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Development of chemical fixation of ubiquitous molecules with bifunctional molecular catalysts

Research Project

Project/Area Number 22225004
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

IKARIYA Takao  東京工業大学, 理工学研究科, 教授 (30107552)

Co-Investigator(Renkei-kenkyūsha) KUWATA Shigeki  東京工業大学, 大学院・理工学研究科, 准教授 (10292781)
DGRIDNEV Ilya  東北大学, 大学院・理学研究科, 准教授 (60374906)
KAYAKI Yoshihito  東京工業大学, 大学院・理工学研究科, 助教 (20572704)
Project Period (FY) 2010-05-31 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥218,140,000 (Direct Cost: ¥167,800,000、Indirect Cost: ¥50,340,000)
Fiscal Year 2013: ¥31,460,000 (Direct Cost: ¥24,200,000、Indirect Cost: ¥7,260,000)
Fiscal Year 2012: ¥37,960,000 (Direct Cost: ¥29,200,000、Indirect Cost: ¥8,760,000)
Fiscal Year 2011: ¥50,310,000 (Direct Cost: ¥38,700,000、Indirect Cost: ¥11,610,000)
Fiscal Year 2010: ¥98,410,000 (Direct Cost: ¥75,700,000、Indirect Cost: ¥22,710,000)
Keywords協奏機能触媒 / 均一系触媒 / 不斉合成 / 水素化 / 小分子活性化 / 選択的合成・反応 / 錯体・有機金属触媒 / 不斉合成・反応 / 触媒設計・反応 / 環境調和型反応 / イミド / アミド / エステル / 炭素-炭素結合形成 / 炭素-窒素結合形成 / ヒドロアミノ化
Research Abstract

On the basis of our accumulated knowledge in the bifunctional catalysis, we tried 1) to design new mono- and multi-nuclear transition metal-based complexes bearing cooperating ligands, and 2) to demonstrate perfect chemical reactions by extension of the scope of the applicability of the bifunctional catalysis, and finally 3) to explore the chemical fixation of the ubiquitous molecules into useful compounds and materials by development of the practical bifunctional molecular catalysts. The emergence of powerful bifunctional molecular catalysts provided efficient, sustainable and green production processes in the field of organic synthesis. In addition, the bifunctional catalyst promoted powerful chemical fixation technology of ubiquitous molecules including H2O, H2, O2, N2, and CO2 available in huge amounts can help to replace the fossil resources.

Assessment Rating
Verification Result (Rating)

A

Report

(6 results)
  • 2014 Research Progress Assessment (Verification Result) ( PDF )
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (182 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (50 results) (of which Peer Reviewed: 45 results) Presentation (108 results) (of which Invited: 11 results) Book (12 results) Remarks (8 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Aerobic Oxidative Desymmetrization of meso-Diols with Bifunctional Amidoiridium Catalysts Bearing Chiral N-Sulfonyldiamine Ligands.2014

    • Author(s)
      J. Moritani, Y. Hasegawa, Y. Kayaki, T. Ikariya
    • Journal Title

      Tetrahedron Letters

      Volume: 55 Issue: 6 Pages: 1188-1191

    • DOI

      10.1016/j.tetlet.2013.12.103

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Reactivities of Iron, Cobalt, and Manganese Complexes Bearing a Pincer Ligand with Two Protic Pyrazole Arms.2014

    • Author(s)
      K. Umehara, S. Kuwata, T. Ikariya
    • Journal Title

      Inorganica Chmica Acta

      Volume: 413 Pages: 136-142

    • DOI

      10.1016/j.ica.2013.12.041

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Selective Hydrogenation of α-Fluorinated Esters with Bifunctional Pincer-Type Ruthenium(II) Catalysts Leading to Fluorinated Alcohols or Fluoral Hemiacetals2013

    • Author(s)
      Takashi Ootsuka, Akihiro Ishii, Pavel A. Dub, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol.135 Issue: 26 Pages: 9600-9603

    • DOI

      10.1021/ja403852e

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] C-F Bond Breaking through Aromatic Nucleophilic Substitution with a Hydroxo Ligand Mediated via Water Bifunctional Activation.2013

    • Author(s)
      Pavel A. Dub, Hui Wang, Asuka Matsunami, Ilya D. Gridnev, Shigeki Kuwata, and Takao Ikariya
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: (In press) Issue: 5 Pages: 557-568

    • DOI

      10.1246/bcsj.20120359

    • NAID

      10031167847

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] N-N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex2013

    • Author(s)
      Kazuki Umehara, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol.135 Issue: 18 Pages: 6754-6757

    • DOI

      10.1021/ja3122944

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Chemical Calculations With the Inclusion of Non-specific and Specific Solvation : Asymmetric Transfer Hydrogenation with Bifunctional Ruthenium Catalysts2013

    • Author(s)
      Pavel A. Dub and Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 7 Pages: 2604-2619

    • DOI

      10.1021/ja3097674

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NHC-Gold(I) Complexes as Effective Catalysts for Carboxylative Cyclization of Propargylamines with Carbon Dioxide.2013

    • Author(s)
      S. Hase, Y. Kayaki, T. Ikariya
    • Journal Title

      Organometallics

      Volume: 32 Issue: 19 Pages: 5285-5288

    • DOI

      10.1021/om400949m

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cycloaddition of Tertiary Aziridines and Carbon Dioxide Using a Recyclable Organocatalyst, 1,3-Di-tert- butylimidazolium-2-carboxylate: Straightforward Access to 3-Substituted 2-Oxazolidones.2013

    • Author(s)
      A. Ueno
    • Journal Title

      Green Chem.

      Volume: 15 Issue: 2 Pages: 425-430

    • DOI

      10.1039/c2gc36414j

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic reductive transformations of carboxylic and carbonic acid derivatives using molecular hydrogen.2012

    • Author(s)
      Pavel A. Dub ; Takao Ikariya
    • Journal Title

      ACS Catal.

      Volume: 2 Issue: 8 Pages: 1718-1741

    • DOI

      10.1021/cs300341g

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Dynamic Kinetic Resolution of Racemic Secondary Alcohols by a Chemoenzymatic System Using Bifunctional Iridium Complexes with C-N Chelate Amido Ligands.2012

    • Author(s)
      Y. Sato
    • Journal Title

      Chem. Commun.

      Volume: 48 Issue: 30 Pages: 3635-3637

    • DOI

      10.1039/c2cc30333g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Consideration of Asymmetric C-N and C-C Bond Formations with Bifunctional Chiral Ir and Ru Catalysts.2012

    • Author(s)
      Y. Hasegawa
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 85 Issue: 3 Pages: 316-334

    • DOI

      10.1246/bcsj.20110307

    • NAID

      10030219021

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Reactivities of Pincer-Type Ruthenium Complexes Bearing Two Proton-Responsive Pyrazole Arms.2012

    • Author(s)
      A. Yoshinari
    • Journal Title

      Chem. Asian J.

      Volume: 7 Issue: 6 Pages: 1417-1425

    • DOI

      10.1002/asia.201200014

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on Solubility of Uranyl Complexes in Supercritical Carbon Dioxide and Its Controlling Factors Using UV-visible and 17O- and 19F-NMR Spectroscopy.2012

    • Author(s)
      N. Miyamoto
    • Journal Title

      J. Nucl. Sci. Tech.

      Volume: 49 Issue: 1 Pages: 37-46

    • DOI

      10.1080/18811248.2011.636531

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Practical Asymmetric Conjugate Addition to Cyclic Enones with Chiral Bifunctional Ru Amido Catalysts2012

    • Author(s)
      Pavel A. Dub ; Hui Wang ; Masahito Watanabe ; Ilya Gridnev ; Takao Ikariya
    • Journal Title

      Tetrahedron Lett.

      Volume: 53 Issue: 27 Pages: 3452-3455

    • DOI

      10.1016/j.tetlet.2012.04.100

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属ヒドリド試薬を猛追する分子触媒 -水素によるエステル還元反応2012

    • Author(s)
      碇屋隆雄
    • Journal Title

      化学

      Volume: 67 Pages: 66-67

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation2012

    • Author(s)
      柏女洋平, 桑田繁樹, 碇屋隆雄
    • Journal Title

      Organometallics

      Volume: 31 Issue: 23 Pages: 8444-8455

    • DOI

      10.1021/om301063n

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and asymmetric hydrogenation of (3E)-1-benzyl-3- [(2-oxopyridin-1(2H)-yl)methylidene]piperidine-2,6-dione.2012

    • Author(s)
      A. A. Bisset
    • Journal Title

      Chem. Commun.

      Volume: 48 Issue: 98 Pages: 11978-11980

    • DOI

      10.1039/c2cc36807b

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Dioxide-promoted Selective Reductive Amination of Aliphatic Ketones with Aniline and Hydrogen Using a Pt/C Catalyst.2012

    • Author(s)
      S. Ichikawa
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 12 Pages: 1628-1629

    • DOI

      10.1246/cl.2012.1628

    • NAID

      10031135773

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Transfer Hydrogenation Catalysis of Bifunctional Iridium Complexes Bearing a C-N Chelate Oxime Ligand.2012

    • Author(s)
      M. Watanabe
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 3 Issue: 3 Pages: 504-511

    • DOI

      10.1002/ejic.201100800

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trapping of a Doubly Unsaturated Dinuclear Iridium(II) Sulfonylimido Complex with Phosphine and Lewis Acidic Group 11 and 12 Metals.2012

    • Author(s)
      T. Kimura
    • Journal Title

      Organometallics

      Volume: 31 Issue: 3 Pages: 1204-1207

    • DOI

      10.1021/om201218j

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H_2 Hydrogenation2011

    • Author(s)
      Taichiro Touge, Tomohiko Hakamata, Hideki Nara, Tohru Kobayashi, Noboru Sayo, Takao Saito, Yoshihito Kayaki, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol. 133 Issue: 38 Pages: 14960-14963

    • DOI

      10.1021/ja207283t

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] H-H and N-H Bond Cleavage of Dihydrogen and Ammonia with Bifunctional Parent Imido (NH)-Bridged Diiridium Complex2011

    • Author(s)
      Takashi Kimura, Naoyuki Koiso, Koji Ishiwata, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol.133 Issue: 23 Pages: 8880-8883

    • DOI

      10.1021/ja203538b

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] β-Protic Pyrazole and N-Heterocyclic Carbene Complexes : Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis2011

    • Author(s)
      Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Chem. Eur. J

      Volume: Vol.17 Issue: 13 Pages: 3542-3556

    • DOI

      10.1002/chem.201003296

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp*Ru Complexes Bearing a Protic Amine Ligand2011

    • Author(s)
      Masato Ito, Takashi Ootsuka, Ryo Watari, Akira Shiibashi, Akio Himizu, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol. 133 Issue: 12 Pages: 4240-4242

    • DOI

      10.1021/ja1117254

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselective Lactonization of Unsymmetrical 1,4-Diols : an Efficient Access to Lactone Lignans2011

    • Author(s)
      Masato Ito, Akira Shiibashi, Takao Ikariya
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 2134-2136

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemistry of Concerto Molecular Catalysis Based on the Metal/NH Bifunctionality2011

    • Author(s)
      Takao Ikariya
    • Journal Title

      Bull.Chem.Soc.Jpn.

      Volume: 84 Pages: 1-16

    • NAID

      10027653991

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp^*Ru Complexes Bearing a Protic Amine Ligand2011

    • Author(s)
      Masato Ito, Takashi Ootsuka, Ryo Watari, Akira Shiibashi, Akio Himizu, Takao Ikariya
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Pages: 4240-4242

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] β-Protic Pyrazole and N-Heterocyclic Carbene Complexes : Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis2011

    • Author(s)
      Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Chem.Eur.J.

      Volume: 17 Pages: 3542-3556

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Proton-Transfer Reactions of Bronsted Basic Pyridylpyrazole Complexes of Ruthenium2011

    • Author(s)
      Yohei Kashiwame, Megumi Watanabe, Kenjirou Araki, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Bull.Chem.Soc.Jpn.

      Volume: 84 Pages: 251-258

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of Enantioselective C-C Bond Formation with Bifunctional Chiral Ru Catalysts : NMR and DFT Study2010

    • Author(s)
      Ilya D. Gridnev, Masahito Watanabe, Hui Wang, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol. 132 Issue: 46 Pages: 16637-16650

    • DOI

      10.1021/ja107597w

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective and Z/E-Selective Conjugate Addition of α-Substituted Cyanoacetates to Acetylenic Esters Catalyzed by Bifunctional Ruthenium and Iridium Complexes2010

    • Author(s)
      Yasuharu Hasegawa, Ilya D. Gridnev, Takao Ikariya
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: Vol. 49 Issue: 44 Pages: 8157-8160

    • DOI

      10.1002/anie.201003585

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds2010

    • Author(s)
      Masato Ito, Chika, Kobayashi, Akio Himizu, Takao Ikariya
    • Journal Title

      J. Am. Chem. Soc

      Volume: Vol. 132 Issue: 33 Pages: 11414-11415

    • DOI

      10.1021/ja105048c

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quest for Metal/NH Bifunctional Bioinspired Catalysis in a Dinuclear Platform2010

    • Author(s)
      Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Dalton Trans

      Volume: 39 Issue: 12 Pages: 2984-2992

    • DOI

      10.1039/b927357c

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 超臨界二酸化炭素2010

    • Author(s)
      碇屋隆雄
    • Journal Title

      工業材料

      Volume: 58 Pages: 48-49

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Metal-Pyrazole Bifunction in Half-Sandwich C-N Chelate Iridium Complexes : Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene2010

    • Author(s)
      Yohei Kashiwame, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Chem.Eur.J.

      Volume: 16 Pages: 766-770

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quest for Metal/NH Bifunctional Bioinspired Catalysis in a Dinuclear Platform2010

    • Author(s)
      Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 2984-2992

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadieneyl Complexes2010

    • Author(s)
      Masato Ito, Noriko Tejima, Masahiro Yamamura, Yoshinori Endo, Takao Ikariya
    • Journal Title

      Organometallics

      Volume: 29 Pages: 1886-1889

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Amorphous Nano-Structured Silicas for High-Performance Carbon Dioxide Confinement2010

    • Author(s)
      Shinichiro Ichikawa, Tsunetake Seki, Mizuki Tada, Yasuhiro Iwasawa, Takao Ikariya
    • Journal Title

      J.Mater.Chem.

      Volume: 20 Pages: 3163-3165

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bifunctional Triflylamide-Tethered Cp'Rh and Cp'Ir Complexes : A New Entry for Asymmetric Hydrogenation Catalysts2010

    • Author(s)
      Masato Ito, Yoshinori Endo, Noriko Tejima, Takao Ikariya
    • Journal Title

      Organometallics

      Volume: 29 Pages: 2397-2399

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bifunctional Transition Metal-Based Molecular Catalysts for Asymmetric C-C and C-N Bond Formation2010

    • Author(s)
      Takao Ikariya, Ilya D.Gridnev
    • Journal Title

      Top.Catal.

      Volume: 53 Pages: 894-901

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxidation with Bifunctional Molecular Catalysts2010

    • Author(s)
      Takao Ikariya, Shigeki Kuwata, Yoshihito Kayaki
    • Journal Title

      Pure Appl.Chem.

      Volume: 82 Pages: 1471-1483

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds2010

    • Author(s)
      Masato Ito, Chika, Kobayashi, Akio Himizu, Takao Ikariya
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 11414-11415

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Reversible Deprotonation of a Half-Sandwich Iridium Complex Bearing a Chelating Oxime Ligand2010

    • Author(s)
      Megumi Watanabe, Yohei Kashiwame, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 758-759

    • NAID

      10027183026

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Nitrile Hydration with Bifunctional Ruthenium Catalysts Bearing Chiral N-Sulfonyldiamine Ligands2010

    • Author(s)
      Shoko Kamezaki, Satoshi Akiyama, Yoshihito Kayaki, Shigeki Kuwata, Takao Ikariya
    • Journal Title

      Tetrahedron Asymmetry

      Volume: 21 Pages: 1169-1172

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 協奏機能触媒の化学2010

    • Author(s)
      碇屋隆雄、榧木啓人
    • Journal Title

      TCIメール

      Volume: 147 Pages: 2-11

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Synthesis and Reactivity of 2-Aminoethanethiolato-Bridged Dinuclear Ru(hmb) Complexes (hmb=η^6-hexamethylbenzene) : Mechanistic Consideration on Transfer Hydrogenation with Bifunctional [RuCl_2(hmb)]_2/2-Aininoethanethiol CatalystSystem2010

    • Author(s)
      Masato Ito, Akira Watanabe, Yuji Shibata, Takao Ikariya
    • Journal Title

      Organometallics

      Volume: 29 Pages: 4584-4592

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ものづくりに役立つ協奏機能触媒2010

    • Author(s)
      碇屋隆雄
    • Journal Title

      化学

      Volume: 65 Pages: 22-27

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Enantioselective and Z/E-Selective Conjugate Addition of α-Substituted Cyanoacetates to Acetylenic Esters Catalyzed by Bifunctional Ruthenium and Iridium Complexes2010

    • Author(s)
      Yasuhiro Hasegawa, Ilya D.Gridnev, Takao Ikariya
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 8157-8160

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of Enantioselective C-C Bond Formation with Bifunctional Chiral Ru Catalysts : NMR and DFT Study2010

    • Author(s)
      Ilya D.Gridnev, Masahito Watanabe, Hui Wang, Takao Ikariya
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 16637-16650

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 超分子触媒のグリーンケミストリー?2010

    • Author(s)
      碇屋隆雄
    • Journal Title

      化学工学

      Volume: 74 Pages: 450-453

    • Related Report
      2010 Annual Research Report
  • [Presentation] 力量ある協奏機能分子触媒の開発2013

    • Author(s)
      碇屋隆雄
    • Organizer
      日本プロセス化学会2013サマーシンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2013-07-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Recent Progress in Concerto Molecular Catalysis with Bifunctional Catalysts2013

    • Author(s)
      Takao Ikariya
    • Organizer
      IUPAC 44th World Chemistry Congress
    • Place of Presentation
      Istanbul, Turkey
    • Related Report
      2013 Final Research Report
  • [Presentation] Recent Progress in Concerto Molecular Catalysis with Bifunctional Catalysts2013

    • Author(s)
      T.Ikariya
    • Organizer
      IUPAC 44th World Chemistry Congress
    • Place of Presentation
      Istanbul Lutfi Kirdar Congress and Exhibition Center, Istanbul(トルコ)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Recent Progress in Concerto Molecular Catalysis2012

    • Author(s)
      Takao Ikariya
    • Organizer
      Chiral India 2012 (Chiral Technologies for Pharmaceutical Fine Chemicals)
    • Place of Presentation
      Hyderabad, India
    • Year and Date
      2012-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] ものづくりに役立つ革新的触媒の開発に向けて2012

    • Author(s)
      碇屋隆雄
    • Organizer
      第2回CSJフェスタ
    • Place of Presentation
      東京工業大学
    • Year and Date
      2012-10-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Chemistry of Concerto Molecular Catalysis2011

    • Author(s)
      Takao Ikariya
    • Organizer
      Catalyst 2011, Dr. Reddy's Chemistry Conclave
    • Place of Presentation
      Hyderabad, India
    • Year and Date
      2011-12-16
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Utilization of Carbon Dioxide in Organic Synthesis2011

    • Author(s)
      碇屋隆雄
    • Organizer
      第18回グリーンケミストリーフォーラム
    • Place of Presentation
      岡山コンベンションセンター
    • Year and Date
      2011-10-31
    • Related Report
      2013 Final Research Report
  • [Presentation] Activation of Molecular Hydrogen and Hydrogenation with Bifunctional Molecular Catalysis2011

    • Author(s)
      Takao Ikariya
    • Organizer
      Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-10-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Recent Advances in Concerto Molecular Catalysis2011

    • Author(s)
      Takao Ikariya
    • Organizer
      France-Japan Joint Forum on Chemistry of Functional Organic Chemicals
    • Place of Presentation
      Université de Strasbourg, France
    • Year and Date
      2011-06-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 協奏機能触媒の化学2011

    • Author(s)
      碇屋隆雄
    • Organizer
      有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      千葉大学
    • Year and Date
      2011-05-22
    • Related Report
      2013 Final Research Report
  • [Presentation] 含窒素複素環カルベン触媒を用いる二酸化炭素固定化:N置換アジリジンのカルボキシル化反応2011

    • Author(s)
      上野篤史、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] ペンタメチルシクロペンタジェニル配位子をもつビス(スルホニルアミド)ロジウム錯体の合成と反応性2011

    • Author(s)
      森あゆみ、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ビナフチル骨格を持つキラルジアミン配位子の合成とCp^*Ir錯体との反応性2011

    • Author(s)
      川田雄一、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] C-Nキレート型オキシム配位子をもつイリジウム錯体の合成と触媒機能2011

    • Author(s)
      渡邊恵、柏女洋平、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヒドラゾン配位子をもつハーフサンドイッチ型IrおよびRu錯体の合成と反応性2011

    • Author(s)
      高見芳恵、柏女洋平、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 置換アニリン類のシクロメタル化によるC-NキレートCp*錯体の合成研究2011

    • Author(s)
      佐藤康博、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ベンシルチオール誘導体のシクロメタル化によるチアイリダサイクルの合成とその反応性2011

    • Author(s)
      山本直樹、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ピンサー型ビス(ピラゾリル)ピリジン配位子を有する鉄錯体の合成と反応性2011

    • Author(s)
      梅原和樹、吉成彰裕、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Reactivities of C-N Chelating Pyrazole-Iridium Complex and Its Application to Catalytic Intramolecular Hydroamination2010

    • Author(s)
      Yohei Kashiwame, Shigeki Kuwata, Takao Ikariya
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Reactions of Dinuclear Indium Complex Bearing μ_2-NH Ligand2010

    • Author(s)
      Shigeki Kuwata, Trakashi Kimura, Koji Ishiwata, Takao Ikariya
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Concerto Molecular Catalysis for Stereo-, Regio-, and Chemo-selective Transformation2010

    • Author(s)
      Takao Ikariya
    • Organizer
      Symposium Chiral China 2010
    • Place of Presentation
      天津(中国)
    • Year and Date
      2010-10-17
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] Cp^*Ru錯体を用いたプロパルギル化合物の触媒的二量化反応2010

    • Author(s)
      Hoang Ngan Nguyen、桑田繁樹、碇屋隆雄
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] オキシム配位子をもつハーフサンドイッチ型イリジウムおよびルテニウム錯体の合成と反応性2010

    • Author(s)
      渡邊恵、柏女洋平、桑田繁樹、碇屋隆雄
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Reactivities of Noble Metal Complexes Bearing Protic β-NH and OH Groups2010

    • Author(s)
      Shigeki Kuwata, Yohei Kashiwame, Megumi Watanabe, Takao Ikariya
    • Organizer
      The 24th International Conference of Organometallic Chemistry
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2010-07-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Dynamic Kinetic Resolution of Racemic Secondary Alcohols with Bifunctional Amido-Ir and -Rh Catalysts2010

    • Author(s)
      Yasuhiro Sato, Kayaki Yoshihito, Takao Ikariya
    • Organizer
      The 24th International Conference of Organometallic Chemistry
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Enantio- and Z/E Selective Addition of Cyanoesters to Acetylenic Esters Catalyzed by Bifunctional Ru and Ir Complexes2010

    • Author(s)
      Yasuharu Hasegawa, Ilya D.Gridnev, Takao Ikariya
    • Organizer
      The 24th International Conference of Organometallic Chemistry
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Oxidative Transformation with Bifunctional Molecular Catalysts2010

    • Author(s)
      Takao Ikariya
    • Organizer
      Presymposium of the 24th International Conference of Organometallic Chemistry
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2010-07-18
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] Carbon Dioxide as a Greener Solvent and Reactant for Catalytic Reactions2010

    • Author(s)
      Takao Ikariya
    • Organizer
      Green Solvent Conference
    • Place of Presentation
      ベルヒテスガーデン(ドイツ)
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] Copper-Catalyzed Carboxylation of Aryl Aluminum Species Generated by C-H Bond Activation of Functionalized Arenes

    • Author(s)
      A. Ueno, M. Takimoto, T. Ikariya, Z. Hou
    • Organizer
      5 th Gratama Workshop
    • Place of Presentation
      東京工業大学くらまえホール(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Carboxylative Cyclization of Propargylamines with CO2 Catalyzed by NHC-Au(I) Complexes

    • Author(s)
      Y.Kayaki, S.Hase, T.Ikariya
    • Organizer
      5 th Gratama Workshop
    • Place of Presentation
      東京工業大学くらまえホール(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 力量ある協奏機能分子触媒の開発

    • Author(s)
      碇屋隆雄
    • Organizer
      日本プロセス化学会2013サマーシンポジウム
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] グラブス先生のご紹介と触媒研究の楽しみ

    • Author(s)
      碇屋隆雄
    • Organizer
      講演会「ノーベル化学賞と触媒」
    • Place of Presentation
      東京工業大学くらまえホール(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Carboxylative Cyclization of Propargylamines with CO2 Catalyzed by NHC-Au(I) Complexes

    • Author(s)
      S.Hase, Y.Kayaki, T.Ikariya
    • Organizer
      17th International IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-17)
    • Place of Presentation
      コロラド州立大学Ft. Collins(米国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Asymmetric Aerobic Oxidation of Cs-Symmetric Diols with Cp*Ir Catalysts Bearing Chiral Diamine Ligands

    • Author(s)
      J. Moritani, Y.Kayaki, T.Ikariya
    • Organizer
      17th International IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-17)
    • Place of Presentation
      コロラド州立大学Ft. Collins(米国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Recent Progress in Concerto Molecular Catalysis

    • Author(s)
      T.Ikariya
    • Organizer
      Weizmann Institute of Science Symposium
    • Place of Presentation
      Rehovot(イスラエル)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Synthesis of New Dinuclear C-N Chelate Iridium Complexes by Cyclometallation of Chiral Benzylic Diamines

    • Author(s)
      Yasuhiro Sato, Shungo Yasui, Kohei Suzuki, Yoshihito Kayaki, Takao Ikariya
    • Organizer
      第60 回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of a New Cp*Ru Complex Bearing a Primary Amine-NHC Chelate Ligand and Its Application to Catalytic Hydrogenation of Carboxamides

    • Author(s)
      Teruhiko Kawano, Ryo Watari, Yoshihito Kayaki, Takao Ikariya
    • Organizer
      第60 回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Copper-Catalyzed Carboxylation of Organo-Aluminum Species Generated by Aluminum Ate Complex

    • Author(s)
      A. Ueno, M. Takimoto, T. Ikariya, Z. Hou
    • Organizer
      第60 回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルなベンジリックジアミンが架橋したC-Nキレート二核Ir錯体の合成

    • Author(s)
      安井隼吾、鈴木康平、佐藤康博、榧木啓人、碇屋隆雄
    • Organizer
      第3回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ペンタフルオロベンゼンスルホニル基をもつ協奏機能イリジウム錯体のシクロメタル化反応:ヒドリド錯体を経由するC-F結合開裂

    • Author(s)
      松並明日香、榧木啓人、碇屋隆雄
    • Organizer
      第3回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ピラゾリルピリジン骨格を有するプロティックな非対称ピンサー型錯体の合成と反応性

    • Author(s)
      戸田達朗、桑田繁樹、碇屋隆雄
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学(沖縄県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Chiral Bifunctional Catalysis: Reductive transformation

    • Author(s)
      T.Ikariya
    • Organizer
      Chiral India 2013
    • Place of Presentation
      Mumbai(インド)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Chiral Bifunctional Catalysis: Oxidative transformation

    • Author(s)
      T.Ikariya
    • Organizer
      Chiral India 2013
    • Place of Presentation
      Mumbai(インド)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] NHC-アミンキレート配位子を有する協奏機能Cp*Ru錯体を用いたカルボン酸アミドの触媒的水素化反応

    • Author(s)
      亘理龍、河野晃丈、榧木啓人、碇屋隆雄
    • Organizer
      第66 回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] O-Nキレート型サリチルオキシム配位子をもつルテニウム錯体の合成と反応性

    • Author(s)
      古田達郎、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] キレート型スルホンアミダト配位子をもつルテニウムおよびイリジウム錯体の合成と反応性

    • Author(s)
      山口あゆみ、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 第2級アルコールとケトン間の不斉水素移動反応に有効なヒドリドイリジウム錯体の結晶構造と動的挙動

    • Author(s)
      森谷隼紀、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケトンの不斉水素移動型還元反応におけるジアステレオメリックなヒドリドイリジウム錯体の反応性評価

    • Author(s)
      森谷隼紀、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヒドリドイリジウム錯体の分子内C-F結合開裂を経るシクロメタル化反応

    • Author(s)
      松並明日香、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ジフェニルピペラジン誘導体のシクロメタル化によるC-Nキレートイリジウム二核錯体の合成

    • Author(s)
      安井隼吾、鈴木康平、佐藤康博、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 8族および9族金属協奏機能アミド錯体によるインドールのN-H結合開裂

    • Author(s)
      上野篤史、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機塩基および銅触媒を用いた二酸化炭素の水素化によるギ酸塩合成

    • Author(s)
      亘理龍、榧木啓人、平野伸一、松本伯夫、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] NHC-銀錯体による二酸化炭素を用いたアミノメチルアレンの触媒的環化カルボキシル化反応

    • Author(s)
      山下恭平、長谷俊、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 触媒的環化カルボキシル化反応中間体モデルとしてのアルケニル金(I)錯体の合成と反応性

    • Author(s)
      長谷俊、山下恭平、榧木啓人、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロティックなピンサー配位子をもつイリジウム錯体の合成

    • Author(s)
      斎藤功紀、吉成彰裕、戸田達朗、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] トリスピラゾール型四座キレート配位子をもつルテニウム錯体の合成と反応性

    • Author(s)
      山岸宏章、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロティックなビス(ピラゾール)アミン配位子をもつルテニウム錯体の合成と反応性

    • Author(s)
      齋藤研人、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロティックなN-ヘテロ環状カルベン部位をもつピンサー型ルテニウム錯体の合成と反応性

    • Author(s)
      戸田達朗、桑田繁樹、碇屋隆雄
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Dynamic Kinetic Resolution of Racemic Secondary Alcohols by a Chemoenzymatic System Using Bifunctional C-N Chelate Amido Complexes

    • Author(s)
      Y.Sato
    • Organizer
      8th Workshop on Organic Chemistry for Junior Chemists (WOCJC-8)
    • Place of Presentation
      KAIST, Korea
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二酸化炭素を用いる第三級アジリジン類の触媒的カルボキシル化反応の開発

    • Author(s)
      上野篤史
    • Organizer
      第1回JACI/GSCシンポジウム
    • Place of Presentation
      ベルサール神田(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis, Structures, and Reactivities of Pincer‐Type Complexes Bearing Two Proton-Responsive Pyrazole Arms

    • Author(s)
      S.Kuwata
    • Organizer
      the XXV International Conference on Organometallic Chemistry (XXV ICOMC)
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] Efficient Synthesis of 1-Indolecarboxamides by Catalytic Ureation Using bis(Sulfonylamido)Rhdium Complexes

    • Author(s)
      A.Mori
    • Organizer
      the XXV International Conference on Organometallic Chemistry (XXV ICOMC)
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] Scope and Mechanism of Intramolecular Hydroamination Catalyzed by Bifunctional Pyrazolato-Iridium Complex

    • Author(s)
      Y.Kashiwame
    • Organizer
      the XXV International Conference on Organometallic Chemistry (XXV ICOMC)
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and Structural Chemistry of Hydrido(amine)iridium Complexes Relevant to Hydrogen Transfer Catalysis

    • Author(s)
      J.Moritani
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Carboxylative Cyclization of Propargylamines with CO2 Catalyzed by NHC-Au(I) Complexes

    • Author(s)
      S.Hase
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and Reactivity of (Cyclopentadienyl) Ruthenium Complexes Bearing a Protic Hydrazone Ligand

    • Author(s)
      Y.Takami
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ハーフサンドイッチ型ビス(スルホニルアミド)コバルト錯体の合成と反応性

    • Author(s)
      森あゆみ
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ビナフチル骨格をもつキラルジアミン配位子により架橋された二核 C-Nキレートイリジウム錯体の合成

    • Author(s)
      佐藤康博
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] NHC-金触媒による二酸化炭素とプロパルギルアミンとの環化カルボキシル化反応

    • Author(s)
      長谷俊
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二官能性ピラゾラトイリジウム錯体を触媒とするアミノアルケンの分子内ヒドロアミノ化反応

    • Author(s)
      柏女洋平
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] キラルジアミンから誘導されるC-Nキレートイリジウム二核錯体の合成とその触媒機能

    • Author(s)
      佐藤康博
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ものづくりに役立つ革新的触媒の開発に向けて

    • Author(s)
      碇屋隆雄
    • Organizer
      第2回CSJ化学フェスタ
    • Place of Presentation
      東京工業大学(東京都)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Recent Progress in Concerto Molecular Catalysis

    • Author(s)
      T.Ikariya
    • Organizer
      Chiral India 2012(Chiral Technologies for Pharmaceutical Fine Chemicals)
    • Place of Presentation
      Hyderabad, India
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ピンサー型ビス(ピラゾリル)ピリジン配位子を有するコバルト錯体の合成と反応性

    • Author(s)
      梅原和樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] プロティックなトリス(ピラゾール)型4座キレート配位子をもつ鉄錯体の合成

    • Author(s)
      鍋谷翔平
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] C-H 結合活性化により調製したアリールアルミニウム種の銅触媒によるカルボキシル化反応

    • Author(s)
      上野篤史
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 6 員環キレートピラゾール配位子をもつイリジウム錯体の合成と反応性

    • Author(s)
      柏女洋平
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] チアメタラサイクル構造をもつCp*Ir 二核錯体の反応性

    • Author(s)
      山本直樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ピンサー型ビスピラゾリルピリジン配位子をもつ多プロトン応答型ルテニウム錯体の合成

    • Author(s)
      正井航平
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ピラゾールと第 3級アミン部位をもつピンサー型ルテニウム錯体の合成と反応性

    • Author(s)
      戸田達朗
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 協奏機能ルテニウムおよびイリジウムアミド錯体を用いるアンモニア、一級アミン、ヒドラジンの活性化とC-F 結合開裂を経るシクロメタル化による三座キレート錯体への変換

    • Author(s)
      P.A.Dub
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] キラルN,N’,N’’-三座キレート協奏機能ルテニウムおよびイリジウムアミド錯体を用いる芳香族ケトンの不斉水素移動還元反応

    • Author(s)
      松並明日香
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] κ3O 三脚型Klaui 配位子をもつルテニウム4価錯体の合成とその反応性

    • Author(s)
      堀内淳矢
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] ヒドラゾンルテニウム錯体触媒を用いたアリルアルコールによるアリル化反応

    • Author(s)
      高見芳恵
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 協奏機能触媒の化学

    • Author(s)
      碇屋隆雄
    • Organizer
      有機合成化学関東支部シンポジウム
    • Place of Presentation
      千葉大学(千葉県)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Recent Advances in Concerto Molecular Catalysis

    • Author(s)
      Takao Ikariya
    • Organizer
      France-Japan Joint Forum on Chemistry of Functional Organic Chemicals
    • Place of Presentation
      University of Strasbourg, France
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Hydrogenation of Esters and Carboxamides Promoted by Bifunctional Cp*Ru Catalysts

    • Author(s)
      R.Watari
    • Organizer
      The 16th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS16)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2011 Annual Research Report
  • [Presentation] ニッケル触媒によるジシアノ化反応を経る2,2’-ビス(アミノメチル)-1,1’-ビナフタレンの簡便合成法

    • Author(s)
      川田雄一
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京農工大学(東京都)
    • Related Report
      2011 Annual Research Report
  • [Presentation] プロティックアミンキレート配位子を有するCp*Ru 錯体を用いたN-アリールカルボン酸アミドの水素化反応

    • Author(s)
      亘理龍
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京農工大学(東京都)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金触媒による二酸化炭素とプロパルギルアミンとの環化カルボキシル化反応

    • Author(s)
      長谷俊
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京農工大学(東京都)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 二酸化炭素を用いるヒドラゾン類の分子内環化カルボキシル化反応の開発

    • Author(s)
      上野篤史
    • Organizer
      日本化学会第5回関東支部大会
    • Place of Presentation
      東京農工大学(東京都)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Catalytic Behavior of Half-sandwich Bis(sulfonylamido)rhodium Complexes

    • Author(s)
      A.Mori
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Properties of Half-sandwich Thiairidacycles Derived from Benzylthiols

    • Author(s)
      N.Yamamoto
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Reactivity of Half-sandwich Iridium and Ruthenium Complexes Bearing a Hydrazone Ligand

    • Author(s)
      Y.Takami
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 新規トリフリルアミドテザー型Cp’Ru 錯体の合成と反応性

    • Author(s)
      坂本直紀
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ピンサー型ビス(ピラゾリル)ピリジン配位子をもつ鉄錯体の合成と反応性

    • Author(s)
      梅原和樹
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ハーフサンドイッチ型カチオン性C-N キレートイリジウムおよびロジウム錯体の合成と水素分子の活性化

    • Author(s)
      佐藤康博
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] カチオン性モノアミド架橋二核錯体の合成と反応

    • Author(s)
      小礒尚之
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Activation of Molecular Hydrogen and Hydrogenation with Bifunctional Molecular Catalysts

    • Author(s)
      Takao Ikariya
    • Organizer
      Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Utilization of Carbon Dioxide in Organic Synthesis

    • Author(s)
      碇屋隆雄
    • Organizer
      第18回グリーンケミストリーフォーラム
    • Place of Presentation
      岡山コンベンションセンター(岡山県)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] ジフェニルピペラジンのシクロメタル化反応によるキラル二核C-Nキレートイリジウム錯体の合成

    • Author(s)
      鈴木康平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] キレート型スルホンアミダト配位子をもつイリジウム錯体の合成と反応性

    • Author(s)
      山口あゆみ
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ピラゾラトイリジウム錯体触媒を用いたアミノアルケンの分子内ヒドロアミノ化とその反応機構

    • Author(s)
      柏女洋平
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] O-Nキレート型サリチルオキシム配位子をもつイリジウム錯体の合成と反応性

    • Author(s)
      古田達郎
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] キラルCp*Ir 錯体を用いた、触媒的空気酸化によるメソ体ジオール類の非対称化

    • Author(s)
      森谷隼紀
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 協奏機能アミン錯体によるα,β-不飽和エステル類の触媒的水素化反応

    • Author(s)
      宮澤和己
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ピンサー型ビス(ピラゾリル)ピリジン鉄錯体とヒドラジン類の反応

    • Author(s)
      梅原和樹
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] プロティックなヒドラゾン配位子をもつハーフサンドイッチ型ルテニウム錯体の合成と反応性

    • Author(s)
      高見芳恵
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学(神奈川県)
    • Related Report
      2011 Annual Research Report
  • [Book] 新しい溶媒を用いた有機合成2013

    • Author(s)
      榧木啓人, 碇屋隆雄
    • Publisher
      S&T 出版
    • Related Report
      2013 Final Research Report
  • [Book] Iridium, [N-[(1R,2R)-2-(amino-κN) cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadi en-1-yl]-, stereoisomer; Iridium, [N-[(1R,2R)-2-(amino-κN)cyclohexyl]-4-methylbenzenesulfonamidat o-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-; Iridium, [N-[(1S,2S)-2- (amino-κN)cyclohexyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopent adien-1-yl]-, Stereoisomer, e-EROS Encyclopedia of Reagents for Organic Synthesis2013

    • Author(s)
      Takao Ikariya
    • Publisher
      John Wiley&Sons
    • Related Report
      2013 Final Research Report
  • [Book] 新しい溶媒を用いた有機合成 第1章 低環境負荷有機合成の概要2013

    • Author(s)
      榧木啓人
    • Total Pages
      8
    • Publisher
      S&T出版
    • Related Report
      2012 Annual Research Report
  • [Book] 新しい溶媒を用いた有機合成 第2章第1節 超臨界二酸化炭素を用いた二酸化炭素固定ー水素化反応2013

    • Author(s)
      榧木啓人
    • Total Pages
      8
    • Publisher
      S&T出版
    • Related Report
      2012 Annual Research Report
  • [Book] 新しい溶媒を用いた有機合成 第2章第2節 超臨界二酸化炭素を用いた二酸化炭素固定ー付加反応2013

    • Author(s)
      榧木啓人
    • Total Pages
      10
    • Publisher
      S&T出版
    • Related Report
      2012 Annual Research Report
  • [Book] 新しい溶媒を用いた有機合成 第2章第5節 超臨界二酸化炭素を溶媒に用いた溝呂木ーHeck反応2013

    • Author(s)
      榧木啓人
    • Total Pages
      8
    • Publisher
      S&T出版
    • Related Report
      2012 Annual Research Report
  • [Book] Rhodium, [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenyl-ethyl]-4-meth yl-benzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl]-, Stereoisomer, e-EROS Encyclopedia of Reagents for Organic Synthesis2012

    • Author(s)
      Takao Ikariya, Y oshihito Kayaki
    • Publisher
      John Wiley&Sons
    • Related Report
      2013 Final Research Report
  • [Book] 最新グリーンケミストリー 持続的社会のための化学、 御園生誠・村橋俊一編<II編13 グリーン反応媒体―超臨界流体:二酸化炭素の固定化 >2012

    • Author(s)
      碇屋隆雄
    • Total Pages
      8
    • Publisher
      講談社サイエンティフィク
    • Related Report
      2011 Annual Research Report
  • [Book] e-EROS Encyclopedia of Reagents for Organic Synthesis, "Rhodium, [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4,-cyclopentadien-1-yl ]-, Stereoisomer"2012

    • Author(s)
      T. Ikariya
    • Total Pages
      1
    • Publisher
      John Wiley & Sons, Ltd
    • Related Report
      2011 Annual Research Report
  • [Book] グリーン反応媒体- 超臨界流体 : 二酸化炭素の固定化, 最新グリーンケミストリー 持続的社会のための化学, 御園生誠, 村橋俊一編2011

    • Author(s)
      碇屋隆雄, 榧木啓人
    • Publisher
      講談社
    • Related Report
      2013 Final Research Report
  • [Book] Bifunctional Transition Metal -Based Molecular Catalysts for Asymmetric Syntheses, Topics in Organometallic Chemistry2011

    • Author(s)
      Takao Ikariya
    • Publisher
      Springer
    • Related Report
      2013 Final Research Report
  • [Book] Topics in Organometallic Chemistry Bifunctional Transition Metal-Based Molecular Catalysts for Asymmetric Syntheses.2011

    • Author(s)
      T. Ikariya
    • Total Pages
      23
    • Publisher
      Springer
    • Related Report
      2011 Annual Research Report
  • [Remarks] 本研究に関わる研究成果と,分子触媒化学の重要性を社会に向けて発信するために, 2005年ノーベル化学賞受賞者 Robert H. Grubbs 教授を招いた講演会「ノーベル化学賞と触媒」を平成25年7月29日に東京工業大学くらまえホールにて主催した. 一流の化学者が語る触媒研究の意義や楽しさを, 日本の将来を担う若者に直に感じて欲しいと考え, 大学学部生や高校生, 中学生にも広く参加を呼びかけた. その結果, 中学生~大学院学生を含め参加者は300余名に達した. 研究成果を広く伝えるだけでなく, 大学院生, 大学学部生, 高校生が英語で直接ノーベル化学賞受賞者と語り合う貴重な機会を提供することができた. なお「現代化学」 (東京化学同人)2013年10月号pp.60-61に, 当日の様子のレポートを掲載した. 関連ホームページ

    • URL

      http://www.apc.titech.ac.jp/~tikariya/Grubbs/

    • Related Report
      2013 Final Research Report
  • [Remarks] 碇屋隆雄,フンボルト賞(2011年)(主な受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 碇屋隆雄,桑田繁樹ほか,日本化学会欧文誌 BCSJ 賞(2011年および 2013年)(主な受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 碇屋隆雄,科学技術分野の文部科学大臣表彰科学技術賞(2014年)(主な受賞)

    • Related Report
      2013 Final Research Report
  • [Remarks] 研究内容 -- Green Chemistryに向けた新機軸の確立

    • URL

      http://www.apc.titech.ac.jp/~tikariya/research.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 研究内容 - Green Chemistryに向けた新機軸の確立

    • URL

      http://www.apc.titech.ac.jp/~tikariya/research.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 研究内容 - Green Chemistryに向けた新機軸の確立

    • URL

      http://www.apc.titech.ac.jp/~tikariya/research.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.apc.titech.ac.jp/~tikariya/research.html

    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 1,3-ジアルキル-2-イミダゾリジノン類の製造方法2013

    • Inventor(s)
      關祐威, 小久保慶陽, 鈴木智之, 榧木啓人, 碇屋隆雄, 市川真一郎
    • Industrial Property Rights Holder
      国立大学法人東京工業大学・三井化学株式会社
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2013-10-04
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 光学活性な含窒素化合物の製造方法2013

    • Inventor(s)
      渡辺正人, 村田邦彦, 碇屋隆雄
    • Industrial Property Rights Holder
      関東化学株式会社
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2013-03-01
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 光学活性ニトロ化合物およびシアノ化合物の製造方法2011

    • Inventor(s)
      渡辺正人, 村田邦彦, 碇屋隆雄
    • Industrial Property Rights Holder
      関東化学株式会社
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2011-08-10
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 光学活性アルコール化合物合成用触媒2010

    • Inventor(s)
      碇屋隆雄, 池平秀行, 村田邦彦, 清藤信夫, 大岡浩仁, 橋口昌平, 大熊毅, 野依良治
    • Industrial Property Rights Holder
      関東化学株式会社
    • Industrial Property Rights Type
      特許
    • Acquisition Date
      2010-12-03
    • Related Report
      2013 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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