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Deformation mechanism of CoCrNi medium entropy alloy with ultrafine grain microstructure

Research Project

Project/Area Number 21K20487
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeMulti-year Fund
Review Section 0401:Materials engineering, chemical engineering, and related fields
Research InstitutionKyoto University

Principal Investigator

Yoshida Shuhei  京都大学, 工学研究科, 助教 (00911710)

Project Period (FY) 2021-08-30 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2022: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2021: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords超微細粒金属材料 / ミディアムエントロピー合金 / 変形組織 / 電子顕微鏡 / 格子欠陥 / 転位 / 双晶 / その場回折測定 / ハイエントロピー合金 / 透過電子顕微鏡 / 力学特性 / 結晶粒界 / 巨大ひずみ加工 / 材料組織
Outline of Research at the Start

材料の強度(強さ)と延性(ねばさ)には一般的にトレードオフ関係がある.そのトレードオフ関係を打開する方法として金属材料の結晶粒組織の超微細粒(UFG)化が注目されている.UFG組織を有するCoCrNi等原子量合金は,高い強度と高い延性を両立した特異な変形挙動を示す.本研究では,電子顕微鏡による変形組織観察と変形中のその場回折測定を組み合わせた独自の手法を駆使し,UFG組織を有するCoCrNi等原子量合金が示す強度と延性を両立した特異な力学特性の発現メカニズムの解明を目指す.それにより,優れた力学特性を有する新しい構造用金属材料の設計が可能になると期待される.

Outline of Final Research Achievements

The present study aims to clarify the origin of the significant mechanical properties in the fully recrystallized ultrafine-grained (UFG) CoCrNi medium entropy alloy (MEA). Specimens of the UFG CoCrNi MEA were fabricated by high-pressure torsion and subsequent annealing. Tensile tests were performed at room temperature. The deformation microstructures were characterized by electron microscopy. At the yield point, widely-extended stacking faults and tangled dislocations were frequently observed. After that, deformation twins started appearing, and the density of dislocations and stacking faults increased. The extraordinary work-hardening ability of UFG CoCrNi MEA was attributed to the boundaries (such as stacking faults and deformation twins) dynamically introduced during plastic deformation as well as the increase in dislocation density.

Academic Significance and Societal Importance of the Research Achievements

本研究は,UFG組織を有するCoCrNi MEAの特異な変形機構の解明を通じて,従来のUFG金属の典型的な問題点であった延性の低下を克服するために何が必要であるかを結晶粒界の拘束と変形組織発達の観点から明らかにすることができた.このようなUFG金属に特徴的な変形挙動を詳細に明らかにする研究は,これまでに世界各国で行われているUFG金属の材料科学研究の発展に大きく貢献するほか,強度と延性を両立した究極の構造材料を設計するための指針を得ることで社会・産業界の発展にも貢献できると考えられる.

Report

(3 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • Research Products

    (29 results)

All 2023 2022 2021 Other

All Int'l Joint Research (7 results) Journal Article (5 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 4 results,  Open Access: 2 results) Presentation (17 results) (of which Int'l Joint Research: 7 results,  Invited: 3 results)

  • [Int'l Joint Research] 大連理工大学/重慶大学/上海交通大学(中国)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] デンマーク工科大学(デンマーク)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] インド工科大学ハイデラバード校(インド)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] インド科学技術大学/インド工科大学(インド)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] デンマーク工科大学(デンマーク)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] 重慶大学/上海交通大学(中国)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] 嶺南大学(韓国)

    • Related Report
      2021 Research-status Report
  • [Journal Article] Characteristic strengthening mechanisms in body-centered cubic refractory high/medium entropy alloys2023

    • Author(s)
      He Qian、Yoshida Shuhei、Tsuji Nobuhiro
    • Journal Title

      Scripta Materialia

      Volume: 231 Pages: 115442-115442

    • DOI

      10.1016/j.scriptamat.2023.115442

    • Related Report
      2022 Annual Research Report
  • [Journal Article] Yield and flow properties of ultra-fine, fine, and coarse grain microstructures of FeCoNi equiatomic alloy at ambient and cryogenic temperatures2023

    • Author(s)
      Lavakumar Avala、Yoshida Shuhei、Punyafu Jesada、Ihara Shiro、Chong Yan、Saito Hikaru、Tsuji Nobuhiro、Murayama Mitsuhiro
    • Journal Title

      Scripta Materialia

      Volume: 230 Pages: 115392-115392

    • DOI

      10.1016/j.scriptamat.2023.115392

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Destruction of mesoscopic chemically modulated domains in single phase high entropy alloy via plastic deformation2022

    • Author(s)
      Miyajima Yoji、Nagata Tomohiro、Takeda Kohei、Yoshida Shuhei、Yasuno Satoshi、Watanabe Chihiro、Kazuhiro Ishikawa、Adachi Hiroki、Tsuji Nobuhiro
    • Journal Title

      Scientific Reports

      Volume: 12 Issue: 1 Pages: 16776-16776

    • DOI

      10.1038/s41598-022-20932-y

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Grain orientation dependence of deformation microstructure evolution and mechanical properties in face-centered cubic high/medium entropy alloys2022

    • Author(s)
      Yoshida S、Fu R、Gong W、Ikeuchi T、Bai Y、Feng Z、Wu G、Shibata A、Hansen N、Huang X、Tsuji N
    • Journal Title

      IOP Conference Series: Materials Science and Engineering

      Volume: 1249 Issue: 1 Pages: 012027-012027

    • DOI

      10.1088/1757-899x/1249/1/012027

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] In-situ observations of static recrystallization and texture formation in a cold-rolled CoCrFeMnNi high entropy alloy2022

    • Author(s)
      Baoqi Guo, Ranjit K. Ray, Shuhei Yoshida, Yu Bai, NobuhiroTsuji
    • Journal Title

      Scripta Materialia

      Volume: 215 Pages: 114706-114706

    • DOI

      10.1016/j.scriptamat.2022.114706

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Deformation Behavior of CoCrFeMnNi High Entropy Alloy Highly Strained by Torsion at Elevated Temperatures2023

    • Author(s)
      Nobuhiro Tsuji, Reza Gholizadeh, Shuhei Yoshida, Yu Bai, Shu, Kurokawa, Akinobu Shibata
    • Organizer
      2023 TMS Annual Meeting & Exhibition
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mechanical Response of Materials Investigated through Novel In-situ Experiments and Modeling2023

    • Author(s)
      Takumi Suzumura, Si Gao, Shuhei Yoshida, Nobuhiro Tsuji
    • Organizer
      2023 TMS Annual Meeting & Exhibition
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recrystallization behavior of face-centered cubic high/medium entropy alloys processed by severe plastic deformation and subsequent annealing2023

    • Author(s)
      Shuhei Yoshida, Nokeun Park, Kohei Shiotani, Yu Bai, Tomoaki Niiyama, Akinobu Shibata, Tomotsugu Shimokawa, Nobuhiro Tsuji
    • Organizer
      International Workshop on High Entropy Alloys
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超微細粒組織を有するCoCrNi medium entropy alloyの室温引張変形挙動2022

    • Author(s)
      吉田 周平, 山下 元気, 池内 琢人, Bai Yu, 柴田 曉伸, 辻 伸泰
    • Organizer
      日本金属学会2022年秋期(第171回)講演大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Grain orientation dependence of deformation microstructure evolution and mechanical properties in face-centered cubic high/medium entropy alloys2022

    • Author(s)
      Shuhei Yoshida, Rui Fu, Wu Gong, Takuto Ikeuchi, Yu Bai, Zongqiang Feng, Guilin Wu, Akinobu Shibata, Niels Hansen, Xiaoxu Huang, Nobuhiro Tsuji
    • Organizer
      42nd Riso International Symposium on Materials Science
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of elemental combination on microstructure and mechanical properties of refractory medium entropy alloys2022

    • Author(s)
      Shuhei Yoshida, Qian He, Hideyuki Yasuda, Nobuhiro Tsuji
    • Organizer
      2022 TMS Annual Meeting and Exhibition
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] FCC構造を有するHigh/Medium Entropy Alloyにおける強化機構と室温引張変形挙動2022

    • Author(s)
      吉田 周平, Fu Rui, Gong Wu, 池内 琢人, Bai Yu, 柴田 曉伸, Feng Zongqiang, Wu Guilin, Hansen Niels, Curtin William, Huang Xiaoxu, 辻 伸泰
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
    • Invited
  • [Presentation] Ni-Cr二元系合金の室温力学特性に及ぼす短範囲規則化の影響2022

    • Author(s)
      常盤 大樹, 吉田 周平, 宮嶋 陽司, 辻 伸泰
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 多結晶純コバルトの微視組織と室温力学特性2022

    • Author(s)
      鈴村 拓未, Gao Si, 吉田 周平, 辻 伸泰
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] ゴムメタルTi-36Nb-2Ta-3Zr-0.4Oにおける力学特性の特異な結晶粒径依存性2022

    • Author(s)
      橋野 達郎, 吉田 周平, Yu Bai, 辻 伸泰
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Effect of Zr addition on microstructure and mechanical properties of CoCrNi medium entropy alloy2022

    • Author(s)
      Singh Rathod Bhukya Devendar, Reza Gholizadeh, Shuhei Yoshida, Nobuhiro Tsuji
    • Organizer
      日本金属学会 2022年春期(第170回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Local chemical ordering in CoCrNi medium-entropy alloy and its impact on mechanical properties2021

    • Author(s)
      Koji Inoue, Shuhei Yoshida, Nobuhiro Tsuji
    • Organizer
      Summit of Materials Science 2022 and GIMRT User Meeting 2022 Affiliated with KINKEN WAKATE 2022
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Short-range ordering in CoCrNi medium-entropy alloy investigated by atom probe tomography and its impact on mechanical properties2021

    • Author(s)
      Koji Inoue, Shuhei Yoshida, Nobuhiro Tsuji
    • Organizer
      Materials Research Meeting 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] 3次元アトムプローブから見たCoCrNiミディアムエントロピー合金における“短距離秩序”と機械的特性への影響2021

    • Author(s)
      井上耕治, 吉田 周平, 辻伸泰
    • Organizer
      日本金属学会 2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] FCC構造を有する High/Medium entropy alloy の引張変形組織と室温力学特性の関係2021

    • Author(s)
      吉田 周平, Fu Rui, Gong Wu, 池内 琢人, Bai Yu, 柴田 曉伸, Feng Zongqiang, Wu Guilin, Hansen Niels, Huang Xiaoxu, 辻 伸泰
    • Organizer
      日本金属学会 2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Gum Metalにおける力学特性の特異な粒径依存性2021

    • Author(s)
      橋野達郎, 吉田 周平, Bai Yu, 辻 伸泰
    • Organizer
      日本金属学会 2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Static recrystallization and texture formation in cold-rolled high entropy CoCrFeMnNi alloy2021

    • Author(s)
      Baoqi Guo, Ranjit Kumar Ray, Shuhei Yoshida, Yu Bai, Nobuhiro Tsuji
    • Organizer
      日本金属学会 2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report

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Published: 2021-10-22   Modified: 2024-01-30  

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