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New theory of electrode potential shift for innovative rechargeable batteries

Research Project

Project/Area Number 21H02039
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionOsaka University

Principal Investigator

Yamada Yuki  大阪大学, 産業科学研究所, 教授 (30598488)

Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2023: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2022: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2021: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywordsリチウムイオン電池 / 電解液 / エネルギー密度 / 電極電位 / イオン液体 / 電気化学 / 電位 / 電池
Outline of Research at the Start

次世代リチウムイオン電池における電解液の酸化・還元分解を抑制する“熱力学的”新戦略を確立する。電解液中におけるリチウムイオンの配位状態を適切に設計することで、次世代電極の反応電位を自在に制御し、従来必ず起こるとされていた電解液の酸化・還元分解を抑制する。これにより、従来の電解液設計戦略では達成不可能な高効率の可逆充放電を達成し、次世代リチウムイオン電池実現に向けた基盤技術を確立する。

Outline of Final Research Achievements

To achieve higher energy density of lithium-ion batteries using high-capacity negative electrodes or high-potential positive electrodes that operate outside the potential window of the electrode, it is necessary to suppress the reduction and oxidation of the electrolyte. In this work, we aimed to suppress the reduction and oxidation of the electrolyte by shifting the electrode potential through electrolyte design. As a result, we found the downshift of the electrode potential using a strongly coordinating anion in lithium salt and the upshift of electrode potential using ionic liquid electrolytes. We also demonstrated that the charge-discharge efficiency of a high-capacity negative electrodes increased with the upshift of the electrode potential in ionic liquid electrolytes.

Academic Significance and Societal Importance of the Research Achievements

本研究で見いだした電極電位の大幅なアップシフト・ダウンシフトを可能にする電解液設計は、リチウムイオン電池において正極・負極材料の選択肢を大きく拡大するものである。高電位正極や高容量負極の採用が可能となることで、高エネルギー密度のリチウムイオン電池の実現が期待される。それにより、リチウムイオン電池を搭載した電気自動車の航続距離は大きく拡大されることになる。

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (17 results)

All 2024 2023 2022 2021 Other

All Presentation (13 results) (of which Int'l Joint Research: 8 results,  Invited: 13 results) Remarks (4 results)

  • [Presentation] 二次電池革新に向けた電解液材料設計2024

    • Author(s)
      山田裕貴
    • Organizer
      第116回ニューフロンティア材料部会例会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] Concentrated electrolytes: underlying science and battery applications2023

    • Author(s)
      Yuki Yamada
    • Organizer
      9th Congress on Ionic Liquids (COIL-9)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Rational design of lithium-metal battery electrolytes based on electrode potentials2023

    • Author(s)
      Yuki Yamada
    • Organizer
      Battery International Symposium 2023 “Human Resources Development for the Battery Industry Strategy”
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Li+の化学ポテンシャルに着目した電解液設計2023

    • Author(s)
      山田裕貴
    • Organizer
      化学電池材料研究会 第50回講演会・夏の学校2023
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 電極電位シフトに着目した電解液設計2023

    • Author(s)
      山田裕貴
    • Organizer
      2023年電気化学会秋季大会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] LIBの長寿命化に向けた電解液設計2023

    • Author(s)
      山田裕貴
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] LIB電解液の研究開発と今後の展望2023

    • Author(s)
      山田裕貴
    • Organizer
      第16回国際二次電池展(バッテリージャパン)
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] Design of lithium metal battery electrolytes based on lithium-ion chemical potential2022

    • Author(s)
      Yuki Yamada
    • Organizer
      International Battery Association 2022 (IBA 2022)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Rational electrolyte design for lithium metal batteries2022

    • Author(s)
      Yuki Yamada
    • Organizer
      Asian Conference on Electrochemical Power Sources 11 (ACEPS 11)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fluorinated cyclic phosphate-based electrolytes for high-voltage and safe batteries2022

    • Author(s)
      Yuki Yamada
    • Organizer
      46th International Conference and Expo on Advanced Ceramics and Composites (ICACC2022)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrolyte design strategies to high-energy-density and safe batteries2021

    • Author(s)
      Yuki Yamada
    • Organizer
      International Battery Association 2021 (IBA 2021)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Concentrated liquid electrolytes: unique functions and battery applications2021

    • Author(s)
      Yuki Yamada
    • Organizer
      The 3rd International Symposium of 5-star Alliance, CEFMS-NCTU, RCAS-AS
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Designing electrolyte and interphase for high-voltage and safe batteries2021

    • Author(s)
      Yuki Yamada and Atsuo Yamada
    • Organizer
      14th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 14)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 山田研究室ウェブサイト

    • URL

      https://www.sanken.osaka-u.ac.jp/labs/eem/

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report 2021 Annual Research Report
  • [Remarks] researchmap

    • URL

      https://researchmap.jp/yuki_yamada

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report 2021 Annual Research Report
  • [Remarks] Google Scholar

    • URL

      https://scholar.google.co.jp/citations?hl=ja&user=c2e3ligAAAAJ&view_op=list_works

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report 2021 Annual Research Report
  • [Remarks] publons

    • URL

      https://publons.com/researcher/1686764/yuki-yamada/

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report 2021 Annual Research Report

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Published: 2021-04-28   Modified: 2025-01-30  

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