, 助教 (70549568)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥2,704,000 (Direct Cost: ¥2,080,000、Indirect Cost: ¥624,000)
Fiscal Year 2010: ¥1,287,000 (Direct Cost: ¥990,000、Indirect Cost: ¥297,000)
Fiscal Year 2009: ¥1,417,000 (Direct Cost: ¥1,090,000、Indirect Cost: ¥327,000)
Keywordsβパイロクロア酸化物 / ラットリング / 同形転移 / 中性子散乱 / 物性実験 / 強相関電子系
Research Abstract

Inβ-pyrochlore oxide KOs_2O_6, a λ-shaped anomaly in heat capacity is observed below its superconducting transition temperature. This anomaly originates in a structure phase transition, but its origin is unknown. We ha ve carried out high -resolution neutron powder diffraction measurements on high quality and small crystals of KOs_2O_6 in order to investigate the crystal structure below and above the transition. It is found that the phase transition is an isomorphic one without symmetry breaking. Besides, in the low-temperature phase, the cage volume expands and the density distribution of K ions becomes broader, indicating that the ground state of rattling motion changes at the transition.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (7 results)

All 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results)

  • [Journal Article] A novel isomorphic phase transition in β -pyrochlore oxide KOs2O6 : a study using high resolution neutron powder diffraction2010

    • Author(s)
      Kenzo Sasai, Maiko Kofu, Richard M Ibberson, Kazuma Hirota, Jun-ichi Yamaura, Zenji Hiroi, Osamu Yamamuro
    • Journal Title

      J.Phys.:Condens.Matter Vol.22

      Pages: 15403-15403

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Novel Isomorphic Phase Transition in β-Pyrochlore Oxide KOs_2O_6 : A Study Using High-resolution Neutron Powder Diffraction2010

    • Author(s)
      K.Sasai, M.Kofu, R.M.Ibberson, K.Hirota, J.Yamaura, Z.Hiroi, O.Yamamuro
    • Journal Title

      Journal of Physics : Condensed matter 22

      Pages: 15403-15403

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] β型パイロクロア酸化物KOs_2O_6における新奇な同形転移2009

    • Author(s)
      古府麻衣子、佐々井健蔵、山浦淳一、廣井善二、廣田和馬、Richard M.bberson、山室修
    • Organizer
      日本中性子科学会第9回年会
    • Place of Presentation
      いばらき量子ビーム研究センター
    • Year and Date
      2009-12-10
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子回折でみたβ型パイロクロア酸化物の新奇相転移2009

    • Author(s)
      古府麻衣子、佐々井健蔵、Richard M.Ibberson、廣田和馬、山浦淳一、廣井善二、山室修
    • Organizer
      金研中性子散乱研究会シリーズ「中性子を用いた新しいマテリアルサイエンスの検討」
    • Place of Presentation
      東北大学
    • Year and Date
      2009-11-11
    • Related Report
      2010 Final Research Report
  • [Presentation] 熱容量測定と中性子回折でみたβ型パイロクロア酸化物KOs_2O_6の相転移2009

    • Author(s)
      古府麻衣子、佐々井健蔵、山室修、廣田和馬、Richard M.Ibberson、山浦淳一、廣井善二
    • Organizer
      第45回熱測定討論会
    • Place of Presentation
      首都大学
    • Year and Date
      2009-09-30
    • Related Report
      2010 Final Research Report
  • [Presentation] 高分解能中性子粉末回折で見たβ型パイロクロア酸化物KOs_2O_6の同形転移2009

    • Author(s)
      古府麻衣子、佐々井健蔵、山室修、廣田和馬、Richard M.Ibberson、山浦淳一、廣井善二
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 高分解能中性子粉末回折で見たβ型パイロクロア酸化物KOs_2O_6の同形転移2009

    • Author(s)
      古府麻衣子
    • Organizer
      第64回日本物理学会秋季大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2020-05-15  

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