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Direct measurement of the adsorption force and shear resistance of oxides in oil and elucidation of the wear mechanism under lubrication

Research Project

Project/Area Number 21K03831
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 18040:Machine elements and tribology-related
Research InstitutionUniversity of Fukui

Principal Investigator

Honda Tomomi  福井大学, 学術研究院工学系部門, 教授 (80251982)

Co-Investigator(Kenkyū-buntansha) 福島 啓悟  福井大学, 学術研究院工学系部門, 講師 (50725322)
Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2023: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2022: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2021: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsメンテナンストライボロジー / 油中酸化物 / 吸着力直接測定 / 吸着シミュレーション / 潤滑摩耗 / 吸着シミ ュレーション
Outline of Research at the Start

機械設備の故障を未然に防ぐためには,摩擦摩耗の起点となる潤滑油の劣化,特に酸化進行メカニズムと酸化した油分子の摩擦面への吸着メカニズムの解明が鍵となる.そこで本研究では,「潤滑油酸化劣化機構」,「酸化物吸着と潤滑摩耗機構」の二つの「学術的問い」に対して,実験・分析とシミュレーションの両視点から,科学的根拠とトライボ志向設計モデルを提示することを目的とする.

Outline of Final Research Achievements

Lubricating oil is deteriorates with use, it not only loses its functions but also causes breakdowns and malfunctions of machine and equipment. In particular, it is lubricating oil that has been oxidized forms insoluble and sticky polymerized products in the oil, which cause sticking and damage to sliding surfaces. In this study, lubricating oils that have been simulated oxidized were prepared, and the size of the adsorbate of the lubricating oil oxides to solid surfaces and the frictional properties of the adsorbate were investigated using an atomic force microscope. As a result, the adsorption force and amount of the sample oil with a higher degree of oxidation increased due to the increase or polymerization of the adsorbate on the sample surface. It was also clarified that the oxide adsorbed on the sample surface behaved like fatty acids up to a certain amount. Still an excessive increase in oxide resulted in a higher friction coefficient.

Academic Significance and Societal Importance of the Research Achievements

トライボロジーの研究分野において,油潤滑下での摩耗機構と摩耗の起点となる油の酸化との因果関係について,その根源まで遡ることによるメカニズムの解明は行われてこなかった.また,機械設備の故障を未然に防ぐためには,摩擦摩耗の起点となる潤滑油の劣化,特に酸化進行メカニズムと酸化した油分子の摩擦面への吸着メカニズムの解明が鍵となる.これに対して,油の酸化物が固体表面に付着するメカニズムやその付着力およびせん断強度が摩擦抵抗の増大や摩耗に及ぼす影響を提示できた.さらに,分子動力学シミュレーションを用いて粘性係数の解析を行い,分子の極性の有無による比較を行い,摩擦・力学的特性の評価を行えることを示した.

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • Research Products

    (3 results)

All 2024 2022

All Presentation (3 results)

  • [Presentation] 油圧作動油の酸化が油潤滑下でのトライボロジー特性に及ぼす影響2024

    • Author(s)
      本野 侑哉,本田 知己,今 智彦
    • Organizer
      日本機械学会北陸信越支部 2024年合同講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 油中酸化物の吸着カ・せん断抵抗の直接測定2022

    • Author(s)
      南立光一,本田知己,今智彦
    • Organizer
      第20 回 評価・診断に関するシンポジウム
    • Related Report
      2022 Research-status Report
  • [Presentation] 無灰摩擦調整剤の吸着および摩擦特性2022

    • Author(s)
      内藤雅之,本田知己,成田恵一
    • Organizer
      第21回機素潤滑設計部門講演会(MDT2022)
    • Related Report
      2022 Research-status Report

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Published: 2021-04-28   Modified: 2025-01-30  

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