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MOFを出発物質として用いた固体スーパーキャパシタ用新規電極材料の創製

Research Project

Project/Area Number 21F20072
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Review Section Basic Section 26020:Inorganic materials and properties-related
Research InstitutionNational Institute for Materials Science

Principal Investigator

山内 悠輔  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (10455272)

Co-Investigator(Kenkyū-buntansha) LIU SHUDE  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
Project Period (FY) 2021-09-28 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2022: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2021: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsPorous materials / 多孔体
Outline of Research at the Start

This project aims to address several challenges to fundamentally understand how MOF-derived cobalt-M (M=Ni/Co/Cu) ternary metal oxides/carbon hybrids enhances the specific capacitance as supercapacitor electrodes. This study gains a fundamental understanding of the defect engineering on materials, and provide inspiration and insight into the development of next-generation supercapacitor materials.

Outline of Annual Research Achievements

Our research has focused on developing MOF-derived materials for energy storage and conversion applications with improved electrochemical performance. Through various synthesis methods, including direct carbonization, template-assisted synthesis, and chemical activation, we have prepared MOF-derived carbon-based materials with high specific surface area, pore volume, and conductivity, which are crucial factors for enhancing electrochemical performance in energy storage devices. For example, wevhave used a self-templating method to prepare hollow ordered mesoporous carbon (HOMC) materials with high N-doping, which have demonstrated superior electrochemical performance for supercapacitors. In addition, I have explored the potential of sulfides in energy storage and conversion, constructing a dual-modulated NiCo2O4@NiCo2S4 heterostructure and incorporating sulfur vacancies in CuCo2S4 hollow nanoarchitectures to achieve enhanced electrochemical performance. Furthermore, we have explored interfacial coupled engineering of plasmonic amorphous MoO3-x nanodots/g-C3N4 nanosheets for photocatalytic water splitting and photothermal conversion, developing highly active photocatalysts with excellent electrochemical performance. Overall, our research has demonstrated the great potential of MOF-derived materials, sulfides, and their heterostructures for energy storage and conversion applications, with publications in prestigious journals such as Energy Storage Materials, Carbon Energy, Advanced Energy Materials, and Small.

Research Progress Status

令和4年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和4年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (13 results)

All 2023 2022 2021

All Journal Article (13 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 13 results)

  • [Journal Article] Unveiling the effect of structural water on Zn-ion storage of polyoxovanadate for high-rate and long-life aqueous zinc ion battery2023

    • Author(s)
      He Huan、Pan Fu-Chun、Liang Xue-Wei、Hu Qiang、Liu Shude、Hu Jisong、Jun Seong Chan、Lin Dunmin、Yamauchi Yusuke、Huo Yu
    • Journal Title

      Chemical Engineering Journal

      Volume: 462 Pages: 142221-142221

    • DOI

      10.1016/j.cej.2023.142221

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interfacial coupled engineering of plasmonic amorphous MoO3-x nanodots/g-C3N4 nanosheets for photocatalytic water splitting and photothermal conversion2023

    • Author(s)
      Ren Yumei、Feng Desheng、Yan Zhiming、Sun Zixu、Zhang Zixuan、Xu Dongwei、Qiao Chong、Chen Zhonghui、Jia Yu、Chan Jun Seong、Liu Shude、Yamauchi Yusuke
    • Journal Title

      Chemical Engineering Journal

      Volume: 453 Pages: 139875-139875

    • DOI

      10.1016/j.cej.2022.139875

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sodium preintercalation-induced oxygen-deficient hydrated potassium manganese oxide for high-energy flexible Mg-ion supercapacitors2023

    • Author(s)
      Liu Shude、Kang Ling、Zhang Jian、Jun Seong Chan、Yamauchi Yusuke
    • Journal Title

      NPG Asia Materials

      Volume: 15 Issue: 1 Pages: 9-9

    • DOI

      10.1038/s41427-022-00450-z

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Covalently Interlayer‐Confined Organic-Inorganic Heterostructures for Aqueous Potassium Ion Supercapacitors2022

    • Author(s)
      Chen Jianping、Liu Bin、Cai Hang、Liu Shude、Yamauchi Yusuke、Jun Seong Chan
    • Journal Title

      Small

      Volume: 19 Issue: 4 Pages: 2204275-2204275

    • DOI

      10.1002/smll.202204275

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Boosting capacitive performance of manganese oxide nanorods by decorating with three-dimensional crushed graphene2022

    • Author(s)
      Reaz Akter Hossain、Saha Shimul、Roy Chanchal Kumar、Wahab Md Abdul、Will Geoffrey、Amin Mohammed A.、Yamauchi Yusuke、Liu Shude、Kaneti Yusuf Valentino、Hossain Md. Shahriar、Firoz Shakhawat H.
    • Journal Title

      Nano Convergence

      Volume: 9 Issue: 1

    • DOI

      10.1186/s40580-022-00300-2

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrathin nanosheet-assembled nickel-based metal-organic framework microflowers for supercapacitor applications2022

    • Author(s)
      Wang Cong-Huan、Zhang Da-Wei、Liu Shude、Yamauchi Yusuke、Zhang Fei-Bao、Kaneti Yusuf Valentino
    • Journal Title

      Chemical Communications

      Volume: 58 Issue: 7 Pages: 1009-1012

    • DOI

      10.1039/d1cc04880e

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic‐Level Platinum Filling into Ni‐Vacancies of Dual‐Deficient NiO for Boosting Electrocatalytic Hydrogen Evolution2022

    • Author(s)
      Yan Yaotian、Lin Jinghuang、Xu Tianxiong、Liu Baishen、Huang Keke、Qiao Liang、Liu Shude、Cao Jian、Jun Seong Chan、Yamauchi Yusuke、Qi Junlei
    • Journal Title

      Advanced Energy Materials

      Volume: ---- Issue: 24 Pages: 2200434-2200434

    • DOI

      10.1002/aenm.202200434

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Defect engineering induced heterostructure of Zn-birnessite@spinel ZnMn2O4 nanocrystal for flexible asymmetric supercapacitor2022

    • Author(s)
      Lyu Lulu、Kim Chae Won、Seong Kwang-dong、Kang Jeongmin、Liu Shude、Yamauchi Yusuke、Piao Yuanzhe
    • Journal Title

      Chemical Engineering Journal

      Volume: 430 Pages: 133115-133115

    • DOI

      10.1016/j.cej.2021.133115

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interfacial Assembled CeO2-x/Co@N-Doped Carbon Hollow Nanohybrids for High-Performance Lithium-Sulfur Batteries2021

    • Author(s)
      Qi Wentao、Yi Wencai、Jiang Wen、Ling Rui、Yang Chao、Liu Shude、Jun Seong Chan、Yamauchi Yusuke、Cao Bingqiang
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 9 Issue: 43 Pages: 14451-14460

    • DOI

      10.1021/acssuschemeng.1c04708

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Recent Advances and Perspectives of Battery-Type Anode Materials for Potassium Ion Storage2021

    • Author(s)
      Liu Shude、Kang Ling、Henzie Joel、Zhang Jian、Ha Jisang、Amin Mohammed A.、Hossain Md Shahriar A.、Jun Seong Chan、Yamauchi Yusuke
    • Journal Title

      ACS Nano

      Volume: 15 Issue: 12 Pages: 18931-18973

    • DOI

      10.1021/acsnano.1c08428

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Realizing Superior Redox Kinetics of Hollow Bimetallic Sulfide Nanoarchitectures by Defect‐Induced Manipulation toward Flexible Solid‐State Supercapacitors2021

    • Author(s)
      Liu Shude、Kang Ling、Hu Jisong、Jung Euigeol、Henzie Joel、Alowasheeir Azhar、Zhang Jian、Miao Ling、Yamauchi Yusuke、Jun Seong Chan
    • Journal Title

      Small

      Volume: 18 Issue: 5 Pages: 2104507-2104507

    • DOI

      10.1002/smll.202104507

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Carbonaceous Anode Materials for Non-aqueous Sodium- and Potassium-Ion Hybrid Capacitors2021

    • Author(s)
      Liu Shude、Kang Ling、Zhang Jian、Jun Seong Chan、Yamauchi Yusuke
    • Journal Title

      ACS Energy Letters

      Volume: 6 Issue: 11 Pages: 4127-4154

    • DOI

      10.1021/acsenergylett.1c01855

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Unlocking the Potential of Oxygen-Deficient Copper-Doped Co3O4 Nanocrystals Confined in Carbon as an Advanced Electrode for Flexible Solid-State Supercapacitors2021

    • Author(s)
      Liu Shude、Kang Ling、Hu Jisong、Jung Euigeol、Zhang Jian、Jun Seong Chan、Yamauchi Yusuke
    • Journal Title

      ACS Energy Letters

      Volume: 6 Issue: 9 Pages: 3011-3019

    • DOI

      10.1021/acsenergylett.1c01373

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research

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Published: 2021-10-22   Modified: 2024-03-26  

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