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Development of a new index of global waming potential for short-lived replacement compounds for CFCs

Research Project

Project/Area Number 22241009
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental impact assessment/Environmental policy
Research InstitutionThe University of Tokyo

Principal Investigator

Ryoichi Imasu  東京大学, 大気海洋研究所, 教授 (40334255)

Co-Investigator(Kenkyū-buntansha) 齋藤 尚子  千葉大学, 環境リモートセンシング研究センター, 助教 (50391107)
田村 正則  独立行政法人産業技術総合研究所, 環境化学技術研究部門, 主任研究員 (40357489)
陳 亮  独立行政法人産業技術総合研究所, 環境化学技術研究部門, 主任研究員 (70371060)
Project Period (FY) 2010-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥46,540,000 (Direct Cost: ¥35,800,000、Indirect Cost: ¥10,740,000)
Fiscal Year 2014: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2013: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2012: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2011: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2010: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywords代替フロン / 放射強制力 / 地球温暖化係数 / 環境技術 / 気候変動 / 気象 / GWP / 気象学 / 環境評価手法 / 温室効果 / 物質輸送モデル / HFE / HFO / PFO
Outline of Final Research Achievements

Most acceptable candidates as replacement compounds for chlorofluorocarbons (CFCs) are hydorofluoroethers (HFEs) and hydrofluoroolefins (HFOs). The rate constants of reaction of these chemical species with OH radical were determined by laboratory experiments. Based on these constants, atmospheric lifetimes of the compounds were estimated, and global warming potentials (GWPs) were updated. On the other hand, chemical transport model based on a global circulation model (GCM) have been developed to calculate the global distribution and radiative forcing of these replacement compounds in the atmosphere. After achieving a stable state in concentration of the compounds in interest, globally integrated radiative forcing can be evaluated. We propose, as a conclusion, to use these values as a new measure to represent more reliable climate impacts of replacement compounds which have shorter lifetimes in the atmosphere.

Academic Significance and Societal Importance of the Research Achievements

IPCCの第4次報告書において報告されたヒドロフルオロカーボン(HFC)の代替物質であるヒドロフルオロエーテル(HFE)やヒドロフルオロオレフィン(HFO)などの物質の地球温暖化暖化ポテンシャル(GWP)値について、より信頼度の高い値を提示することができる。これにより、実際に使用するHFEを選択する判断基準がより明確になることで、HFCからHFEへの転換を促すことに繋げられる。

Report

(6 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (13 results)

All 2015 2013 2012 2011 2010 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (11 results) (of which Invited: 2 results)

  • [Journal Article] Rate constants for the gas-phase reactions of cyclo-CX=CXCF2CF2- (X = H, F) with OH radicals at a temperature range of 253 to 328 K2013

    • Author(s)
      Xiaoqing Jia, Liang Chen, Junji Mizukado, Shuzo Kutsuna, Kazuaki Tokuhashi (Xiaoqing Jia)
    • Journal Title

      Chem. Phys. Lett.

      Volume: 18 Pages: 1-5

    • DOI

      10.1016/j.cplett.2013.04.020

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and mechanism of gas-phase reactions of n-C4F9OCH3, i-C4F9OCH3, n-C4F9OC(O)H, and i-C4F9OC(O)H with OH radicals in an environmental reaction chamber at 253-328 K2011

    • Author(s)
      K, Liang Chen, et al.
    • Journal Title

      Chemical Physics Letters

      Volume: 514 Issue: 4-6 Pages: 207-213

    • DOI

      10.1016/j.cplett.2011.08.049

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Global warming potentials and radiative effects of chlorofluorocarbon (CFC) replacements, hydrofluoroethers (HFEs) and hydrofluoroolefins (HFOs)2015

    • Author(s)
      Imasu, R., L. Chen, M. Tamura, K. Tokuhashi, Y. Niwa, and B. Fomin
    • Organizer
      International Symposium on Atmospheric Radiation and Dynamics 2015(ISARD-2015)
    • Place of Presentation
      St. Petersburg, Russia
    • Year and Date
      2015-06-23 – 2015-06-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] PSC and cirrus cloud detection over the high latitudes using thermal infrared spectra observed by TANSO-FTS/GOSAT2013

    • Author(s)
      Yu Someya, Ryoichi Imasu, Kei Shiomi, Naoko Saito, and Yoshifumi Ota
    • Organizer
      European Geosciences Union
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2013 Annual Research Report
  • [Presentation] Minor Gas Constituents and Cloud Properties Retrieved from TANSO-FTS/GOSAT Spectra2013

    • Author(s)
      Imasu R., Saitoh N., Hayashi Y., Someya Y., Arai Y., Kondo H., Machida T., Matsueda H., Sawa Y., Niwa Y., Fomin B.
    • Organizer
      Inter. Sympo. on Atmos. Rad. And Dynam. (ISIRD-2013)
    • Place of Presentation
      Saint-Petersburg-Petrodvorets, Russia
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] TANSO-FTS/GOSAT Band4 データを用いた南極上空の極域成層圏雲の検出2013

    • Author(s)
      染谷有, 今須良一, 太田芳文, 齋藤尚子
    • Organizer
      第19回大気化学討論会
    • Place of Presentation
      石川県七尾市 和倉
    • Related Report
      2013 Annual Research Report
  • [Presentation] 温室効果気体計測に関する最近の研究動向2012

    • Author(s)
      今須良一
    • Organizer
      ロシア中央気象台温室効果気体に関するワークショップ
    • Place of Presentation
      モスクワ(ロシア)(招待)
    • Year and Date
      2012-03-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 含フッ素不飽和化合物の大気寿命評価2012

    • Author(s)
      徳橋和明、陳亮, 他
    • Organizer
      産総研環境・エネルギーシンポジウム
    • Place of Presentation
      つくば
    • Year and Date
      2012-02-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] GOSAT 衛星を用いたフロン類等大気中微量気体の解析2012

    • Author(s)
      稲子谷昂子、今須良一、林洋司、塩見慶
    • Organizer
      日本気象学会2012年春季大会
    • Place of Presentation
      つくば市つくば国際会議場
    • Related Report
      2012 Annual Research Report
  • [Presentation] GOSAT specific observation targeting urban CO2 emissions2010

    • Author(s)
      今須良一
    • Organizer
      American Geophysical Union, fall meeting
    • Place of Presentation
      サンフランシスコ、アメリカ合衆国
    • Year and Date
      2010-12-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Retrieval of minor constituents using GOSAT TANSO-FTS thermal infrared (TIR) data

    • Author(s)
      Ryoichi Imasu
    • Organizer
      International workshop on greenhouse gas measurement from space, USA
    • Place of Presentation
      California, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] Simultaneous observations of column abundances and profiles of CH4 by GOSAT: Validation of GOSAT CH4 products using aircraft CH4 measurements over Guam

    • Author(s)
      Naoko Saitoh
    • Organizer
      International workshop on greenhouse gas measurement from space, USA
    • Place of Presentation
      California, USA
    • Related Report
      2012 Annual Research Report
  • [Presentation] NICAM-TMを用いたメタンの大気輸送シミュレーション

    • Author(s)
      高見澤秀樹, 今須良一, 丹羽洋介, Prabir K. Patra
    • Organizer
      第18回大気化学討論会
    • Place of Presentation
      福岡市ホテルバーレンス小野屋
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2025-01-30  

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