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Development on a novel catalysis based on the structural fluctuation of metal cluster catalysts

Research Project

Project/Area Number 21850001
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

TSUNOYAMA Hironori  Hokkaido University, 触媒化学研究センター, 助教 (40390661)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥3,016,000 (Direct Cost: ¥2,320,000、Indirect Cost: ¥696,000)
Fiscal Year 2010: ¥1,456,000 (Direct Cost: ¥1,120,000、Indirect Cost: ¥336,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsクラスター化学 / 触媒化学 / 有機分子保護金クラスター / 空気酸化反応 / 魔法数 / 電子構造 / アルコール酸化 / 有機保護金クラスター / ポリビニルピロリドン / 電子殻モデル
Research Abstract

The effect of size in the aerobic oxidation catalysis of Au clusters stabilized by PVP has been investigated in the atomic resolution. It is concluded that (1) only the Au clusters smaller than 70-mer are active in the catalysis and (2) the activity is originated from the excess negative charge on the Au clusters which is donated by PVP. It was found that the microwave irradiation drastically accelerates the aerobic oxidation catalysis of Au11 supported on mesoporus silica.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (45 results)

All 2011 2010 2009 Other

All Journal Article (22 results) (of which Peer Reviewed: 22 results) Presentation (21 results) Book (2 results)

  • [Journal Article]2011

    • Author(s)
      Y.Lei-Kalisman, P.D.Jadzinsk, 角山寛規, 佃達哉, D-A.Bushnell, R.Komberg
    • Journal Title

      J.Am.Chem.Soc. Vol.133

      Pages: 2976-2982

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxidations Catalyzed by Colloidal Nanogold2011

    • Author(s)
      佃達哉,角山寛規,櫻井英博
    • Journal Title

      Chem.Asian J. Vol.6

      Pages: 736-748

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite : Size Effect in the Sub-2 nm Regime2011

    • Author(s)
      Y.Liu, H.Tsunoyama, T.Akita, S.Xie, T.Tsukuda
    • Journal Title

      ACS Catal.

      Volume: 1 Pages: 2-6

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxidations Catalyzed by Colloidal Nanogold2011

    • Author(s)
      T.Tsukuda, H.Tsunoyama, H.Sakurai
    • Journal Title

      Chem. Asian J.

      Volume: 6 Pages: 736-748

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Au102 (p-MBA) 44 Nanoparticles2011

    • Author(s)
      Y.Lei-Kalisman, P.D.Jadzinsky, H.Tsunoyama, T.Tsukuda, D.A.Bushnell, R.Kornberg
    • Journal Title

      J.Am. Chem. Soc.

      Volume: 133 Pages: 2976-2982

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] MALDI Mass Analysis of 11 kDa Gold Clusters Protected by Octadecanethiolate Ligands2010

    • Author(s)
      角山理沙子, 角山寛規, P.Pamopard, J.Limtrakul, 佃達哉
    • Journal Title

      J.Phys.Chem.C Vol.114

      Pages: 16004-16009

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chirality and Electronic Structure of the Thiolate-Protected Au38 Nanocluster2010

    • Author(s)
      O.Lopez-Acevedo, 角山寛規, 佃達哉, H.Hakkinen, C.M.Aikens
    • Journal Title

      J.Am.Chem.Soc. Vol.132

      Pages: 8210-8218

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Size Effect of Silica-Supported Gold Clusters in the Microwave-Assisted Oxidation of Benzyl Alcohol with H_2O_22010

    • Author(s)
      劉永梅,角山寛規,秋田友樹,佃達哉
    • Journal Title

      Chem.Lett. Vol.39

      Pages: 159-161

    • NAID

      10027177531

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Efficient and Selective Epoxidation of Styrene with TBHP Catalyzed by Au25 Clusterson2010

    • Author(s)
      劉永梅,角山寛規,秋田友樹,佃達哉
    • Journal Title

      Hydroxyapatite, Chem.Commun. Vol.46

      Pages: 550-552

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Size Effect of Silica-Supported Gold Clusters in the Microwave-Assisted Oxidation of Benzyl Alcohol with H2O22010

    • Author(s)
      Y.Liu, H.Tsunoyama, T.Akita, T.Tsukuda
    • Journal Title

      Chem. Lett.

      Volume: 39 Pages: 159-161

    • NAID

      130004425758

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chirality and Electronic Structure of the Thiolate-Protected Au38 Nanocluster2010

    • Author(s)
      O.Lopez-Acevedo, H.Tsunoyama, T.Tsukuda, H.Hakkinen, C.M.Aikens
    • Journal Title

      J.Am. Chem. Soc.

      Volume: 132 Pages: 8210-8218

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] MALDI Mass Analysis of 11 kDa Gold Clusters Protected by Octadecanethiolate Ligands2010

    • Author(s)
      R.Tsunoyama, H.Tsunoyama, P.Pannopard, J.Limtrakul, T.Tsukuda
    • Journal Title

      J.Phys. Chem. C

      Volume: 114 Pages: 16004-16009

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient and Selective Epoxidation of Styrene with TBHP Catalyzed by Au25 Clusters on Hydroxyapatite2010

    • Author(s)
      劉永梅, 角山寛規, 秋田友樹, 佃達哉
    • Journal Title

      Chemical Communications 46

      Pages: 550-552

    • NAID

      120002725526

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magic Numbers of Gold Clusters Stabilized by PVP2009

    • Author(s)
      角山寛規,佃達哉
    • Journal Title

      J.Am.Chem.Soc. Vol.131

      Pages: 18216-18217

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis2009

    • Author(s)
      角山寛規,一國伸之,櫻井英博,佃達哉
    • Journal Title

      J.Am.Chem.Soc. Vol.131

      Pages: 7086-7093

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of~1 nm Gold Clusters Confined within Mesoporous Silica and Microwave-Assisted Catalytic Application for Alcohol Oxidation2009

    • Author(s)
      劉永梅,角山寛規,秋田友樹,佃達哉
    • Journal Title

      J.Phys.Chem.C Vol.113

      Pages: 13457-13461

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxygenation of Benzylic Ketones Promoted by Gold Nanocluster Catalyst2009

    • Author(s)
      櫻井英博,神谷郁代,北原宏明,角山寛規,佃達哉
    • Journal Title

      Synlett

      Pages: 245-248

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxygenation of Benzylic Ketones Promoted by Gold Nanocluster Catalyst2009

    • Author(s)
      櫻井英博, 神谷郁代, 北原宏明, 角山寛規, 佃達哉
    • Journal Title

      Synlett

      Pages: 245-248

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of ~1nm Gold Clusters Confined within Mesoporous Silica and Microwave-Assisted Catalytic Application for Alcohol Oxidation2009

    • Author(s)
      劉永梅, 角山寛規, 秋田友樹, 佃達哉
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 13457-13461

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis2009

    • Author(s)
      角山寛規, 一國伸之, 櫻井英博, 佃達哉
    • Journal Title

      Journal of the American Chemical Society 131

      Pages: 7086-7093

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magic Numbers of Gold Clusters Stabilized by PVP2009

    • Author(s)
      角山寛規, 佃達哉
    • Journal Title

      Journal of the American Chemical Society 131

      Pages: 18216-18217

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]

    • Author(s)
      劉永梅,角山寛規,秋田友樹,謝頒海,佃達哉
    • Journal Title

      ACS Catal. Vol.1

      Pages: 2-6

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Presentation] Critical Size for Aerobic Oxidation Catalysis by PVP-Stabilized Au Clusters2011

    • Author(s)
      角山寛規
    • Organizer
      Intemational Conference on MEXT Project of Integrated Research on Chemical Synthesis
    • Place of Presentation
      北海道大学
    • Year and Date
      2011-01-24
    • Related Report
      2010 Final Research Report
  • [Presentation] Critical Size for Aerobic Oxidation Catalysis by PVP-Stabilized Au Clusters2011

    • Author(s)
      角山寛規、佃達哉
    • Organizer
      International Conference on MEXT Project of Integrated Research on Chemical Synthesis
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2011-01-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] On the Origin of Size Specific Catalysis of Poly (Vinylpyrrolidone) Stabilized Au Clusters for Aerobic Oxidation Reactions2010

    • Author(s)
      角山寛規
    • Organizer
      Nano Thailand 2010
    • Place of Presentation
      バンコク,タイ
    • Year and Date
      2010-11-19
    • Related Report
      2010 Final Research Report
  • [Presentation] On the Origin of Size Specific Catalysis of Poly (Vinylpyrrolidone) Stabilized Au Clusters for Aerobic Oxidation Reactions2010

    • Author(s)
      角山寛規、一國伸之、櫻井英博、佃達哉
    • Organizer
      NanoThailand 2010
    • Place of Presentation
      バンコク(タイ) 招待講演
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Size Effect on Aerobic Oxidation Catalysis of Pvp-Stabilized Au Clusters Studied by Mass Spectrometry2010

    • Author(s)
      角山寛規
    • Organizer
      ISSPIC-15
    • Place of Presentation
      オアバカ,メキシコ
    • Year and Date
      2010-09-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Size Effect on Aerobic Oxidation Catalysis of Pvp-Stabilized Au Clusters Studied by Mass Spectrometry2010

    • Author(s)
      角山寛規、佃達哉
    • Organizer
      ISSPIC-15
    • Place of Presentation
      オアバカ(メキシコ)
    • Year and Date
      2010-09-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] PVP保護Auクラスターの酸化触媒活性におけるしきいサイズの発見2010

    • Author(s)
      角山寛規
    • Organizer
      分子科学討論会2010
    • Place of Presentation
      大阪大学
    • Year and Date
      2010-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] PVP保護Auクラスターの酸化触媒活性におけるしきいサイズの発見2010

    • Author(s)
      角山寛規、佃達哉
    • Organizer
      分子科学討論会2010
    • Place of Presentation
      大阪大学(吹田市)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] On The Origin of Size Specific Catalysis of Poly (Vinylpyrrolidone) Stabilized Au Clusters for Aerobic Oxidation Reactions2010

    • Author(s)
      角山寛規
    • Organizer
      TocAr6/APcAr5
    • Place of Presentation
      北海道札幌市
    • Year and Date
      2010-07-22
    • Related Report
      2010 Final Research Report
  • [Presentation] On The Origin of Size Specific Catalysis of Poly (Vinylpyrrolidone) Stabilized Au Clusters for Aerobic Oxidation Reactions2010

    • Author(s)
      角山寛規、一國伸之、櫻井英博、佃達哉
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌市コンベンションセンター
    • Year and Date
      2010-07-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見とその酸化触媒作用2010

    • Author(s)
      角山寛規、佃達哉
    • Organizer
      統合物質創製化学推進事業-第一回若手研究会
    • Place of Presentation
      福岡県福岡市休暇村志賀島
    • Year and Date
      2010-06-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリビニルピロリドン保護金クラスターにおける魔法数の発見と触媒作用2010

    • Author(s)
      角山寛規
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリビニルピロリドン保護金クラスターにおける魔法数の発見と触媒作用2010

    • Author(s)
      角山寛規, 佃達哉
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見とその酸化触媒作用2010

    • Author(s)
      角山寛規
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都府京都市
    • Year and Date
      2010-03-25
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見とその酸化触媒作用2010

    • Author(s)
      角山寛規, 佃達哉
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都テルサ(京都市)
    • Year and Date
      2010-03-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見2010

    • Author(s)
      角山寛規, 佃達哉
    • Organizer
      ナノ学会 ナノ構造・物性部会 第2回研究会
    • Place of Presentation
      神戸大学(神戸市)
    • Year and Date
      2010-01-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見2010

    • Author(s)
      角山寛規
    • Organizer
      ナノ学会ナノ構造・物性部会第2回研究会
    • Place of Presentation
      神戸大学
    • Year and Date
      2010-01-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Exploring Magic Numbersin Au Clusters Stabilized by PVP2009

    • Author(s)
      角山寛規
    • Organizer
      CRC20周年記念国際シンポジウム
    • Place of Presentation
      北海道大学
    • Year and Date
      2009-12-07
    • Related Report
      2010 Final Research Report
  • [Presentation] Exploring Magic Numbers in Au Clusters Stabilized by PVP2009

    • Author(s)
      角山寛規, 佃達哉
    • Organizer
      触媒化学研究センター20周年記念国際シンポジウム
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見2009

    • Author(s)
      角山寛規
    • Organizer
      分子科学討論会 2009
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリマー保護金クラスターにおける魔法数の発見2009

    • Author(s)
      角山寛規, 佃達哉
    • Organizer
      分子科学討論会2009
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      2009-09-24
    • Related Report
      2009 Annual Research Report
  • [Book] 現代化学増刊44 16章(金属ナノクラスターの化学)2011

    • Author(s)
      角山寛規,佃達哉
    • Publisher
      東京化学同人
    • Related Report
      2010 Final Research Report
  • [Book] 現代化学増刊44 16章「金属ナノクラスターの化学」2011

    • Author(s)
      角山寛規、佃達哉
    • Total Pages
      14
    • Publisher
      東京化学同人
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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