Development of catalytic formation of molecular skeletons using cobalt oxide supported gold nanoparticles
Project/Area Number |
21850023
|
Research Category |
Grant-in-Aid for Research Activity Start-up
|
Allocation Type | Single-year Grants |
Research Field |
Organic chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
HAMASAKI Akiyuki Kyushu University, 大学院・理学研究院, 助教 (00515174)
|
Project Period (FY) |
2008 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥2,652,000 (Direct Cost: ¥2,040,000、Indirect Cost: ¥612,000)
Fiscal Year 2010: ¥1,274,000 (Direct Cost: ¥980,000、Indirect Cost: ¥294,000)
Fiscal Year 2009: ¥1,378,000 (Direct Cost: ¥1,060,000、Indirect Cost: ¥318,000)
|
Keywords | 酸化物担持金ナノ粒子 / コバルトカルボニル / ニコラス反応 / 代替触媒 / 金ナノ粒子 / 触媒反応化 / 不均一系触媒 |
Research Abstract |
Cobalt oxide supported gold nanoparticles have been revealed to effectively provide a cobalt active species under syngas (a mixture of carbon monoxide and hydrogen) atmosphere. This cobalt species could be used as an alternative reagent for the traditional cobalt carbonyls. The Pauson?Khand reaction, the alkoxycarbonylation, and the formation of cobalt complex with alkynes smoothly proceeded by using cobalt oxide supported gold nanoparticles.
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Report
(3 results)
Research Products
(15 results)