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Development of highly efficient catalytic systems based on structural control of manganese oxides by crystallization of precursors

Research Project

Project/Area Number 21H01713
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kamata Keigo  東京工業大学, 科学技術創成研究院, 教授 (40451801)

Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2023: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2022: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2021: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywords触媒 / マンガン酸化物 / 酸化反応 / 無機合成 / ナノ粒子 / メソポーラス / チャネル構造 / OMS-1 / 酸化 / ポーラス / マンガン / 酸化物
Outline of Research at the Start

本申請研究では、独自に開発した層状マンガン酸化物前駆体の低温での結晶化手法(前駆体結晶化法)に着目し、構造(結晶・チャネル・細孔)を制御したマンガン酸化物ナノ粒子触媒を合成する。優れた酸化力、隣接する酸塩基点との共同作用、特殊ナノ空間での反応促進を利用した、従来法で合成したマンガン酸化物では達成し得ない高難度あるいは新しい触媒反応系の開発を目的とする。

Outline of Final Research Achievements

In this research, we focused on the low-temperature solid-to-solid phase transition (denoted as " crystallization of precursor method") of low-crystallinity layered manganese oxide precursors to control the crystal, channel, and porous structures of manganese oxide nanoparticle catalysts. Mesoporous OMS-1 and β-type manganese dioxide nanoparticles were synthesized by controlling the synthesis conditions of the precursors, and we applied them to the aerobic oxidation of various substrates using only molecular oxygen as the oxidant through their excellent oxidizing power and synergistic effect with acid-base properties. We have successfully developed the aerobic oxidation of sulfides and the one-pot oxidative conversion of aromatic alcohols to the corresponding nitriles and amides.

Academic Significance and Societal Importance of the Research Achievements

本研究では、極めてシンプルな手法で新しい概念に基づく高活性な多機能マンガン酸化物触媒の合成と開発を達成した。これらは熱安定性の高い無機固体材料であるため、液相酸化反応だけでなく揮発性有機化合物の酸化浄化・電気化学的なエネルギー変換などの幅広い反応に対しても21世紀にふさわしい新しい省資源・省エネルギープロセスの一端を担うことが期待される。無機合成・有機合成と理論化学的アプローチとの融合により新触媒の創出が期待され、触媒設計の方法論を提供する点で学術的な波及効果も大きいと考えられる。

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (51 results)

All 2024 2023 2022 2021 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Open Access: 2 results) Presentation (36 results) (of which Int'l Joint Research: 5 results,  Invited: 7 results) Remarks (6 results)

  • [Int'l Joint Research] National Cheng Kung University/National Synchrotron Radiation Research(その他の国・地域(台湾))

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Acid and base catalysis of SrTiO3 nanoparticles for C-C bond-forming reactions2024

    • Author(s)
      Aihara Takeshi、Aoki Wataru、Hara Michikazu、Kamata Keigo
    • Journal Title

      Catalysis Today

      Volume: 428 Pages: 114448-114448

    • DOI

      10.1016/j.cattod.2023.114448

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanosized Ti-Based Perovskite Oxides as Acid-Base Bifunctional Catalysts for Cyanosilylation of Carbonyl Compounds2023

    • Author(s)
      Aihara Takeshi、Aoki Wataru、Kiyohara Shin、Kumagai Yu、Kamata Keigo、Hara Michikazu
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 15 Issue: 14 Pages: 17957-17968

    • DOI

      10.1021/acsami.3c01629

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bismuth phosphate nanoparticle catalyst for direct oxidation of methane into formaldehyde2023

    • Author(s)
      Matsuda Aoi、Obara Kazuhiko、Ishikawa Atsushi、Tsai Meng-Hsuan、Wang Chia-Hsin、Lin Yu-Chuan、Hara Michikazu、Kamata Keigo
    • Journal Title

      Catalysis Science & Technology

      Volume: 13 Issue: 18 Pages: 5180-5189

    • DOI

      10.1039/d3cy00590a

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and Aerobic Oxidation Catalysis of Mesoporous Todorokite-type Manganese Oxides Nanoparticles by Crystallization of Precursors2022

    • Author(s)
      Maki Koutani, Eri Hayashi, Keigo Kamata, Michikazu Hara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 31 Pages: 14090-14100

    • DOI

      10.1021/jacs.2c02308

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability enhancement of iron-based perovskite catalysts by A-site substituion for oxidative transposition of α-bromostyrene to phenacyl bromide2022

    • Author(s)
      Satomi Shibata, Keigo Kamata, Michikazu Hara
    • Journal Title

      ChemCatChem

      Volume: 14 Issue: 18

    • DOI

      10.1002/cctc.202200395

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] β-MnO2 nanoparticles as heterogenous catalysts for aerobic oxidative transformation of alcohols to carbonyl compounds, nitriles, and amides2022

    • Author(s)
      Keigo Kamata, Nanami Kinoshita, Maki Koutani, Ryusei Aono, Eri Hayashi, Michikazu Hara
    • Journal Title

      Catalysis Science & Technology

      Volume: 12 Issue: 20 Pages: 6219-6230

    • DOI

      10.1039/d2cy01476a

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Metal Oxide Catalysts for Organic Synthesis2022

    • Author(s)
      Kamata Keigo、Aihara Takeshi
    • Journal Title

      Crystalline Metal Oxide Catalysts for Organic Synthesis. In: Ueda, W. (eds)

      Volume: 8 Pages: 219-271

    • DOI

      10.1007/978-981-19-5013-1_8

    • ISBN
      9789811950124, 9789811950131
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Base-Assisted Aerobic C-H Oxidation of Alkylarenes with a Murdochite-Type Oxide Mg6MnO8 Nanoparticle Catalyst2022

    • Author(s)
      Hayashi Eri、Tamura Takatoshi、Aihara Takeshi、Kamata Keigo、Hara Michikazu
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 14 Issue: 5 Pages: 6528-6537

    • DOI

      10.1021/acsami.1c20080

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] SrTiO3ナノ粒子の酸塩基性質へのAサイト金属ドープ効果2024

    • Author(s)
      相原 健司,青木 航流,鎌田 慶吾
    • Organizer
      日本化学会 第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] Ruドープ六方晶型ペロブスカイト酸化物を触媒としたスルフィドの酸素酸化2024

    • Author(s)
      牧澤 昌史,和知 慶樹,相原 健司,鎌田 慶吾
    • Organizer
      日本化学会 第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホスホン酸を用いた担持リン酸鉄触媒によるメタンの選択酸化2024

    • Author(s)
      古谷 一眞,松田 蒼依,原 亨和,鎌田 慶吾
    • Organizer
      日本化学会 第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] リン酸銅触媒によるメタンからホルムアルデヒドの直接合成2024

    • Author(s)
      松田 蒼依,相原 健司,原 亨和,鎌田 慶吾
    • Organizer
      日本化学会 第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] Synthesis and Catalytic Application of Mesoporous Manganese Oxides2023

    • Author(s)
      Keigo Kamata
    • Organizer
      2023 Taiwan International Conference on Catalysis (TICC-2023) & The 40th Taiwan Symposium on Catalysis and Reaction Engineering 2023 (TSCRE-2023)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct Methane Oxidation to Formaldehyde by Metal Phosphate Nanoparticle Catalyst2023

    • Author(s)
      Aoi Matsuda, Kazuhiko Obara, Atsushi Ishikawa, Meng-Hsuan Tsai, Chia-Hsin Wang, Yu-Chuan Lin, Michikazu Hara, Keigo Kamata
    • Organizer
      2023 Taiwan International Conference on Catalysis (TICC-2023) & The 40th Taiwan Symposium on Catalysis and Reaction Engineering 2023 (TSCRE-2023)
    • Related Report
      2023 Annual Research Report
  • [Presentation] SrTiO3ナノ粒子の酸塩基性質とKnoevenagel縮合反応への応用2023

    • Author(s)
      青木航流,相原健司,原亨和,鎌田慶吾
    • Organizer
      第132回触媒討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホスホン酸を用いたリン酸鉄担持触媒によるメタンの直接酸化反応2023

    • Author(s)
      古谷一眞,松田蒼依,原亨和,鎌田慶吾
    • Organizer
      第132回触媒討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] リン酸銅触媒を用いたメタンからホルムアルデヒドの直接合成と反応機構解明2023

    • Author(s)
      松田蒼依, 相原健司, 原亨和, 鎌田慶吾
    • Organizer
      第132回触媒討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高原子価鉄を含むペロブスカイト酸化物触媒を用いた低級アルカンの液相酸化2023

    • Author(s)
      山本昌尚,相原健司,原亨和,鎌田慶吾
    • Organizer
      第132回触媒討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] リン酸ビスマスナノ粒子触媒によるメタンの直接酸化2023

    • Author(s)
      松田蒼依,小原和彦,石川敦之,Meng-Hsuan Tsai,Chia-Hsin Wang, Yu-Chuan Lin,原亨和,鎌田慶吾
    • Organizer
      第132回触媒討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 金属酸化物のナノ構造制御と触媒作用2023

    • Author(s)
      鎌田慶吾
    • Organizer
      さきがけ「革新的触媒の科学と創製」第1回領域研究会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Direct Oxidation of Methane into Formaldehyde over Bismuth Phosphate Nanoparticles2023

    • Author(s)
      Aoi Matsuda, Kazuhiko Obara, Atsuhi Ishikawa, Meng Hsuan Tsai, Chia Hsin Wang, Yu Chuan Lin, Michikazu Hara, Keigo Kamata
    • Organizer
      3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture-DEJlMA 2023-
    • Related Report
      2023 Annual Research Report
  • [Presentation] Synthesis of SrTiO3 nanoparticles and application for acid and base-catalyzed reactions2023

    • Author(s)
      Takeshi Aihara, Wataru Aoki, Keigo Kamata
    • Organizer
      3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture-DEJlMA 2023-
    • Related Report
      2023 Annual Research Report
  • [Presentation] 原子価を制御した鉄系ペロブスカイト型酸化物触媒による低級アルカンの液相酸化反応2023

    • Author(s)
      山本昌尚,相原健司,原亨和,鎌田慶吾
    • Organizer
      第13回 CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] リン酸ビスマス触媒によるメタンからホルムアルデヒドの直接合成と機構解明2023

    • Author(s)
      松田蒼依,小原和彦,石川敦之,Meng-Hsuan Tsai,Chia-Hsin Wang, Yu-Chuan Lin,原亨和,鎌田慶吾
    • Organizer
      第13回 CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] SrTiO3ナノ粒子を用いたKnoevenagel縮合と反応機構の検討2023

    • Author(s)
      青木航流,相原健司,原亨和,鎌田慶吾
    • Organizer
      第13回 CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホスホン酸を用いた担持リン酸鉄触媒によるメタンからホルムアルデヒドへの直接酸化反応2023

    • Author(s)
      古谷一眞,松田蒼依,原亨和,鎌田慶吾
    • Organizer
      第13回 CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Nano-structure Control and Catalytic Application of Metal Oxide Nanoparticles2023

    • Author(s)
      Keigo Kamata
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2023 (C&FC 2023)
    • Related Report
      2023 Annual Research Report
  • [Presentation] Design and development of high-performance catalysts based on nanostructure control of complex oxides2023

    • Author(s)
      Keigo Kamata
    • Organizer
      The 99th GREEN Seminar, NIMS
    • Related Report
      2023 Annual Research Report
  • [Presentation] リン酸ビスマスナノ粒子触媒によるメタンの直接酸化反応2023

    • Author(s)
      鎌田 慶吾
    • Organizer
      第2回出島コンソーシアムセミナー
    • Related Report
      2023 Annual Research Report
  • [Presentation] Design, Synthesis, and Unique Catalysis of Crystalline Metal Oxides2022

    • Author(s)
      Keigo Kamata
    • Organizer
      Taipei International Conference on Catalysis (TICC-2022)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Aerobic oxidation of alkenes with iron-containing perovskite oxide catalysts2022

    • Author(s)
      Keigo Kamata, Satomi Shibata, Michikazu Hara
    • Organizer
      9th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT9)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Direct methane oxidation to formaldehyde by iron phosphate nanoparticle catalyst2022

    • Author(s)
      Aoi Matsuda, Haruka Tateno, Keigo Kamata, Michikazu Hara
    • Organizer
      9th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT9)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 前駆体結晶化法によるメソポーラスOMS-1ナノ粒子の合成と酸化触媒作用2022

    • Author(s)
      鎌田慶吾,幸谷真芸,林愛理,原亨和
    • Organizer
      第130回触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 金属酸化物のナノ構造制御に基づいた高機能触媒の開発2022

    • Author(s)
      鎌田慶吾
    • Organizer
      JAIST 物質化学フロンティアシンポジウム 2022(北陸先端科学技術大学院大学)
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 複合金属酸化物のナノ構造制御に基づいた高機能触媒の設計と開発2022

    • Author(s)
      鎌田慶吾
    • Organizer
      新化学技術推進協会 エネルギー・資源技術部会 バイオマス分科会 勉強会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] ムルドカイト型酸化物Mg6MnO8ナノ粒子の合成と酸化触媒特性2022

    • Author(s)
      林愛理,田村高敏,相原健司,鎌田慶吾,原亨和
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 高表面積β-MnO2ナノ粒子触媒によるアルコールからのニトリル合成2022

    • Author(s)
      木下七海,青野竜征,林愛理,鎌田慶吾,原亨和
    • Organizer
      日本化学会第102春季年会(2022)
    • Related Report
      2021 Annual Research Report
  • [Presentation] 高表面積β-MnO2ナノ粒子触媒によるアルコールからのニトリル合成選択酸化2022

    • Author(s)
      木下七海,林愛理,鎌田慶吾,原亨和
    • Organizer
      第129回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] トドロカイト型マンガン酸化物ナノ粒子の合成と酸化触媒応用2022

    • Author(s)
      幸谷真芸,林愛理,鎌田慶吾,原亨和
    • Organizer
      第129回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Development of Crystalline Mixed Oxide Catalysts for Selective Oxidation Reactions2021

    • Author(s)
      K. Kamata
    • Organizer
      Asia Pacific Society for Materials Science (APSMR) 2021 Annual Meeting
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 複合酸化物の構造制御に基づいた酸化・酸塩基触媒反応系の開発2021

    • Author(s)
      鎌田 慶吾
    • Organizer
      触媒学会西日本支部 令和3年度触媒技術セミナー~今輝く触媒研究者を迎えて~
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] トドロカイト型マンガン酸化物ナノ粒子の合成と触媒作用2021

    • Author(s)
      幸谷 真芸,林 愛理,鎌田 慶吾,原 亨和
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] トドロカイト型マンガン酸化物ナノ粒子の合成と酸化触媒作用2021

    • Author(s)
      幸谷 真芸,林 愛理,鎌田 慶吾,原 亨和
    • Organizer
      第11回CSJ化学フェスタ2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis and catalytic application of mixed metal oxide nanoparticles2021

    • Author(s)
      鎌田慶吾
    • Organizer
      2021年度 ナノ構造・物性-ナノ機能・応用部会 合同シンポジウム
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Remarks] 東京工業大学 科学技術創成研究院 フロンティア材料研究所 鎌田研究室

    • URL

      https://www.msl.titech.ac.jp/~kamata/index.html

    • Related Report
      2023 Annual Research Report
  • [Remarks] トンネル構造をもつマンガン酸化物のナノ粒子触媒を合成(東工大ニュース)

    • URL

      https://www.titech.ac.jp/news/2022/064544

    • Related Report
      2022 Annual Research Report
  • [Remarks] トンネル構造をもつマンガン酸化物超微粒子触媒を合成(ケムステのスポットライトリサーチ)

    • URL

      https://www.chem-station.com/blog/2022/08/mnoxide.html

    • Related Report
      2022 Annual Research Report
  • [Remarks] 東京工業大学科学技術創成研究院フロンティア材料研究所鎌田研究室

    • URL

      https://www.msl.titech.ac.jp/~kamata/index.html

    • Related Report
      2022 Annual Research Report
  • [Remarks] 東京工業大学 科学技術創成研究院 フロンティア材料研究所 原・鎌田研究室

    • URL

      http://www.msl.titech.ac.jp/~hara/k_kamata.html

    • Related Report
      2021 Annual Research Report
  • [Remarks] 理想とされるC-H結合の直接酸化反応を低温・高効率で達成

    • URL

      https://www.titech.ac.jp/news/2022/062999

    • Related Report
      2021 Annual Research Report

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Published: 2021-04-28   Modified: 2025-01-30  

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