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Electrodeposition and Characterization of Atomic-Level Metal Clusters

Research Project

Project/Area Number 21K04827
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Chang Tso-Fu Mark  東京工業大学, 科学技術創成研究院, 准教授 (10647069)

Co-Investigator(Kenkyū-buntansha) 曽根 正人  東京工業大学, 科学技術創成研究院, 教授 (30323752)
Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2023: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2022: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2021: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
KeywordsElectrodeposition / Atomic metal / Conductive polymer / Catalyst / Biosensor / Atomic Metal / Conductive Polymer
Outline of Research at the Start

The main purpose in this research is atomic-level manipulation of metal clusters. The manipulation includes number, composition, structure and sequence of the atoms in a cluster. 3. In order to achieve this, a novel and original cyclic atomic electrodeposition process allowing deposition of metal
atoms one-by-one at a specific location has been developed to allow preparation of the atomic-level metal clusters. In addition, evaluating and clarifying the atomic-level metal clusters’ extraordinary properties, especially the even-odd effect, is another purpose in my research.

Outline of Final Research Achievements

The objective of this 3-year project is to develop novel catalytic materials for biosensors through the decoration of atomic-level metal clusters onto conjugated polymers using a unique cyclic atomic electrodeposition technique. The accomplishments include 7 peer-reviewed papers, presentations at 12 international conferences, and 4 domestic conferences. Of the 7 published papers, 6 are open access publications. Additionally, one of the conference presentations was delivered as an invited talk at an international conference.

The research commenced with the optimization of the original cyclic atomic electrodeposition technique, followed by the preparation and study of atomic pure metal clusters (such as Au, Pd, and Pt) on polyaniline. In the last fiscal year, the research progressed to the deposition of atomic Pd-Au alloy clusters, with the results already published in a peer-reviewed scientific paper.

Academic Significance and Societal Importance of the Research Achievements

Catalytic materials are expected to be a key solution for achieving the Sustainable Development Goals (SDGs). It is anticipated that performance will be enhanced through size reduction. Therefore, the atomic-level catalysts developed in this project will make a significant contribution to the SDGs.

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • Research Products

    (32 results)

All 2024 2023 2022 2021 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 9 results,  Open Access: 7 results) Presentation (21 results) (of which Int'l Joint Research: 15 results,  Invited: 1 results) Remarks (1 results)

  • [Int'l Joint Research] National Yang Ming Chiao Tung University(その他の国・地域)

    • Related Report
      2021 Research-status Report
  • [Journal Article] Decoration of atomic PdxAuy (1<=x+y<=4) on polyaniline in electrochemical sensing of 1-propanol2024

    • Author(s)
      Yoshida Shohei、Okamoto Keisuke、Kurioka Tomoyuki、Chen Chun-Yi、Chakraborty Parthojit、Lin Yi-Feng、Hsu Yung-Jung、Nakamoto Takamichi、Sone Masato、Chang Tso-Fu Mark
    • Journal Title

      Surface and Coatings Technology

      Volume: 483 Pages: 130762-130762

    • DOI

      10.1016/j.surfcoat.2024.130762

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] New Trend of Amperometric Gas Sensors Using Atomic Gold-Decorated Platinum/Polyaniline Composites2024

    • Author(s)
      Faricha Anifatul、Chakraborty Parthojit、Chang Tso-Fu Mark、Sone Masato、Nakamoto Takamichi
    • Journal Title

      Chemosensors

      Volume: 12 Issue: 2 Pages: 27-27

    • DOI

      10.3390/chemosensors12020027

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Array of Miniaturized Amperometric Gas Sensors Using Atomic Gold Decorated Pt/PANI Electrodes in Room Temperature Ionic Liquid Films2023

    • Author(s)
      Faricha Anifatul、Yoshida Shohei、Chakraborty Parthojit、Okamoto Keisuke、Chang Tso-Fu Mark、Sone Masato、Nakamoto Takamichi
    • Journal Title

      Sensors

      Volume: 23 Issue: 8 Pages: 4132-4132

    • DOI

      10.3390/s23084132

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gold/MnO2 particles decorated on electrodeposited polyaniline toward non-enzymatic electrochemical sensor for glucose2023

    • Author(s)
      Okamoto Keisuke、Kawakami Hiroki、Chien Yu-An、Kurioka Tomoyuki、Chiu Wan-Ting、Chakraborty Parthojit、Nakamoto Takamichi、Hsu Yung-Jung、Sone Masato、Chang Tso-Fu Mark
    • Journal Title

      Micro and Nano Engineering

      Volume: 18 Pages: 100175-100175

    • DOI

      10.1016/j.mne.2023.100175

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Toward Planar Atomic-Gold Decorated Polyaniline Gas Sensors for Enhanced Electrochemical Sensing2023

    • Author(s)
      Chakraborty Parthojit、Faricha Anifatul、Okamoto Keisuke、Kawakami Hiroki、Chang Tso-Fu Mark、Sone Masato、Nakamoto Takamichi
    • Journal Title

      IEEE Sensors Journal

      Volume: 23 Issue: 7 Pages: 6481-6488

    • DOI

      10.1109/jsen.2023.3242318

    • Related Report
      2023 Annual Research Report 2022 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microgravimetric and Amperometric Sensor Coated With Room Temperature Ionic Liquid to Enhance Butanol Isomers Gas Separation2022

    • Author(s)
      Faricha Anifatul、Chakraborty Parthojit、Okamoto Keisuke、Chang Tso-Fu Mark、Sone Masato、Nakamoto Takamichi
    • Journal Title

      IEEE Sensors Journal

      Volume: 22 Issue: 24 Pages: 24471-24478

    • DOI

      10.1109/jsen.2022.3221114

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Supercritical carbon dioxide assisted co-electrodeposition of nickel-titanium dioxide composite film and the dispersity2022

    • Author(s)
      Chien Yu-An、Chen Chun-Yi、Sone Masato、Chang Tso-Fu Mark
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 181 Pages: 105495-105495

    • DOI

      10.1016/j.supflu.2021.105495

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of polypyrrole/nano-gold composite for non-enzymatic glucose sensors2022

    • Author(s)
      Kawakami Hiroki、Ito Yuki、Chien Yu-An、Chen Chun-Yi、Chiu Wan-Ting、Chakraborty Parthojit、Nakamoto Takamichi、Sone Masato、Chang Tso-Fu Mark
    • Journal Title

      Micro and Nano Engineering

      Volume: 14 Pages: 100109-100109

    • DOI

      10.1016/j.mne.2022.100109

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sample size effect in Ni-TiO2 composites fabricated by supercritical CO2 emulsified CO-electroplating for miniaturized device2022

    • Author(s)
      Chien Yu-An、Chen Chun-Yi、Sone Masato、Chang Tso-Fu Mark
    • Journal Title

      Micro and Nano Engineering

      Volume: 15 Pages: 100135-100135

    • DOI

      10.1016/j.mne.2022.100135

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 有機化合物センシンングに対する原子レベル白金クラスターの触媒活性2024

    • Author(s)
      渡邉 賢吾, 吉田 祥平, 栗岡 智行, Chun-Yi Chen, Parthojit Chakraborty, Tso-Fu Mark Chang, 中本 高道, 曽根 正人
    • Organizer
      第71回応用物理学会春季学術講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Design of Electrodeposited Materials for MEMS Sensors2023

    • Author(s)
      Tso-Fu Mark Chang, Tomoyuki Kurioka, Chun-Yi Chen, Xun Luo, Daisuke Yamane, Hwai En Lin, Masato Sone
    • Organizer
      The 2023 International Conference on Green Electrochemical Technologies & The 2023 Annual Meeting of Electrochemical Society of Taiwan
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Catalytic Activity of Heterogeneous Atomic Metal Clusters Decorated Polyaniline for Electrochemical Oxidation of 1-Propanol,2023

    • Author(s)
      Shohei Yoshida, Tomoyuki Kurioka, Chun-Yi Chen, Parthojit Chakraborty, Yung-Jung Hsu, Takamichi Nakamoto, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      Taiwan Association for Coating and Thin Film Technology (TACT2023)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic Activity of Atomic Metals Clusters Decorated Polyaniline Electrodes in Electrochemical Oxidation of 1-Propanol2023

    • Author(s)
      Shohei Yoshida, Keisuke Okamoto, Tomoyuki Kurioka, Chun-Yi Chen, Parthojit Chakraborty, Takamichi Nakamoto, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      244th ECS Meeting
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Atomic Gold Decorated Polyaniline Derivative Electrodes toward Electrochemical Alcohol Sensing2023

    • Author(s)
      Tomoyuki Kurioka, Keisuke Okamoto, Shohei Yoshida, Kengo Watanabe, Chun Yi Chen, Parthojit CHAKRABORTY, TAKAMICHI NAKAMOTO, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      49th international conference on Micro and Nano Engineering (MNE2023)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic PdxAuy Clusters Decorated Polyaniline for Electrochemical Sensing of 1-Propanol2023

    • Author(s)
      Shohei Yoshida, Keisuke Okamoto, Tomoyuki Kurioka, Chun-Yi Chen, Parthojit Chakraborty, Takamichi Nakamoto, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      49th international conference on Micro and Nano Engineering (MNE2023)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Gold Decorated Polyaniline toward Glucose Oxidation2023

    • Author(s)
      Tso-fu Mark Chang, Keisuke Okamoto, Tomoyuki Kurioka, Chun-Yi Chen, Wan-Ting Chiu, Parthojit Chakraborty, Takamichi Nakamoto, Masato Sone
    • Organizer
      Euroanalysis XXI,
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Gas Sensor Array System Using Microgravimetric and Amperometric Sensors Coated with Room Temperature Ionic Liquid to Enhance Isomers Separation2023

    • Author(s)
      Faricha Anifatul, Parthojit CHAKRABORTY, Tso-Fu Mark Chang, Masato Sone, TAKAMICHI NAKAMOTO
    • Organizer
      Advances in Functional Materials (AFM) 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリアニリンと貴金属原子の複合電極の開発と1-プロパノールの電解酸化に対する触媒活性評価2023

    • Author(s)
      吉田 祥平, 岡本 奎祐, 栗岡 智行, Chun-Yi Chen Parthojit Chakraborty, Tso-Fu Mark Chang, 中本 高道, 曽根 正人
    • Organizer
      第70回応用物理学会春季学術講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Functionalization of Polyethylene Terephthalate Fabrics with Au@Cu2O Core@Shell Nanocrystals for Environmental Purifications2023

    • Author(s)
      Jhen-Yang Wu, Tomoyuki Kurioka, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang, Yung-Jung Hsu
    • Organizer
      第70回応用物理学会春季学術講演会
    • Related Report
      2022 Research-status Report
  • [Presentation] Development of Au nanoparticles-MnO2 modified polyaniline electorode for Non-Enzymatic Glucose Sensors2022

    • Author(s)
      Keisuke Okamoto, Hiroki Kawakami, Yu-An Chien, Tomoyuki Kurioka, Wan-Ting Chiu, Parthojit Chakraborty, Takamichi Nakamoto, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      48th international conference on Micro and Nano Engineering - Eurosensors (MNE-ES)
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] アスコルビン酸センサのためのポリアニリン・原&#12070;&#12198;電極の開発2022

    • Author(s)
      岡本 奎祐, 川上 宙輝, CHIENYu-An, Pathojit Chakraborty, 中本&#12220;道, 曽根正&#12040;, Tso-Fu Mark Chang
    • Organizer
      2022年応物理学会春季講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] Fabrication and Characterization of Ultrahigh Strength Ni-TiO2 Composite Coatings Electroplated with Supercritical Carbon Dioxide Emulsified Electrolyte2022

    • Author(s)
      Yu-an Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      2022年応物理学会春季講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] 非酵素型グルコースセンサーに向けたポリピロール・金ナノ粒子触媒電極の開発2021

    • Author(s)
      川上 宙輝, 伊藤 勇毅, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, 中本 高道, 曽根 正人
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] Non-enzymatic Polypyrrole/Nano-Gold Composite Electrode for Glucose Oxidation2021

    • Author(s)
      Hiroki Kawakami, Yuki Ito, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, Takamichi Nakamoto, Masato Sone
    • Organizer
      TACT2021 International Thin Films Conference
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Polyaniline-Atomic Au Modified Platinum Electrode with Ionic Liquid As Configuration for Enhanced Electrochemical Sensing2021

    • Author(s)
      Parthojit Chakraborty, Hiroki Kawakami, Tso-Fu Mark Chang, Masato Sone, Takamichi Nakamoto
    • Organizer
      IEEE Sensors 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Polypyrrole/Gold Nanoparticle Composite Electrode for Electrochemical Sensor2021

    • Author(s)
      Hiroki Kawakami, Yuki Ito, Yu-An Chien, Wan-Ting Chiu, Parthojit Chakraborty, Chun-Yi Chen, Tso-Fu Mark Chang, Takamichi Nakamoto, Masato Sone
    • Organizer
      Micro and Nano Engineering Conference 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electro-co-deposition of Au-TiO2 Composites with Improved Mechanical Property toward Miniaturized Electronics2021

    • Author(s)
      Yu-An Chien, Tso-Fu Mark Chang, Chun-Yi Chen, Daisuke Yamane, Hiroyuki Ito, Katsuyuki Machida, Kazuya Masu, Masato Sone
    • Organizer
      The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem 2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Supercritical Carbon Dioxide Assisted Co-Electrodeposition of TiO2 Nanoparticle Reinforced Ni Films2021

    • Author(s)
      Yu-An Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      30th Topical Meeting of the International Society of Electrochemistry
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Nanoparticle Reinforced High Strength Ni-TiO2 Composite Film Electroplated by Supercritical Carbon Dioxide Assisted Method2021

    • Author(s)
      Yu-An Chien, Chun-Yi Chen, Masato Sone, Tso-Fu Mark Chang
    • Organizer
      TACT2021 International Thin Films Conference
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Co-Electrodeposition of TiO2 Nanoparticle Reinforced High Strength Ni Film Assisted by Supercritical Carbon Dioxide for Miniaturized Electronics2021

    • Author(s)
      Yu-An Chien, Chun-Yi Chen, Tso-Fu Mark Chang, Masato Sone
    • Organizer
      Micro and Nano Engineering Conference 2021 (MNE2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Remarks] Tokyo Tech Research Repository

    • URL

      https://t2r2.star.titech.ac.jp/cgi-bin/researcherpublicationlist.cgi?q_researcher_content_number=CTT100592953

    • Related Report
      2022 Research-status Report

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Published: 2021-04-28   Modified: 2025-01-30  

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