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Development of new organic reactions and functionalities within porous coordination networks as nano-sized flasks

Research Project

Project/Area Number 21850008
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

INOKUMA Yasuhide  The University of Tokyo, 大学院・工学系研究科, 助教 (80555566)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2010: ¥1,755,000 (Direct Cost: ¥1,350,000、Indirect Cost: ¥405,000)
Fiscal Year 2009: ¥1,755,000 (Direct Cost: ¥1,350,000、Indirect Cost: ¥405,000)
Keywords細孔性錯体 / X線結晶構造解析 / 固相反応 / ホストーゲスト化学 / ホスト-ゲスト化学
Research Abstract

A variety of organic reactions have been examined within porous coordination network crystals, and these structural transformations have also been analyzied by X-ray single crystallography. In addition, networked molecular cages in which solution-like rich host-guest interactions take place have been successfully synthesized. These findings promise further developments in crystalline state chemistry.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (24 results)

All 2010 2009 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (6 results) Remarks (2 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 2 results)

  • [Journal Article] A Molecular Capsule Network : Guest Encapsulation and Control of Diels-Alder Reactivity2010

    • Author(s)
      Y.Inokuma, S.Yoshioka, M.Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 8912-8914

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests2010

    • Author(s)
      Y.Inokuma, T.Arai, M.Fujita
    • Journal Title

      Nature Chem. 2巻

      Pages: 780-783

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask2010

    • Author(s)
      K. Ikemoto, Y. Inokuma, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 5750-5752

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network2010

    • Author(s)
      K. Ohara, Y. Inokuma, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 5507-5509

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Huisgen Cycloaddition within Porous Coordination Networks2010

    • Author(s)
      T. Kawamichi, Y. Inokuma, M. Kawano, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 2375-2377

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore2010

    • Author(s)
      K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
    • Journal Title

      J.Am.Chem.Soc. 132巻

      Pages: 30-31

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photosensitizing Porous Coordination Network : The Catalytic, Z to E One-way Photo-isomerizations of Stilbenes in the Pore2010

    • Author(s)
      Kazuaki Ohara, Yasuhide Inokuma, Makoto Fujita
    • Journal Title

      Angewandte Chemie, International Edition

      Volume: 49 Pages: 5507-5509

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask2010

    • Author(s)
      Koki Ikemoto, Yasuhide Inokuma, Makoto Fujita
    • Journal Title

      Angewandte Chemie, Ihternational Edition

      Volume: 49 Pages: 5750-5752

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Networked molecular cages as crystalline sponges for fullerenes and other guests2010

    • Author(s)
      Yasuhide Inokuma, Tatsuhiko Arai, Makoto Fujita
    • Journal Title

      Nature Chemistry

      Volume: 2 Pages: 780-783

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Molecular Capsule Network : Guest Encapsulation and Control of Diels-Alder Reactivity2010

    • Author(s)
      Yasuhide Inokuma, Shota Yoshioka, Makoto Fujita
    • Journal Title

      Angewandte Chemie, International Edition

      Volume: 49 Pages: 8912-8914

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore2010

    • Author(s)
      Kazuaki Ohara, Masaki Kawano, Yasuhide Inokuma, Makoto Fujita
    • Journal Title

      Journal of the American Chemical Society 132

      Pages: 30-31

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Huisgen Cycloaddition within Porous Coordination Networks2010

    • Author(s)
      Takehide Kawamichi, Yasuhide Inokuma, Masaki Kawano, Makoto Fujita
    • Journal Title

      Angewandte Chemie, International Edition 49

      Pages: 2375-2377

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Networked Cages and Capsules : Rich Host-Guest Chemistry in a Crystal2010

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      ハワイ・ホノルル
    • Year and Date
      2010-12-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Networked Cages and Capsules : Rich Host-Guest Chemistry in a Crystal2010

    • Author(s)
      Yasuhide Inokuma, Makoto Fulita
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      ハワイ・ホノルル(アメリカ)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Guest Inclusion of Networked M_6L_4 Molecular Cages2010

    • Author(s)
      猪熊泰英, Tatsuhiko Arai, Makoto Fujita
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA, JAPAN
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and Guest Inclusion of Networked M_6L_4 Molecular Cages2010

    • Author(s)
      Yasuhide Inokuma, Tatsuhiko Arai, Makoto Fujita
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA, JAPAN
    • Place of Presentation
      大阪国際交流センター(大阪府)
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] M6L4ケージを無限配列した細孔性錯体(1):合成・構造・単結晶-単結晶ゲスト包接2010

    • Author(s)
      猪熊泰英、荒井達彦、藤田誠
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-26
    • Related Report
      2010 Final Research Report
  • [Presentation] M6L4ケージを無限配列した細孔性錯体(1):合成・構造・単結晶-単結晶ゲスト包接2010

    • Author(s)
      猪熊泰英、荒井達彦、藤田誠
    • Organizer
      日本化学会 第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/

    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2010

    • Inventor(s)
      藤田誠、猪熊泰英、荒井達彦
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Filing Date
      2010-11-19
    • Related Report
      2010 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2010

    • Inventor(s)
      荒井達彦, 猪熊泰英, 藤田誠
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Filing Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2009

    • Inventor(s)
      藤田誠、猪熊泰英、荒井達彦
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Number
      2009-265505
    • Filing Date
      2009-11-20
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2009

    • Inventor(s)
      藤田誠, 猪熊泰英, 荒井達彦
    • Industrial Property Rights Holder
      国立大学法人 東京大学
    • Industrial Property Number
      2009-265505
    • Filing Date
      2009-11-20
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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