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Photo-plastic effect of zincblende semiconductor crystals and its relationship with quantum structures of dislocation cores

Research Project

Project/Area Number 21H04618
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionNagoya University

Principal Investigator

Matsunaga Katsuyuki  名古屋大学, 工学研究科, 教授 (20334310)

Project Period (FY) 2021-04-05 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥42,640,000 (Direct Cost: ¥32,800,000、Indirect Cost: ¥9,840,000)
Fiscal Year 2023: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2022: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2021: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Keywords転位 / 光照射 / 電子構造
Outline of Research at the Start

半導体やセラミックスに用いられる無機結晶は、強固な化学結合性故に、室温で強度は高いが脆い性質をもつとされてきた。しかし近年の硫化亜鉛(ZnS)結晶に関する研究により、周囲の光環境が結晶の機械的性質に大きな影響を与えていることが判明した。しかし、同現象がどのような結晶で発現するのかについては、未だ明らかになっていない。本研究では、ZnSと同じ閃亜鉛鉱構造を持つ化合物半導体結晶を対象とし、光硬化現象のメカニズムと重要因子を明らかにする。

Outline of Final Research Achievements

First-principles calculations and experimental mechanical tests were performed for II-VI group and III-V group compound semiconductors, in order to clarify a physical origin of their photo-plastic effect. It was found that glide-dislocation cores of II-VI group semiconductors have localized electrostatic fields and can interact with excess electrons and holes excited by external light. Moreover, the glide dislocations underwent atomic reconstruction at their cores due to excess carriers. Such reconstructed cores may result in reduced mobility of glide dislocations, which should result in hardening of the systems under external light. Experimental mechanical tests for ZnTe supported this argument. In contrast, glide dislocations in GaP were found to undergo structural transformation from reconstructed to unreconstructed structure in the presence of excess carriers. It can be expected that GaP crystals show softening under light illumination unlike II-VI group semiconductors.

Academic Significance and Societal Importance of the Research Achievements

硫化亜鉛単結晶は、通常の白色光下では数%の塑性歪みを示したのち急激な破壊を示す(光硬化現象)のに対し、暗室下では10倍以上の塑性歪みを示す。この申請者らの成果により、従来から脆いと考えられてきた無機結晶であっても、光環境を変えることで、機械的性質を大きく制御できる可能性が広がったといえる。本研究は、この現象の起源を電子・原子レベルで解明した。半導体やセラミックスの無機結晶は、その結晶構造および化学結合性により硬くて脆いと考えられてきた。その常識を覆す成果に対する基本原理を提示したという点で、学術的意義は大きいといえる。

Report

(5 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Comments on the Screening Results   Annual Research Report
  • Research Products

    (6 results)

All 2023 2022 2021

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (4 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Electronic and atomic structures of Shockley-partial dislocations in CdX (X = S, Se and Te)2023

    • Author(s)
      Hoshino Sena、Yokoi Tatsuya、Ogura Yu、Matsunaga Katsuyuki
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 131 Issue: 10 Pages: 613-620

    • DOI

      10.2109/jcersj2.23055

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2023-10-01
    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] DFT calculations of carrier-trapping effects on atomic structures of 30° partial dislocation cores in zincblende II-VI group zinc compounds2023

    • Author(s)
      S. Hoshino, Y. Oshima, T. Yokoi, A. Nakamura, K. Matssunaga
    • Journal Title

      Physical Review Materials

      Volume: 7 Issue: 1 Pages: 013603-013603

    • DOI

      10.1103/physrevmaterials.7.013603

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Presentation] GaPにおける転位コア量子構造に関するDFT計算2023

    • Author(s)
      星野聖奈, 小椋優, 横井達矢, 松永克志
    • Organizer
      日本金属学会 2023年秋期(第173回)講演大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Electronic and atomic structures of glide dislocations in inorganic semiconductors relevant to their light-illumination dependent mechanical behavior2023

    • Author(s)
      Katsuyuki Matsunaga
    • Organizer
      The 11th Pacific Rim International Conference on Advanced Materials and Processing (PRICM11)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 化合物半導体 ZnX(X = S, Se, Te)における転位コア再構成に関する DFT計算2022

    • Author(s)
      星野聖奈, 大島優, 横井達矢, 中村篤智, 松永克志
    • Organizer
      日本金属学会 2022年秋期(第171回)講演大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Electronic and atomic structures of crystal defect cores determining peculiar materials properties2021

    • Author(s)
      Katsuyuki Matsunaga
    • Organizer
      14th Pacific Rim Conference on Ceramic and Glass Technology
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2021-04-28   Modified: 2025-01-30  

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