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Functionalized-graphene sensor on the hydrophobic surface for the selective detection of ppb-level volatile organic compounds (VOCs)

Research Project

Project/Area Number 21K14510
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 28050:Nano/micro-systems-related
Research InstitutionThe University of Tokyo (2022-2023)
Japan Advanced Institute of Science and Technology (2021)

Principal Investigator

RAMARAJ SankarGanesh  東京大学, 大学院工学系研究科(工学部), 特任研究員 (20896295)

Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2023: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2022: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2021: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
KeywordsGraphene / Health care / Acetone / Ethanol / SAW sensor / Zeolite / Activated carbon / Gas sensor / Hydrophobic / Volatile gas molecules / Nanosensor
Outline of Research at the Start

The research aims to (1) demonstrate the novel method to reduce the adsorption of oxygen and water molecules on graphene nanoribbon field-effect transistor (GNR-FET) with fluoropolymer GNR (FGNR) as a dielectric and hydrophobic layer, (2) detect multiple volatile organic compounds (VOC) with 1 ppt sensitive and selective detection of individual VOC gas molecules.

Outline of Final Research Achievements

We have successfully functionalized metal nanoparticles and activated carbon molecular sieve on the surface of graphene nanoribbon FET with a size of 200 x 200 nm. 50 ppb concentration of Ethanol gas molecules was detected under 150°C using activated carbon molecular sieve functionalized graphene FET. In addition, Aluminum nanoparticles functionalized graphene showed exceptional sensitivity and selectivity towards ammonia gas molecules at real-time atmosphere. Furthermore, We have performed surface acoustic wave technique to detect even lower concentrations of acetone gas molecules. Graphene based surface acoustic wave gas sensor exhibited an enhanced gas response towards acetone gas molecules (800 ppt) under a real atmosphere.

Academic Significance and Societal Importance of the Research Achievements

Scientific and social significance of your research achievements
We have achieved the detection of acetone molecules at parts per trillion at room temperature. Our device can be utilized to detect disease at an early stage in human beings and provide a healthy life to everyone.

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • Research Products

    (29 results)

All 2024 2023 2022 2021 Other

All Journal Article (16 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 16 results,  Open Access: 4 results) Presentation (12 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] Synergistic Fabrication, Characterization, and Prospective Optoelectronic Applications of DES grafted Activated Charcoal Dispersed PVA Films2024

    • Author(s)
      Lokesh Kumar S, Binish C J, J.Rajprasad, Sumaiya Tabassum, Vivekananthan Sadaiyandi, Sankar Ganesh Ramaraj, Mohammad Ahmad Wadaan, Nikolai Ivanovich Vatin, Santhosh Govindaraju, Vijayasankar A V
    • Journal Title

      Wiley Polymer for Advanced

      Volume: -

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Real-time detection of acetone gas molecules at ppt levels in an air atmosphere using a partially suspended graphene surface acoustic wave skin gas sensor2023

    • Author(s)
      Zhou Haolong、Ramaraj Sankar Ganesh、Ma Kaijie、Sarker Md Shamim、Liao Zhiqiang、Tang Siyi、Yamahara Hiroyasu、Tabata Hitoshi
    • Journal Title

      Nanoscale Advances

      Volume: 5 Issue: 24 Pages: 6999-7008

    • DOI

      10.1039/d3na00914a

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thorn-like morphology of TiO2 hierarchical structures for efficient dye-sensitized solar cell application2023

    • Author(s)
      Arthi G.、Selvam Rajiv、Muthamizhchelvan C.、Hayakawa Y.、Ganesh Ramaraj Sankar
    • Journal Title

      Materials Letters

      Volume: 347 Pages: 134654-134654

    • DOI

      10.1016/j.matlet.2023.134654

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] First-Principles Calculations to Investigate the Structural, Electronic, Optical, and Elastic Constants; Thermal Conductivity; Raman Scattering; Mulliken Population; and XPS Loss Features of Boron Nitride Polytypes2023

    • Author(s)
      Zhang Zhongyong、Jiao Yongjie、S. K. S Saravana Karthikeyan、Ramaraj Sankar Ganesh、Zhang Fuchun、Nguyen Dang Nam、Qin Xuesong、Liu Xinghui
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 127 Issue: 34 Pages: 17213-17230

    • DOI

      10.1021/acs.jpcc.3c04086

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] First-Principles Calculations to Investigate Coupling Fe Doping with Oxygen Vacancies in Stannic Oxide and Their Physical Properties2023

    • Author(s)
      Ramaraj Sankar Ganesh、SKS Saravana Karthikeyan、Zhang Fuchun、Liu Xinghui、Kong Chang Yi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 127 Issue: 27 Pages: 13414-13427

    • DOI

      10.1021/acs.jpcc.3c03627

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural, electronic, optical, elastic, thermodynamic and thermal transport properties of Cs<sub>2</sub>AgInCl<sub>6</sub> and Cs<sub>2</sub>AgSbCl<sub>6</sub> double perovskite semiconductors using a first-principles study2023

    • Author(s)
      Zhang Keqing、Zhang Lijun、Saravana Karthikeyan S. K. S.、Kong Chang Yi、Zhang Fuchun、Guo Xiang、Dang Nam Nguyen、Ramaraj Sankar Ganesh、Liu Xinghui
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 25 Issue: 46 Pages: 31848-31868

    • DOI

      10.1039/d3cp03795a

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Electronic, elastic properties and thermal conductivity of the major clinker phases of portland cement: Insights from first-principles calculations2023

    • Author(s)
      Ramaraj Sankar Ganesh、SKS Saravana Karthikeyan、zhang Fuchun、Liu Xinghui、Kong Chang YI
    • Journal Title

      Vacuum

      Volume: 215 Pages: 112340-112340

    • DOI

      10.1016/j.vacuum.2023.112340

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Cost‐effective dye‐sensitized solar cells based on rutile‐phase three‐dimensional <scp>TiO<sub>2</sub></scp> hierarchical nanostructures2023

    • Author(s)
      G. Arthi、Selvam Rajiv、Y. Hayakawa、J. Archana、M. Navaneethan、S. Ponnusamy、C. Muthamizhchelvan、Ramaraj Sankar Ganesh
    • Journal Title

      Microscopy Research and Technique

      Volume: 86 Issue: 7 Pages: 813-822

    • DOI

      10.1002/jemt.24342

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Reconfigurable magnon interference by on-chip dynamic wavelength conversion2023

    • Author(s)
      Md Shamim Sarker, Lihao Yao, Hiroyasu Yamahara, Kaijie Ma, Zhiqiang Liao, Kenyu Terao, Siyi Tang, Sankar Ganesh Ramaraj, Munetoshi Seki, Hitoshi Tabata
    • Journal Title

      Scientific Reports

      Volume: 13 Issue: 1 Pages: 4872-4872

    • DOI

      10.1038/s41598-023-31607-7

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] First-principles study on the role of anion in the physical properties of lead-free halide double perovskites2023

    • Author(s)
      Rajeev Kumar N.、Ramaraj Sankar Ganesh、Karthika P.C.、Mathew Nishitha P.、Radhakrishnan R.
    • Journal Title

      Computational Materials Science

      Volume: 218 Pages: 111975-111975

    • DOI

      10.1016/j.commatsci.2022.111975

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solvothermal synthesis of 3D hierarchical rutile TiO2 nanostructures for efficient dye-sensitized solar cells2023

    • Author(s)
      Arthi G.、Archana J.、Navaneethan M.、Ponnusamy S.、Hayakawa Y.、Muthamizhchelvan C.、Ramaraj Sankar Ganesh
    • Journal Title

      Materials Letters

      Volume: 337 Pages: 133961-133961

    • DOI

      10.1016/j.matlet.2023.133961

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A review of flexible lead-free piezoelectric energy harvester2022

    • Author(s)
      Yue Ruifeng、Ramaraj Sankar Ganesh、Liu Hailong、Elamaran Durgadevi、Elamaran Vidya、Gupta Vinay、Arya Sandeep、Verma Sonali、Satapathi Soumitra、hayawaka Yasuhiro、Liu Xinghui
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 918 Pages: 165653-165653

    • DOI

      10.1016/j.jallcom.2022.165653

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Carbon molecular sieve-functionalized graphene sensors for highly sensitive detection of ethanol2022

    • Author(s)
      Sankar Ganesh Ramaraj, Manoharan Muruganathan, Osazuwa G. Agbonlahor, Hisashi Maki, Yosuke Onda, Masashi Hattori, Hiroshi Mizuta
    • Journal Title

      Carbon

      Volume: 190 Pages: 359-365

    • DOI

      10.1016/j.carbon.2022.01.023

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] RF Sputtered Nb-Doped MoS<sub>2</sub> Thin Film for Effective Detection of NO<sub>2</sub> Gas Molecules: Theoretical and Experimental Studies2022

    • Author(s)
      Ramaraj Sankar Ganesh、Nundy Srijita、Zhao Pin、Elamaran Durgadevi、Tahir Asif Ali、Hayakawa Yasuhiro、Muruganathan Manoharan、Mizuta Hiroshi、Kim Sang-Woo
    • Journal Title

      ACS Omega

      Volume: 7 Issue: 12 Pages: 10492-10501

    • DOI

      10.1021/acsomega.1c07274

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Clogging-Free Electrospinning of Micro-And Nanofibers From Polymer Solutions and Its Blends2022

    • Author(s)
      Satheesh Arjun、Ramaraj Sankar Ganesh、Alagiriswamy A. A.
    • Journal Title

      Brazilian Journal of Physics

      Volume: 52 Issue: 3 Pages: 82-82

    • DOI

      10.1007/s13538-022-01087-7

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Development of morphologically engineered flower-like Hafnium doped ZnO with experimental and DFT validation for low-temperature and ultrasensitive detection of VOC gas2022

    • Author(s)
      1.Srijita Nundy, Sankar Ganesh Ramaraj, Manoharan Muruganathan, Aritra Ghosh, Asif Ali Tahir, Tapas Kumar Mallick, Joon-Shik Park, Hoo-Jeong Lee
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: -

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Suspended graphene Surface acoustic wave skin gas sensor for effective detection of acetone gas molecules2024

    • Author(s)
      Sankar Ganesh Ramaraj, Zhou Haolong, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      The 71st JSAP Spring Meeting 2024
    • Related Report
      2023 Annual Research Report
  • [Presentation] 酸化物半導体マイクロパターン及びゼオライト複合センサによる短鎖脂肪酸ガスのセンシング2024

    • Author(s)
      高村 尭良, Sankar Ramaraj, Zang Chuanlai, 田畑, 仁
    • Organizer
      The 71st JSAP Spring Meeting 2024
    • Related Report
      2023 Annual Research Report
  • [Presentation] Detection of acetone gas molecules from the human skin using Zeolite Functionalized Graphene FET gas sensor2023

    • Author(s)
      Sankar Ganesh Ramaraj, Zhou Haolong, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      The 84th JSAP Autumn Meeting 2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Graphene Surface Acoustic Wave Gas sensor for effective detection of acetone down to Ppt levels in the Air atmosphere2023

    • Author(s)
      Zhou Haolong, Sankar Ganesh Ramaraj, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      The 84th JSAP Autumn Meeting 2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Dynamic Redox Reaction-Driven Electrically Tunable Magnon FET2023

    • Author(s)
      Shamim sarker, Hiroyasu Yamahara, Kenyu Terao, Siyi Tang, Sankar G Ramaraj, Lihao Yao, EMK Ikball Ahamed, Munetoshi Seki, Hitoshi Tabata
    • Organizer
      The 84th JSAP Autumn Meeting 2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Enhanced acetone gas sensing using zeolite functionalized graphene nanoribbon FET in the real-air environment2023

    • Author(s)
      Sankar Ganesh Ramaraj, Zhou Haolong, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      International Conference on Solid State Devices and Materials 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ppt Level Detection of Acetone in Air atmosphere using Graphene Surface Acoustic Wave Gas Sensor2023

    • Author(s)
      Haolong Zhou, Ganesh Ramaraj Sankar, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      2023年第70回応用物理学会 春季学術講演会
    • Related Report
      2022 Research-status Report
  • [Presentation] Zeolite functionalized graphene FET E-nose for selective detection of volatile organic compounds2023

    • Author(s)
      Sankar Ganesh Ramaraj, Haolong Zhou, Yuka Yamada, Hiroyasu Yamahara, Hitoshi Tabata
    • Organizer
      2023年第70回応用物理学会 春季学術講演会
    • Related Report
      2022 Research-status Report
  • [Presentation] Catalyst-modified graphene FET towards ammonium gas sensing2022

    • Author(s)
      浜坂 省吾, Manoharan Muruganathan, Sankar Ganesh Ramaraj, 槇 恒, 恩田 陽介, 服部 将志, 水田 博
    • Organizer
      第69回応用物理学会春季学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] Enhanced acetone gas sensing of activated carbon functionalized graphene nanoribbon FET in the real-air environment2021

    • Author(s)
      R. Sankar Ganesh, M. Manoharan, Gabriel Agbonlahor, H. Maki, M. Hattori, H. Mizuta
    • Organizer
      82nd JSAP Autumn Meeting 2021
    • Related Report
      2021 Research-status Report
  • [Presentation] Charge neutrality point disparity based identification of ethanol gas molecules in activated carbon functionalized graphene2021

    • Author(s)
      R. Sankar Ganesh, M. Manoharan, Gabriel Agbonlahor, H. Maki, M. Hattori, K. Shimomai, H. Mizuta
    • Organizer
      SSDM 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Real-time Conformational Switching of Graphene-Molecule van der Waals Bonding Complexes in Graphene Gas Sensors2021

    • Author(s)
      Osazuwa Gabriel Agbonlahor, Manoharan Muruganathan, Sankar Ganesh Ramaraj, Kohei Taketomi, Hisashi Maki, Masashi Hattori, Hiroshi Mizuta
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Research-status Report
  • [Remarks] 田畑・松井・関研究室HP

    • URL

      http://www.bioxide.t.u-tokyo.ac.jp/

    • Related Report
      2022 Research-status Report

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Published: 2021-04-28   Modified: 2025-01-30  

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