Development of new organic reactions and functionalities within porous coordination networks as nano-sized flasks

• Project/Area Number: 21850008
• Research Category: Grant-in-Aid for Research Activity Start-up
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: The University of Tokyo
• Principal Investigator: INOKUMA Yasuhide The University of Tokyo, 大学院・工学系研究科, 助教 (80555566)
• Project Period (FY): 2009 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2010: ¥1,755,000 (Direct Cost: ¥1,350,000、Indirect Cost: ¥405,000); Fiscal Year 2009: ¥1,755,000 (Direct Cost: ¥1,350,000、Indirect Cost: ¥405,000)
• Keywords: 細孔性錯体 / X線結晶構造解析 / 固相反応 / ホストーゲスト化学 / ホスト-ゲスト化学

Research Abstract

A variety of organic reactions have been examined within porous coordination network crystals, and these structural transformations have also been analyzied by X-ray single crystallography. In addition, networked molecular cages in which solution-like rich host-guest interactions take place have been successfully synthesized. These findings promise further developments in crystalline state chemistry.

Research Products

• [Journal Article] A Molecular Capsule Network : Guest Encapsulation and Control of Diels-Alder Reactivity (2010)
  • Author(s): Y.Inokuma, S.Yoshioka, M.Fujita
  • Journal Title: Angew.Chem.Int.Ed. 49巻 Pages: 8912-8914
  • Peer Reviewed
• [Journal Article] Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests (2010)
  • Author(s): Y.Inokuma, T.Arai, M.Fujita
  • Journal Title: Nature Chem. 2巻 Pages: 780-783
  • Peer Reviewed
• [Journal Article] The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask (2010)
  • Author(s): K. Ikemoto, Y. Inokuma, M. Fujita
  • Journal Title: Angew.Chem.Int.Ed. 49巻 Pages: 5750-5752
  • Peer Reviewed
• [Journal Article] The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network (2010)
  • Author(s): K. Ohara, Y. Inokuma, M. Fujita
  • Journal Title: Angew.Chem.Int.Ed. 49巻 Pages: 5507-5509
  • Peer Reviewed
• [Journal Article] Regioselective Huisgen Cycloaddition within Porous Coordination Networks (2010)
  • Author(s): T. Kawamichi, Y. Inokuma, M. Kawano, M. Fujita
  • Journal Title: Angew.Chem.Int.Ed. 49巻 Pages: 2375-2377
  • Peer Reviewed
• [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore (2010)
  • Author(s): K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
  • Journal Title: J.Am.Chem.Soc. 132巻 Pages: 30-31
  • Peer Reviewed
• [Journal Article] Photosensitizing Porous Coordination Network : The Catalytic, Z to E One-way Photo-isomerizations of Stilbenes in the Pore (2010)
  • Author(s): Kazuaki Ohara, Yasuhide Inokuma, Makoto Fujita
  • Journal Title: Angewandte Chemie, International Edition Volume: 49 Pages: 5507-5509
  • Peer Reviewed
• [Journal Article] The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask (2010)
  • Author(s): Koki Ikemoto, Yasuhide Inokuma, Makoto Fujita
  • Journal Title: Angewandte Chemie, Ihternational Edition Volume: 49 Pages: 5750-5752
  • Peer Reviewed
• [Journal Article] Networked molecular cages as crystalline sponges for fullerenes and other guests (2010)
  • Author(s): Yasuhide Inokuma, Tatsuhiko Arai, Makoto Fujita
  • Journal Title: Nature Chemistry Volume: 2 Pages: 780-783
  • Peer Reviewed
• [Journal Article] A Molecular Capsule Network : Guest Encapsulation and Control of Diels-Alder Reactivity (2010)
  • Author(s): Yasuhide Inokuma, Shota Yoshioka, Makoto Fujita
  • Journal Title: Angewandte Chemie, International Edition Volume: 49 Pages: 8912-8914
  • Peer Reviewed
• [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore (2010)
  • Author(s): Kazuaki Ohara, Masaki Kawano, Yasuhide Inokuma, Makoto Fujita
  • Journal Title: Journal of the American Chemical Society 132 Pages: 30-31
  • Peer Reviewed
• [Journal Article] Regioselective Huisgen Cycloaddition within Porous Coordination Networks (2010)
  • Author(s): Takehide Kawamichi, Yasuhide Inokuma, Masaki Kawano, Makoto Fujita
  • Journal Title: Angewandte Chemie, International Edition 49 Pages: 2375-2377
  • Peer Reviewed
• [Presentation] Networked Cages and Capsules : Rich Host-Guest Chemistry in a Crystal (2010)
  • Author(s): Yasuhide Inokuma, Makoto Fujita
  • Organizer: PACIFICHEM 2010
  • Place of Presentation: ハワイ・ホノルル
  • Year and Date: 2010-12-16
• [Presentation] Networked Cages and Capsules : Rich Host-Guest Chemistry in a Crystal (2010)
  • Author(s): Yasuhide Inokuma, Makoto Fulita
  • Organizer: PACIFICHEM 2010
  • Place of Presentation: ハワイ・ホノルル(アメリカ)
  • Year and Date: 2010-12-16
• [Presentation] Synthesis and Guest Inclusion of Networked M_6L_4 Molecular Cages (2010)
  • Author(s): 猪熊泰英, Tatsuhiko Arai, Makoto Fujita
  • Organizer: 60th Anniversary Conference on Coordination Chemistry in OSAKA, JAPAN
  • Place of Presentation: 大阪国際交流センター
  • Year and Date: 2010-09-28
• [Presentation] Synthesis and Guest Inclusion of Networked M_6L_4 Molecular Cages (2010)
  • Author(s): Yasuhide Inokuma, Tatsuhiko Arai, Makoto Fujita
  • Organizer: 60th Anniversary Conference on Coordination Chemistry in OSAKA, JAPAN
  • Place of Presentation: 大阪国際交流センター(大阪府)
  • Year and Date: 2010-09-28
• [Presentation] M6L4ケージを無限配列した細孔性錯体(1):合成・構造・単結晶-単結晶ゲスト包接 (2010)
  • Author(s): 猪熊泰英、荒井達彦、藤田誠
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-26
• [Presentation] M6L4ケージを無限配列した細孔性錯体(1):合成・構造・単結晶-単結晶ゲスト包接 (2010)
  • Author(s): 猪熊泰英、荒井達彦、藤田誠
  • Organizer: 日本化学会 第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス
  • Year and Date: 2010-03-26
• [Remarks] ホームページ等
  • URL: http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/
• [Remarks]
  • URL: http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/
• [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法 (2010)
  • Inventor(s): 藤田誠、猪熊泰英、荒井達彦
  • Industrial Property Rights Holder: 国立大学法人東京大学
  • Filing Date: 2010-11-19
  • Overseas
• [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法 (2010)
  • Inventor(s): 荒井達彦, 猪熊泰英, 藤田誠
  • Industrial Property Rights Holder: 国立大学法人東京大学
  • Filing Date: 2010-11-19
  • Overseas
• [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法 (2009)
  • Inventor(s): 藤田誠、猪熊泰英、荒井達彦
  • Industrial Property Rights Holder: 国立大学法人東京大学
  • Industrial Property Number: 2009-265505
  • Filing Date: 2009-11-20
• [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法 (2009)
  • Inventor(s): 藤田誠, 猪熊泰英, 荒井達彦
  • Industrial Property Rights Holder: 国立大学法人 東京大学
  • Industrial Property Number: 2009-265505
  • Filing Date: 2009-11-20