• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of basic science for highly efficient and selective photocatalytic water splitting

Research Project

Project/Area Number 21H02049
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionKobe University

Principal Investigator

Tachikawa Takashi  神戸大学, 分子フォトサイエンス研究センター, 教授 (20432437)

Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2023: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2022: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2021: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords光触媒 / 光水分解 / 過酸化水素 / 水素エネルギー / 太陽光利用 / 金属酸化物
Outline of Research at the Start

独自に開発した世界最高性能のメソ結晶光電極を用いて、高効率かつ高選択的な太陽光水分解を達成するための動作原理と材料設計指針を獲得する。特に、単一粒子レベルのオペランド顕微分光計測から、高効率電荷分離のための駆動力、光電流生成における極めて小さな活性化エネルギーの起源、水の酸化における酸素と過酸化水素の選択性を支配する局所構造と反応経路などを明らかにする。得られた知見を統合して、高効率かつ高選択的な水の酸化反応をつかさどる新しいサイエンスを見いだし、より高機能な光エネルギー変換系を合理設計するための知的基盤を提供する。

Outline of Final Research Achievements

To achieve a carbon neutral society, CO2-free hydrogen production using solar energy has gained attention. If chemical products with applications in the health and food industries could be produced at the same time as hydrogen through photocatalyst-mediated solar water-splitting, it would be possible to develop solar energy conversion systems with even greater added value. In this study, we demonstrate efficient and selective production of hydrogen peroxide using photoelectrodes prepared with metal-doped hematite mesocrystals under simulated sunlight illumination. The composite oxide cocatalyst formed via segregation of tin and titanium ions doped in hematite was found to be the key to improving the efficiency and selectivity of the surface oxidation reaction.

Academic Significance and Societal Importance of the Research Achievements

光触媒として有用なヘマタイトの表面を改質することで、これまでほとんど生成しなかった過酸化水素を高い効率と選択性で得ることに成功し、その要因の一端を明らかにした。今後は、光触媒電極の更なる高効率化や他の金属酸化物や反応系への応用展開、実用化を目指した太陽光水素・過酸化水素オンサイト製造システムの開発が期待される。

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • Research Products

    (38 results)

All 2024 2023 2022 2021

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 3 results) Presentation (30 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results) Book (1 results)

  • [Journal Article] Charge Trapping in Semiconductor Photocatalysts: A Time- and Space-Domain Perspective2024

    • Author(s)
      Xue Jiawei、Fujitsuka Mamoru、Tachikawa Takashi、Bao Jun、Majima Tetsuro
    • Journal Title

      Journal of the American Chemical Society

      Volume: 146 Issue: 13 Pages: 8787-8799

    • DOI

      10.1021/jacs.3c14757

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Intricate Reaction Pathways on CH3NH3PbI3 Photocatalysts in Aqueous Solution Unraveled by Single-Particle Spectroscopy2023

    • Author(s)
      Takeuchi Aito、Kumabe Yoshitaka、Tachikawa Takashi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 14 Issue: 10 Pages: 2565-2572

    • DOI

      10.1021/acs.jpclett.3c00350

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Size-Controlled Synthesis of Luminescent Few-Atom Silver Clusters via Electron Transfer in Isostructural Redox-Active Porous Ionic Crystals2023

    • Author(s)
      N. Haraguchi, N. Ogiwara, Y. Kumabe, S. Kikkawa, S. Yamazoe, T. Tachikawa*, S. Uchida*
    • Journal Title

      Small

      Volume: - Issue: 23 Pages: 2300743-2300743

    • DOI

      10.1002/smll.202300743

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] HNb3O8/g-C3N4 nanosheet composite membranes with two-dimensional heterostructured nanochannels achieve enhanced water permeance and photocatalytic activity2022

    • Author(s)
      Imoto Seiji、Nakagawa Keizo、Hu Chechia、Yoshioka Tomohisa、Shintani Takuji、Matsuoka Atsushi、Kamio Eiji、Tachikawa Takashi、Tsang Shik Chi Edman、Matsuyama Hideto
    • Journal Title

      Chemical Engineering Journal

      Volume: 442 Pages: 136254-136254

    • DOI

      10.1016/j.cej.2022.136254

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Extension of the mechanoresponsive luminescence shift via formation of a doped organic crystal2022

    • Author(s)
      Yoshida Ryohei、Tachikawa Takashi、Ito Suguru
    • Journal Title

      Chemical Communications

      Volume: 58 Issue: 48 Pages: 6781-6784

    • DOI

      10.1039/d2cc00741j

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tunable mechanochromic luminescence via surface protonation of pyridyl-substituted imidazole crystals2022

    • Author(s)
      Kubota Rikuto、Yuan Yanqiu、Yoshida Ryohei、Tachikawa Takashi、Ito Suguru
    • Journal Title

      Materials Advances

      Volume: 3 Issue: 14 Pages: 5826-5835

    • DOI

      10.1039/d2ma00256f

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Binary dopant segregation enables hematite-based heterostructures for highly efficient solar H2O2 synthesis2022

    • Author(s)
      Zhang Zhujun、Tsuchimochi Takashi、Ina Toshiaki、Kumabe Yoshitaka、Muto Shunsuke、Ohara Koji、Yamada Hiroki、Ten-no Seiichiro L.、Tachikawa Takashi
    • Journal Title

      Nature Communications

      Volume: 13 Issue: 1 Pages: 1499-1499

    • DOI

      10.1038/s41467-022-28944-y

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 太陽光水分解システムにおけるヘマタイト光電極性能の改善2024

    • Author(s)
      隈部 佳孝
    • Organizer
      日本化学会第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水への安定性を示すスズ系ハライドペロブスカイトの発光挙動2024

    • Author(s)
      田中 直純
    • Organizer
      日本化学会第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] 溶液内動的平衡状態における有機無機ペロブスカイトのその場観測2024

    • Author(s)
      竹内 愛斗
    • Organizer
      日本化学会第104春季年会(2024)
    • Related Report
      2023 Annual Research Report
  • [Presentation] 実験データの機械学習によるヘマタイト光電極の光触媒性能予測2024

    • Author(s)
      西村 拓真
    • Organizer
      第71回応用物理学会春季学術講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高選択的光過酸化水素生成に向けたヘマタイトメソ結晶光触媒の局所構造解析2023

    • Author(s)
      西村 拓真
    • Organizer
      第44回 光化学若手の会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水溶液系ペロブスカイトナノ粒子の単一粒子発光イメージング2023

    • Author(s)
      竹内 愛斗
    • Organizer
      第44回 光化学若手の会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水中におけるスズ系有機無機ペロブスカイトの発光観測2023

    • Author(s)
      田中 直純
    • Organizer
      第44回 光化学若手の会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水中におけるDMASnI3の発光挙動2023

    • Author(s)
      田中 直純
    • Organizer
      高知化学シンポジウム2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] プラスチック分解物の高効率・高選択的酸化に寄与する光触媒システムの構築2023

    • Author(s)
      村尾 智央
    • Organizer
      高知化学シンポジウム2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高効率光水素製造を目指したSrTiO3/TiO2光触媒の開発2023

    • Author(s)
      劉 詩宇
    • Organizer
      高知化学シンポジウム2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] ペロブスカイト光触媒における界面電荷移動速度と水素生成活性の相関2023

    • Author(s)
      竹内 愛斗
    • Organizer
      高知化学シンポジウム2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高選択的光過酸化水素生成に向けた異種金属ドープヘマタイトメソ結晶の局所構造解析2023

    • Author(s)
      西村 拓真
    • Organizer
      高知化学シンポジウム2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Fluctuated charge transfer of CH3NH3PbI3 in aqueous solution observed by single-particle spectroscopy2023

    • Author(s)
      Aito Takeuchi
    • Organizer
      The 31st International Conference on Photochemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanoscopic structure-property relationships of organolead halide perovskites2023

    • Author(s)
      Takashi Tachikawa
    • Organizer
      The 31st International Conference on Photochemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水溶液系で形成する有機無機ペロブスカイトの構造・発光特性のその場観測2023

    • Author(s)
      竹内 愛斗
    • Organizer
      2023年光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] プラスチック分解物の高効率・高選択的酸化に向けた光触媒システムの設計2023

    • Author(s)
      村尾 智央
    • Organizer
      2023年光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高選択的光過酸化水素生成に向けたヘマタイトメソ結晶の構造解析2023

    • Author(s)
      西村 拓真
    • Organizer
      2023年光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水浸条件下におけるスズ系有機無機ペロブスカイトの発光挙動2023

    • Author(s)
      田中 直純
    • Organizer
      2023年光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 低温アニールによるヘマタイト光電極の電荷再結合抑制2023

    • Author(s)
      隈部 佳孝
    • Organizer
      2023年光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 水溶液系における有機無機ペロブスカイトの単一粒子発光観測2023

    • Author(s)
      立川 貴士
    • Organizer
      第42回固体・表面光化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高効率・高選択的太陽光H2O2生成に向けたヘマタイトメソ結晶の局所構造解析2023

    • Author(s)
      西村拓真
    • Organizer
      日本化学会第103春季年会(2023)
    • Related Report
      2022 Annual Research Report
  • [Presentation] 単一粒子分光法による水溶液系CH3NH3PbI3ナノ粒子の発光観測2023

    • Author(s)
      竹内愛斗
    • Organizer
      日本化学会第103春季年会(2023)
    • Related Report
      2022 Annual Research Report
  • [Presentation] ヘマタイトメソ結晶光電極を用いた高効率・高選択的過酸化水素生成2022

    • Author(s)
      立川貴士
    • Organizer
      2022年光化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 太陽光水分解を目的としたヘマタイトメソ結晶光電極の最適化2022

    • Author(s)
      隈部佳孝
    • Organizer
      2022年光化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 高効率・高選択的なH2O2生成をもたらすヘマタイトメソ結晶光触媒の構造探索2022

    • Author(s)
      西村拓真
    • Organizer
      2022年光化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 水溶液系における有機無機ペロブスカイトの単一粒子発光2022

    • Author(s)
      竹内愛斗
    • Organizer
      2022年光化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 光機能性材料の単一粒子発光-電子顕微鏡複合解析2022

    • Author(s)
      立川貴士
    • Organizer
      第78回日本顕微鏡学会学術講演会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 単一粒子顕微分光で観る光エネルギー・物質変換2022

    • Author(s)
      立川貴士
    • Organizer
      界面科学コロキウム「光物質変換をささえる分光計測」
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] International Conference on Chemical and Environmental Sciences (ICCAES) 2022Hematite-based mesocrystals for photoelectrochemical solar fuel production2022

    • Author(s)
      立川貴士
    • Organizer
      International Conference on Chemical and Environmental Sciences (ICCAES) 2022
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of hematite mesocrystal-based photoanodes for solar fuel production2021

    • Author(s)
      Takashi Tachikawa
    • Organizer
      11th Asian Photochemistry Conference
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Conversion of Water and CO2 to Fuels using Solar Energy: Science, Technology and Materials2024

    • Author(s)
      Appu V. Raghu, Takashi Tachikawa
    • Total Pages
      416
    • Publisher
      John Wiley & Sons, Inc.
    • ISBN
      9781119600848
    • Related Report
      2023 Annual Research Report

URL: 

Published: 2021-04-28   Modified: 2025-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi