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Creation of Smart Alloys with Anticorrosion Functions: A Change in Concept from Solid Solution of Corrosion-Resistant Elements to Secondary Phases

Research Project

Project/Area Number 21K18804
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionTohoku University

Principal Investigator

Muto Izumi  東北大学, 工学研究科, 教授 (20400278)

Co-Investigator(Kenkyū-buntansha) 菅原 優  東北大学, 工学研究科, 准教授 (40599057)
西本 昌史  東北大学, 工学研究科, 助教 (20880967)
Project Period (FY) 2021-07-09 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2022: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2021: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords耐孔食性 / 腐食 / ステンレス鋼 / アルミニウム合金 / スマートアロイ / 耐食性 / マイクロ電気化学 / 腐食防食 / 耐食合金 / 非平衡組織 / Mo
Outline of Research at the Start

ステンレス鋼とAl合金に対し、防食元素であるMoやNなどを「固溶」ではなく「第二相化」した新しい省資源・高耐食合金「スマートアロイ」を開発する。MoやNは腐食により、イオンになり溶液の腐食性を低下させ、耐食性向上に寄与している。しかし、MoやNを均一に固溶させた場合、防食作用が現れる時には、合金は大きく侵食されている。このため、高耐食化には多量の合金元素の添加が不可欠である。耐海水鋼では6%のMoと0.2%のNが必須であるが、あまりにも高価である。このように、「固溶による高耐食化」は、工学的には限界に達している。本研究は、この壁を突破する新しい高耐食化原理導出への挑戦である。

Outline of Final Research Achievements

Resource-saving and highly corrosion resistant alloys (smart alloys) have been developed in this study. The newly developed smart alloys improved local corrosion resistance by utilizing a second phase. For Type 304L stainless steel, Mo was used to form the second phase, and two different steels were developed: insoluble Mo-enriched phase or soluble Mo-enriched phase. For AA7075 aluminum alloy, Mn was used to form the second phase, and it was found that the corrosion resistance is improved by the Mn-rich phase.

Academic Significance and Societal Importance of the Research Achievements

Moは腐食部で、可溶性のイオンになり溶液の腐食性を低下させることで、耐食性向上に寄与していることは知られていた。しかし、Moを母相に均一に固溶させた際には、防食作用が現れる時には、すでに合金は大きく腐食している。このため、「高耐食化=高合金化」とされてきた。しかし、本研究は、Moを第二相に濃縮させることでも、防食効果が発揮することを見出した世界初の研究成果であり、今までの「固溶・高合金化による高耐食化」に対するパラダイム転換であり、耐食合金設計に大転換をもたらす可能性を秘めている。Al合金のMn濃化相に関しても、積層造形材など、粉末を出発材料とする工業製品の高耐食化への応用が期待される。

Report

(3 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • Research Products

    (25 results)

All 2023 2022 2021 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 8 results) Presentation (16 results) (of which Int'l Joint Research: 7 results)

  • [Int'l Joint Research] USTB(中国)

    • Related Report
      2022 Annual Research Report
  • [Journal Article] Role of KMnO<sub>4</sub>–NaF Treatment in Galvanic Corrosion Resistance of AA5083 Coupled to Steel2023

    • Author(s)
      Kosaba Takumi、Muto Izumi、Nishimoto Masashi、Sugawara Yu
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 64 Issue: 4 Pages: 896-903

    • DOI

      10.2320/matertrans.MT-L2022021

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2023-04-01
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chemical Conversion Treatment of AA5083 Aluminum Alloy and AISI 1045 Carbon Steel under Galvanically Coupled Condition in Na<sub>2</sub>MoO<sub>4</sub>: Effect of pH on Corrosion Resistance2023

    • Author(s)
      Kosaba Takumi、Muto Izumi、Nishimoto Masashi、Sugawara Yu
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 64 Issue: 2 Pages: 568-577

    • DOI

      10.2320/matertrans.MT-M2022163

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2023-02-01
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fabrication of a model specimen for understanding micro-galvanic corrosion at the boundary of α-Mg and β-Mg17Al122023

    • Author(s)
      Shao Zheng、Nishimoto Masashi、Muto Izumi、Sugawara Yu
    • Journal Title

      Journal of Magnesium and Alloys

      Volume: 11 Issue: 1 Pages: 137-153

    • DOI

      10.1016/j.jma.2022.10.020

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Change in Oxygen Reduction Reactivity of Intermetallics: A Mechanism of the Difference in Trenching around Al-Fe and Al-Fe-Si Particles on AA1050 in NaCl2023

    • Author(s)
      Kakinuma Hiroshi、Muto Izumi、Oya Yoshiyuki、Momii Takahiro、Jin Ying、Sugawara Yu、Hara Nobuyoshi
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 170 Issue: 2 Pages: 021503-021503

    • DOI

      10.1149/1945-7111/acb6ba

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Micro-electrochemical insights into pit initiation site on aged UNS S32750 super duplex stainless steel2023

    • Author(s)
      Amatsuka Shuichiro、Nishimoto Masashi、Muto Izumi、Kawamori Makoto、Takara Yuya、Sugawara Yu
    • Journal Title

      npj Materials Degradation

      Volume: 7 Issue: 1 Pages: 15-15

    • DOI

      10.1038/s41529-023-00335-8

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Corrosion-resistant sintered stainless steels with non-equilibrium Mo-rich phases2022

    • Author(s)
      Saito Haruka、Muto Izumi、Nishimoto Masashi、Sugawara Yu
    • Journal Title

      Materials Today Communications

      Volume: 33 Pages: 104211-104211

    • DOI

      10.1016/j.mtcomm.2022.104211

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sudden pH and Cl- Concentration Changes during the Crevice Corrosion of Type 430 Stainless Steel2022

    • Author(s)
      Matsumura Kengo、Nishimoto Masashi、Muto Izumi、Sugawara Yu
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 169 Issue: 10 Pages: 101506-101506

    • DOI

      10.1149/1945-7111/ac9bda

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Micro-Electrochemical Aspects of the Effects of Temperature on Pit Initiation at MnS Inclusion in Type 304 Stainless Steel2022

    • Author(s)
      Takayama Riku、Nishimoto Masashi、Muto Izumi、Sugawara Yu
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 169 Issue: 11 Pages: 111501-111501

    • DOI

      10.1149/1945-7111/ac9d6c

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 溶液中マイクロインデンテーションによるType304ステンレス鋼の孔食発生要因の解析2022

    • Author(s)
      中嶋優汰、武藤泉、菅原優
    • Organizer
      材料と環境2022(腐食防食学会講演大会)
    • Related Report
      2022 Annual Research Report
  • [Presentation] アルミニウム合金AA5083表面における Al6(Fe,Mn)周囲でのトレンチ形成に及ぼすMg2Siの影響2022

    • Author(s)
      小鯖 匠、武藤泉、西本昌史、菅原優
    • Organizer
      材料と環境2022(腐食防食学会講演大会)
    • Related Report
      2022 Annual Research Report
  • [Presentation] 第二相によるオーステナイト系ステンレス鋼の高耐食化の検討2022

    • Author(s)
      齋藤遥、武藤泉、西本昌史、菅原優
    • Organizer
      材料と環境2022(腐食防食学会講演大会)
    • Related Report
      2022 Annual Research Report
  • [Presentation] Mg 合金のα/β界面の作製と腐食挙動の評価2022

    • Author(s)
      邵筝、西本昌史、武藤泉、菅原優
    • Organizer
      材料と環境2022(腐食防食学会講演大会)
    • Related Report
      2022 Annual Research Report
  • [Presentation] Mn含有水溶液中での表面処理とMn濃化組織によるアルミニウム合金の高耐食化2022

    • Author(s)
      海老名航、西本昌史、武藤泉、菅原優
    • Organizer
      材料と環境2022(腐食防食学会講演大会)
    • Related Report
      2022 Annual Research Report
  • [Presentation] AZ91Dマグネシウム合金のリン酸塩溶液中での陽極酸化処理2022

    • Author(s)
      邵筝、西本昌史、武藤泉、菅原優
    • Organizer
      日本金属学会2022年秋期(第171回)講演大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] マイクロ電気化学システムを用いた硝酸イオンによる孔食の抑制機構の解明2022

    • Author(s)
      雨塚 秀一朗、武藤泉、西本昌史、菅原優
    • Organizer
      日本金属学会2022年秋期(第171回)講演大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Effect of Mg2si on Trenching Formation Around Al6(Fe, Mn) on AA5083 in Diluted Synthetic Seawater2022

    • Author(s)
      Takumi Kosaba, Izumi Muto, Masashi Nishimoto, Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of secondary phases in stainless steel on corrosion resistance2022

    • Author(s)
      Haruka Saito, Izumi Muto, Masashi Nishimoto, Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spark Plasma Sintering Fabrication of α/β Interface in Mg Alloys and Analysis of Corrosion Behavior2022

    • Author(s)
      Zheng Shao, Masashi Nishimoto, Izumi Muto, Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of AA7075 containing Mn-rich phases by spark plasma sintering and evaluation of the pitting corrosion resistance2022

    • Author(s)
      Ko Ebina, Izumi Muto, Masashi Nishimoto, and Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Elucidation of the corrosion inhibition mechanism of nitrogen-based inhibitors and fabrication of a flow-cell type microelectrochemical system2022

    • Author(s)
      Shuichiro Amatsuka, Izumi Muto, Masashi Nishimoto, Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Micro-Electrochemical Analysis of Initiation Processes of Intergranular Corrosion of Al-Cu and Al-Cu-Mg Alloys2022

    • Author(s)
      Hiroki Yoshida, Izumi Muto, Masashi Nishimoto, Mai Takaya, Yoshihiko Kyo, Tadashi Minoda, Yu Sugawara
    • Organizer
      242nd ECS Meeting (The Electrochemical Society)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 第二相を利用したステンレス鋼の高耐食化の試み2022

    • Author(s)
      齋藤遥、武藤泉、西本昌史、菅原優
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Mo濃化領域によるステンレス鋼の耐食性への影響2021

    • Author(s)
      齋藤 遥、武藤 泉、菅原 優
    • Organizer
      日本金属学会 2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Fabrication of Type 304L Containing Mo-rich Areas and Corrosion Behavior2021

    • Author(s)
      Haruka Saito, Izumi Muto, Yu Sugawara
    • Organizer
      240th ECS Meeting
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research

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Published: 2021-07-13   Modified: 2024-01-30  

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