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Simultaneous utilization of vacant and filled orbitals of group 13 element compounds in low oxidation state: novel reaction and photoelectronic property

Research Project

Project/Area Number 21H01915
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 33010:Structural organic chemistry and physical organic chemistry-related
Research InstitutionNagoya University

Principal Investigator

Makoto YAMASHITA  名古屋大学, 工学研究科, 教授 (10376486)

Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2023: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2022: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2021: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Keywordsホウ素 / アルミニウム / 求核性 / アニオン / 金属間結合 / 三重項 / 3重項
Outline of Research at the Start

本研究では13族元素化合物の充填軌道および空軌道の位置およびエネルギー準位を精密に制御して、13族元素間単結合分子および13族元素アニオンの化学を展開することを目的とする。それぞれの研究項目において、複数軌道の同時制御を通した新反応を開拓すると共に、特異な電子状態の創出を行い、有機化合物の特性に対する元素の効果についての学理構築を目指す。

Outline of Final Research Achievements

In this study, we focused on “Control of Electronic States of Group 13 Single-Bonded Molecules with High Electron Acceptance and New Reactions”. As a result, we found (1) tetra(1-naphthyl)diborane could be synthesized and its emission in solution showed a maximum at much shorter wavelength than those of the previously reported tetra(o-tolyl)diborane, and (2) unsymmetrical dialumanes and trialumanes could be synthesized by using an originally developed Al anion reagent and it was found that they are easily reduced. In addition, we also focused on “Elucidation of the Reactivity of Diamino-Al Anions”. We demonstrated that Al atoms could be introduced to V and Sm center to form unprecedented V-Al and Sm-Al bonds which have never been reported. Their unique reactivity toward small molecules were also shown in this study.

Academic Significance and Societal Importance of the Research Achievements

本研究により得られた13族元素間単結合分子が示す高い反応性は、原子軌道である空軌道の重なりによりLUMOがその大きさをコンパクトに保ったままエネルギー準位が低下した結果であることを見いだしている。これは高反応性分子を設計するための新たな指針になると考えられる。また、Al-Sc, Al-V, Al-Sm分子は未踏の金属間結合を含んでおり、その電子状態に対する理解は合金の無機化学における理解に対しても一般化することが可能となる。このように、本研究はの成果は基礎化学的に重要であり、分子化学の根幹に対して大きく寄与すると言えよう。

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (73 results)

All 2024 2023 2022 2021 Other

All Int'l Joint Research (3 results) Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (58 results) (of which Int'l Joint Research: 22 results,  Invited: 25 results) Remarks (2 results)

  • [Int'l Joint Research] 香港科学技術大学(中国)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] 香港科学技術大学(中国)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] 香港科学技術大学(中国)

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C-H Alumanylation of Alkenes2024

    • Author(s)
      Zatsepin Pavel、Moriyama Takumi、Chen Chaoqi、Muratsugu Satoshi、Tada Mizuki、Yamashita Makoto
    • Journal Title

      Journal of the American Chemical Society

      Volume: 146 Issue: 5 Pages: 3492-3497

    • DOI

      10.1021/jacs.3c13418

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical properties of 1-Aza-2-boraacenaphthene synthesized by a reduction of base-stabilized aminodibromoborane2024

    • Author(s)
      Kumada Haruki、Nakano Ryo、Yamashita Makoto
    • Journal Title

      Chemistry Letters

      Volume: 53 Issue: 4

    • DOI

      10.1093/chemle/upae057

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Alumanyl-Samarium(II): Synthesis, Characterization, and Reactivity Studies2024

    • Author(s)
      Feng Genfeng、Chan Ka Lok、Lin Zhenyang、Yamashita Makoto
    • Journal Title

      Journal of the American Chemical Society

      Volume: 146 Issue: 11 Pages: 7204-7209

    • DOI

      10.1021/jacs.4c01193

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Mechanochemical Synthesis of Non‐Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species**2023

    • Author(s)
      Kurumada Satoshi、Yamanashi Ryotaro、Sugita Kengo、Kubota Koji、Ito Hajime、Ikemoto Satoru、Chen Chaoqi、Moriyama Takumi、Muratsugu Satoshi、Tada Mizuki、Koitaya Takanori、Ozaki Taisuke、Yamashita Makoto
    • Journal Title

      Chemistry A European Journal

      Volume: 30 Issue: 7

    • DOI

      10.1002/chem.202303073

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reactions of Tetra(o‐tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron‐Fused Hexazenes2023

    • Author(s)
      Yamamoto Masahiro、Chan Wing Chun、Lin Zhenyang、Yamashita Makoto
    • Journal Title

      Chemistry - A European Journal

      Volume: 29 Issue: 51

    • DOI

      10.1002/chem.202302027

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Alkali Chloride Adducts of Acyclic Acylaluminum: Synthesis, Structure, and Reactivity Studies2023

    • Author(s)
      Feng Genfeng、Yamashita Makoto
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 62 Issue: 30

    • DOI

      10.1002/anie.202306366

    • Related Report
      2023 Annual Research Report
  • [Journal Article] Al?Sc Bonded Complexes: Synthesis, Structure, and Reaction with Benzene in the Presence of Alkyl Halide2022

    • Author(s)
      Feng Genfeng、Chan Ka Lok、Lin Zhenyang、Yamashita Makoto
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 49 Pages: 22662-22668

    • DOI

      10.1021/jacs.2c09746

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Tetraorganyl-Alumaborane with An Al-B σ-Bond and Two Adjacent Lewis-Acidic Centers2022

    • Author(s)
      Kurumada Satoshi、Yamashita Makoto
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 10 Pages: 4327-4332

    • DOI

      10.1021/jacs.2c01580

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic study on the reaction of pinB-BMes2 with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent2021

    • Author(s)
      Wu Linlin、Kojima Chiemi、Lee Ka-Ho、Morisako Shogo、Lin Zhenyang、Yamashita Makoto
    • Journal Title

      Chemical Science

      Volume: 12 Issue: 28 Pages: 9806-9815

    • DOI

      10.1039/d1sc02863d

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Isomerization of a cis‐(2‐Borylalkenyl)Gold Complex via a Retro‐1,2‐Metalate Shift: Cleavage of a C-/C-Si Bond trans to a C-Au Bond2021

    • Author(s)
      Suzuki Akane、Wu Linlin、Lin Zhenyang、Yamashita Makoto
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 38 Pages: 21007-21013

    • DOI

      10.1002/anie.202108530

    • Related Report
      2021 Annual Research Report
  • [Presentation] Comparing and Contrasting Alumanyl Complexes of Early Transition Metals2024

    • Author(s)
      Pavel Zatsepin, Takumi Moriyama, Chaoqi Chen, Satoshi Muratsugu, Mizuki Tada, Makoto Yamashita
    • Organizer
      日本化学会第104春季年会
    • Related Report
      2023 Annual Research Report
  • [Presentation] テトラ(1-ナフチル)ジボラン(4)の合成と性質2024

    • Author(s)
      谷澤倫・山下誠
    • Organizer
      日本化学会第104春季年会
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホウ素架橋ヘキサゼン分子及びその誘導体の合成2024

    • Author(s)
      山本真洋・山下誠
    • Organizer
      日本化学会第104春季年会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 同一原子上に空軌道と電子対をもつ13族元素含有分子の研究2024

    • Author(s)
      山下誠
    • Organizer
      日本化学会第104春季年会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] Synthesis of linear trialumane and unsymmetrical dialumane using Al anion2024

    • Author(s)
      Ryotaro Yamanashi, Kanata Mizutani, Makoto Yamashita
    • Organizer
      日本化学会第104春季年会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Synthesis, Structure, and Properties of Aluminum-Early Metal Complexes2024

    • Author(s)
      Makoto Yamashita
    • Organizer
      13th Japan-China Joint Symposium on Metal Cluster Compounds
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of linear trialumane and unsymmetrical dialumane using Al anion2024

    • Author(s)
      Ryotaro Yamanashi, Kanata Mizutani, Makoto Yamashita
    • Organizer
      The 9th Asian Conference on Coordination Chemistry (ACCC9)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structure, and Properties of Aluminum-Early Metal Complexes2024

    • Author(s)
      Makoto Yamashita
    • Organizer
      The 9th Asian Conference on Coordination Chemistry (ACCC9)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 同一原子上に空軌道と電子対を持つ13族元素含有分子の特性2024

    • Author(s)
      山下誠
    • Organizer
      2023年度「化学生命の最前線2」
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 求核性Alアニオンを用いた低酸化数Al化学種の合成とXPSによる電子状態評価2024

    • Author(s)
      山梨 遼太朗・車田 怜史・水谷 奏太・杉田 健悟・伊藤 肇・久保田 浩司・唯 美津木・邨次 智・池本 悟・Chen Chaoqi・森山 拓海・小板谷 貴典・尾崎 泰助・山下 誠
    • Organizer
      学際統合物質科学研究機構(IRCCS)成果報告会・産学ワークショップ
    • Related Report
      2023 Annual Research Report
  • [Presentation] テトラ(1-ナフチル)ジボラン(4)の合成と性質2024

    • Author(s)
      谷澤倫・山下誠
    • Organizer
      学際統合物質科学研究機構(IRCCS)成果報告会・産学ワークショップ
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホウ素架橋ヘキサゼン分子及びその誘導体の合成2024

    • Author(s)
      山本真洋・山下誠
    • Organizer
      学際統合物質科学研究機構(IRCCS)成果報告会・産学ワークショップ
    • Related Report
      2023 Annual Research Report
  • [Presentation] Syntheses of Low Oxidation State Aluminums by reactions of nucleophilic Al anion and its XPS characterization2024

    • Author(s)
      山梨 遼太朗・車田 怜史・水谷 奏太・杉田 健悟・伊藤 肇・久保田 浩司・唯 美津木・邨次 智・池本 悟・Chen Chaoqi・森山 拓海・小板谷 貴典・尾崎 泰助・山下 誠
    • Organizer
      2023年度GTR成果報告会
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 13族元素_遷移金属間の新しい結合の創製とその性質の解明2024

    • Author(s)
      山下誠
    • Organizer
      第3回関東典型元素化学セミナー
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] テトラ(1-ナフチル)ジボラン(4)の合成と性質2023

    • Author(s)
      谷澤倫・山下誠
    • Organizer
      第2回量子制御生命研究会
    • Related Report
      2023 Annual Research Report
  • [Presentation] N,Oモノアニオン性二座配位子を有するハロボランの還元2023

    • Author(s)
      熊田春輝・中野遼・山下 誠
    • Organizer
      第2回量子制御生命研究会
    • Related Report
      2023 Annual Research Report
  • [Presentation] ホウ素架橋ヘキサゼン分子及びその誘導体の合成2023

    • Author(s)
      山本真洋・山下誠
    • Organizer
      第2回量子制御生命研究会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 求核的アルミニウムと求電子的アルミニウムの反応によるAl-Al結合の構築2023

    • Author(s)
      山梨 遼太朗・水谷 奏太・山下 誠
    • Organizer
      第2回量子制御生命研究会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 13族元素を含む新結合と新反応2023

    • Author(s)
      山下誠
    • Organizer
      令和5年度有機合成化学協会東海支部総合講演会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] ホウ素架橋ヘキサゼン分子及びその誘導体の合成2023

    • Author(s)
      山本真洋・山下誠
    • Organizer
      第1回 「高密度共役の科学」 若手会合宿
    • Related Report
      2023 Annual Research Report
  • [Presentation] 低酸化数アルミニウム化学種の合成とXPS測定による電子状態評価2023

    • Author(s)
      山梨 遼太朗・車田 怜史・水谷 奏太・杉田 健悟・伊藤 肇・久保田 浩司・唯 美津木・邨次 智・池本 悟・Chen Chaoqi・森山 拓海・小板谷 貴典・尾崎 泰助・山下 誠
    • Organizer
      第50回有機典型元素化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Transfer Dehydrogenation of Alkanes Using PXP-Pincer Catalyst (X = B, Al, C)2023

    • Author(s)
      Makoto Yamashita
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of linear oligoalumanes by reaction of nucleophilic and electrophilic aluminum species2023

    • Author(s)
      Ryotaro Yamanashi, Kanata Mizutani, Makoto Yamashita
    • Organizer
      2023 International IRCCS-ILR-IRTG Symposium on “New Horizons of Molecular Functions”
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of New Tetraaryldiborane(4)2023

    • Author(s)
      Rin Tanizawa, Makoto Yamashita
    • Organizer
      2023 International IRCCS-ILR-IRTG Symposium on “New Horizons of Molecular Functions”
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and derivatization of boron-bridged hexazene2023

    • Author(s)
      Masahiro Yamamoto, Makoto Yamashita
    • Organizer
      2023 International IRCCS-ILR-IRTG Symposium on “New Horizons of Molecular Functions”
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristic Reactions of Carbon-Substituted Diborane(4)s2023

    • Author(s)
      Makoto YAMASHITA
    • Organizer
      The XXIII International Conference on Organic Synthesis (23-ICOS)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 求核的アルミニウムと求電子的アルミニウムの反応によるAl-Al結合の構築2023

    • Author(s)
      山梨 遼太朗・水谷 奏太・山下 誠
    • Organizer
      第39回有機合成化学協会セミナー
    • Related Report
      2023 Annual Research Report
  • [Presentation] テトラ(1-ナフチル)ジボラン(4)の合成と性質2023

    • Author(s)
      谷澤倫・山下誠
    • Organizer
      第33回基礎有機化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] N,Oモノアニオン性二座配位子を有するハロボランの還元2023

    • Author(s)
      熊田春輝・中野遼・山下 誠
    • Organizer
      第33回基礎有機化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Chemistry of Aluminum-Early Transition Metal Complexes2023

    • Author(s)
      Makoto YAMASHITA
    • Organizer
      Achievements in Molecular Inorganic Chemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemistry of Unprecedented Intermetallic Bonds Including Group 13 Element2023

    • Author(s)
      Makoto YAMASHITA
    • Organizer
      Trilateral Japan-Canada-Germany symposium on smart molecules design and practical applications in chemical and biochemical process
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Properties of Carbon-Substituted Diborane(4)s2023

    • Author(s)
      Makoto YAMASHITA
    • Organizer
      The 17th International Meeting on Boron Chemistry (IMEBORON XVII)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Characterization of Alumanyl Complexes of Vanadium2023

    • Author(s)
      Pavel Zatsepin, Makoto Yamashita
    • Organizer
      日本化学会第103春季年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] テトラアリールジボラン(4)と有機アジドの反応によるB2N6二環式化合物の合成と蛍光特性2023

    • Author(s)
      山本真洋・山下誠
    • Organizer
      日本化学会第103春季年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Attempt on Mechanochemical Synthesis of Boryl Anions2023

    • Author(s)
      熊田春輝・中野遼・山下誠
    • Organizer
      学際統合物質科学研究機構(IRCCS) 成果報告会・産学ワークショップ
    • Related Report
      2022 Annual Research Report
  • [Presentation] テトラアリールジボラン(4)と有機アジドの反応によるB2N6二環式化合物の合成と蛍光特性2023

    • Author(s)
      山本真洋・山下誠
    • Organizer
      学際統合物質科学研究機構(IRCCS) 成果報告会・産学ワークショップ
    • Related Report
      2022 Annual Research Report
  • [Presentation] 非環状ハロアルマンの還元反応2022

    • Author(s)
      菅野由稀・山下誠
    • Organizer
      第49回有機典型元素化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] テトラアリールジボラン(4)と有機アジドの反応によるB2N6二環式化合物の合成と蛍光特性2022

    • Author(s)
      山本真洋・山下誠
    • Organizer
      第53回中部化学関係学協会支部連合秋季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] テトラアリールジボラン(4)と有機アジドの反応によるB2N6二環式化合物の合成と蛍光特性2022

    • Author(s)
      山本真洋・山下誠
    • Organizer
      第32回基礎有機化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Characteristic Reactivity of Tetraorganyl-diborane(4) and alumaborane2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      BORAM XVII (Boron in Americas)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemistry of Reactive Group 13 Element Compounds in Low Oxidation State: Diborane(4) and Al-centered anion2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      The 15th International Conference on Cutting-Edge Organic Chemistry in Asia
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemistry of Reactive Group 13 Element Compounds in Low Oxidation State: Diborane(4) and Al-centered anion2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      Workshop New Achievements in Molecular Main Group Element Chemistry"
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characteristic Reactivity of Group 13 Element Compounds: Diborane(4) and Al-Anion2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      29th International Conference on Organometallic Chemistry
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characteristic Features of Transition Metal Complexes Having Lewis Acidic Group 13 Element Ligand2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      8th Asian Conference on Coordination Chemistry
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 低酸化数13族元素化学種の示す特異な反応2022

    • Author(s)
      山下 誠
    • Organizer
      第56回有機反応若手の会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 結合性空軌道分子:13族元素と金属により発現する特異な反応と物性2022

    • Author(s)
      山下 誠
    • Organizer
      第49回オルガノメタリックセミナー
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Chemistry of Reactive Group 13 Element Compounds in Low Oxidation State: Diborane(4) and Al-centered anion2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      The 19th Korean-Japan Joint Symposium on Organometallic and Coordination Chemistry
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characteristic structure and reactivity of Al-anions and their derivatives2022

    • Author(s)
      Makoto Yamashita
    • Organizer
      2023 Harry Gray Award for Creative Work in Inorganic Chemistry by a Young Investigator: Symposium in Honor of Robert J. Gilliard, Jr. at ACS spring meeting 2023
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電子的安定化のないアルマボランの反応性2022

    • Author(s)
      車田怜史・山下誠
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis of an aluminum-scandium bonded compound from a newly-designed aluminum anion2022

    • Author(s)
      Genfeng Feng, Makoto Yamashita
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 電子的安定化のないアルマボランの合成および性質の解明2021

    • Author(s)
      車田怜史・山下誠
    • Organizer
      第52回中部化学関係学協会支部連合秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 低酸化数13族元素分子が持つ特異な結合・構造・反応性2021

    • Author(s)
      山下誠
    • Organizer
      第32回万有仙台シンポジウム
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Characteristic Reactivity of Group-13 Element Compounds in Low Oxidation State2021

    • Author(s)
      Makoto Yamashita
    • Organizer
      104th Canadian Chemistry Conference and Exhibition
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 低酸化数13族元素分子が持つ特異な結合・構造・反応性2021

    • Author(s)
      山下誠
    • Organizer
      日本セラミックス協会第34回秋季シンポジウム
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Isomerization of a cis-(2-Borylalkenyl)gold Complex via a 'Retro-1,2-Metalate Shift': Cleavage of C-C/C-Si Bond trans to C-Au Bond2021

    • Author(s)
      Makoto YAMASHITA, Akane SUZUKI, Linlin WU, Zhenyang LIN
    • Organizer
      錯体化学会第71回討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] cis-2-ボリルアルケニル金錯体のretro-1,2-metalate shiftによる異性化2021

    • Author(s)
      山下誠・鈴木あかね・Wu Linlin・Lin Zhenyang
    • Organizer
      第52回中部化学関係学協会支部連合秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis and property of reactive dialkylalumanyl anion2021

    • Author(s)
      Makoto Yamashita
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and property of inter-group 13-element bonds2021

    • Author(s)
      Makoto Yamashita
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 東京工業大学 山下・森本研究室

    • URL

      http://www.chemistry.titech.ac.jp/~oec/index.html

    • Related Report
      2023 Annual Research Report
  • [Remarks] 名古屋大学大学院工学研究科 有機・高分子化学専攻 有機元素化学研究室ウェブサイト

    • URL

      http://oec.chembio.nagoya-u.ac.jp/

    • Related Report
      2022 Annual Research Report 2021 Annual Research Report

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Published: 2021-04-28   Modified: 2025-01-30  

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