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The study on the mechanism of ferromagnetic metal-insulator transition and novel quantum properties in chromium oxides

Research Project

Project/Area Number 22244041
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

UEDA Yutaka  東京大学, 物性研究所, 教授 (20127054)

Co-Investigator(Renkei-kenkyūsha) UEDA Hiroaki  京都大学, 理学研究科, 准教授 (10373276)
ISOBE Masahiko  東京大学, 物性研究所, 技術専門職員 (70396919)
YAMAUCHI Toru  東京大学, 物性研究所, 技術専門職員 (10422445)
SHIN Shigi  東京大学, 物性研究所, 教授 (00162785)
FUJIWARA Naoki  京都大学, 人間環境学研究科, 准教授 (60272530)
OHTA Yukinori  千葉大学, 理学研究科, 教授 (70168954)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥45,110,000 (Direct Cost: ¥34,700,000、Indirect Cost: ¥10,410,000)
Fiscal Year 2012: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Fiscal Year 2011: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Fiscal Year 2010: ¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Keywords強相関電子系 / 物性実験 / クロム酸化物 / 電磁気物性 / 金属絶縁体転移 / ホランダイト酸化物 / クロムホランダイト / 構造相転移 / 層状ペロフスカイト物質 / マンガンホランダイト / パイエルス転移 / 金属強磁性
Research Abstract

Detailed structure analysis by synchrotron x-ray diffraction experiments and the electronic structure calculations demonstrate that the novel ferromagnetic metal-insulator transition in K2Cr8O16 is caused by a Peierls instability in the quasi-one-dimensional column structure made of four coupled Cr-O chains running in the c direction, leading to the formation of tetramers of Cr ions below the transition temperature. This provides a rare example of the Peierls transition of fully spin-polarized electron systems.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (44 results)

All 2013 2012 2011 2010 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (24 results) (of which Invited: 5 results) Remarks (1 results)

  • [Journal Article] Interlayer Switching of Reduction in Layered Oxide, Bi4V2O11-δ (0?δ?1)2013

    • Author(s)
      Y. Zhang and Y. Ueda
    • Journal Title

      Inorg. Chem

      Volume: 52 Issue: 9 Pages: 5206-5213

    • DOI

      10.1021/ic400111w

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure and Electromagnetic Properties of Manganese Hollandite, KxMn8O162012

    • Author(s)
      T. Kuwabara, M. Isobe, H. Gotou, T. Yagi, D. Nishio-Hamane, and Y. Ueda
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Issue: 10 Pages: 104701-104701

    • DOI

      10.1143/jpsj.81.104701

    • NAID

      210000109733

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] μ+SR study on ferromagnetic hollandites, K2Cr8O16 and Rb2Cr8O162012

    • Author(s)
      J. Sugiyama, H. Nozaki . M. Mansson, K. Pr?a, D. Andreica, A. Amato, M. Isobe, and Y. Ueda
    • Journal Title

      Phys. Rev. B

      Volume: 85

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared phonons and specific heat in the gapped quantum magnet Ba3Cr2O82012

    • Author(s)
      Z. Wang, M. Schmidt, A. Gunther, F. Mayr, Y. Wan, S.-H. Lee, H. Ueda, Y. Ueda, A. Loidl, and J. Deisenhofer
    • Journal Title

      Phys. Rev. B

      Volume: 85 Issue: 22

    • DOI

      10.1103/physrevb.85.224304

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Structural Change in the Novel Ferromagnetic2012

    • Author(s)
      Akiko NAKAO
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 81 Issue: 5 Pages: 054710-054710

    • DOI

      10.1143/jpsj.81.054710

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic hollandite K2Cr8O162012

    • Author(s)
      J. Sugiyama
    • Journal Title

      Physics Procedia

      Volume: 30 Pages: 186-189

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] u+SR study on ferromagnetic hollandites, K2Cr8O16 and Rb2Cr8O162012

    • Author(s)
      J. Sugiyama
    • Journal Title

      Physical Review B

      Volume: 85 Issue: 21

    • DOI

      10.1103/physrevb.85.214407

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Peierls Mechanism of the Metal-Insulator Transition in Ferromagnetic Hollandite K2Cr80162011

    • Author(s)
      T.Toriyama, A.Nakao, H.Nakao, Y.Murakami, K.Hasegawa, M.
    • Journal Title

      Phys.Rev.Lett.

      Volume: 107 Issue: 26

    • DOI

      10.1103/physrevlett.107.266402

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic order, transport and infrared optical properties in the ACrO3 system (A = Ca, Sr, and Pb)2011

    • Author(s)
      A. C. Komarek, T. Moller, M. Isobe, Y. Drees, H. Ulbrich, M. Azuma, M. T. Fernandez-Diaz, A. Senyshyn, M. Hoelzel, G. Andre, Y. Ueda, M. Gruninger, and M. Braden
    • Journal Title

      Phys. Rev. B

      Volume: 84 Issue: 12

    • DOI

      10.1103/physrevb.84.125114

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electromagnetic properties of hollandite K2V8O16 under pressure2011

    • Author(s)
      T. Yamauchi, H. Ueda, M. Isobe, and Y. Ueda
    • Journal Title

      Phys. Rev. B

      Volume: 84 Issue: 11

    • DOI

      10.1103/physrevb.84.115104

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of an antiferromagnetic metal : CaCrO_32011

    • Author(s)
      P.A.Bhobe
    • Journal Title

      Physical Review B

      Volume: 83 Issue: 16 Pages: 165132-165132

    • DOI

      10.1103/physrevb.83.165132

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Ferromagnetic Chromium Chalcogenides, ACr5Te8 (A = K, Cs and Rb)2011

    • Author(s)
      S. Yamazaki
    • Journal Title

      Solid State Phenomena

      Volume: 170 Pages: 17-20

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-insulator transition in the hollandite K_2V_8O_<16> with a frustrated zigzag ladder probed by ^<51>V NMR2011

    • Author(s)
      Y.Shimizu, K.Okai, M.Itoh, M.Isobe, J.Yamaura, T.Yamauchi, Y.Ueda
    • Journal Title

      Phys.Rev.B

      Volume: 83 Issue: 15

    • DOI

      10.1103/physrevb.83.155111

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dimerization and Charge Order in Hollandite K2V8O162011

    • Author(s)
      A. C. Komarek
    • Journal Title

      Physical Review Letters

      Volume: 107 Issue: 2

    • DOI

      10.1103/physrevlett.107.027201

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic interactions and orbital state in double chain systems investigated by NMR measurements2011

    • Author(s)
      M. Itoh
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 320

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Ferromagnetic Chromium Chalcogenides, ACr5Te8 (A=K, Cs and Rb)2011

    • Author(s)
      S.Yamazaki, Y.Ueda
    • Journal Title

      Solid State Phenomena

      Volume: 170 Pages: 17-20

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of an antiferromagnetic metal : CaCrO32011

    • Author(s)
      P.A.Bhobe, Y.Ueda, 他12名
    • Journal Title

      Physical Review B

      Volume: 83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Peierls Mechanism of the Metal-Insulator Transition in Ferromagnetic Hollandite K2Cr8O162011

    • Author(s)
      T.Toriyama, Y.Ueda, 他9名
    • Journal Title

      Physical Review Letters

      Volume: 107

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structures and magnetic properties of pseudo-hollandite chromium sulfides2010

    • Author(s)
      S. Yamazaki and Y. Ueda
    • Journal Title

      J. Solid State Chem.

      Volume: 183 Issue: 9 Pages: 1905-1911

    • DOI

      10.1016/j.jssc.2010.03.013

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] Unusual bismuth and vanadium chemistry in a low dimensional oxide system2013

    • Author(s)
      Y. Zhang
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学東広島キャンパス(広島)
    • Year and Date
      2013-03-28
    • Related Report
      2012 Final Research Report
  • [Presentation] 物質設計と物質開発2013

    • Author(s)
      上田 寛
    • Organizer
      第1回京都大学理学研究科化学専攻無機化学合同セミナー
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ホランダイト型KxMn8O16のX線光電子分光2013

    • Author(s)
      福沢 真
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学東広島キャンパス(広島)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Unusual bismuth and vanadium chemistry in a low dimensional oxide system2013

    • Author(s)
      Yaoqing Zhang
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      広島大学東広島キャンパス(広島)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Hollandite K2Cr8O16: Crystal Growth under High Pressure and Ferromagnetic Metal-Insulator Transition2012

    • Author(s)
      Y. Ueda
    • Organizer
      Freiberg HighPressure Symposium 2012
    • Place of Presentation
      Freiberg, Germany
    • Year and Date
      2012-10-10
    • Related Report
      2012 Final Research Report
  • [Presentation] ホランダイト構造の強磁性体 K2Cr8O16 のμSR2012

    • Author(s)
      杉山純
    • Organizer
      日本物理学会 2012 秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(横浜)
    • Year and Date
      2012-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Novel Ferromagnetic Metal- Insulator Transition in K2Cr8O16 -Peierls Transition of Spinless Fermion-2012

    • Author(s)
      Y. Ueda
    • Organizer
      18th International Conference on Solid Compounds of Transition Elements, SCTE2012
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2012-04-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Novel Ferromagnetic Metal-Insulator Transition in K2Cr8O16 -Peierls Transition of Spinless Fermion-2012

    • Author(s)
      Yutaka Ueda
    • Organizer
      18th International Conference on Solid Compounds of Transition Elements, SCTE2012
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] Peierls Mechanism of MI Transition in Ferromagnetic K2Cr8O162012

    • Author(s)
      Yutaka Ueda
    • Organizer
      IUCr5 Commission on High Pressure 2012 Meeting, IUCrHP2012/QuBS2012
    • Place of Presentation
      Mito, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Hollandite K2Cr8O16: Crystal Growth under High Pressure and Ferromagnetic Metal-Insulator Transition2012

    • Author(s)
      Yutaka Ueda
    • Organizer
      Freiberg High Pressure Symposium 2012
    • Place of Presentation
      Freiberg, Germany
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ホランダイト構造の強磁性体K2Cr8O16のuSR2012

    • Author(s)
      杉山 純
    • Organizer
      日本物理学会2012秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(横浜)
    • Related Report
      2012 Annual Research Report
  • [Presentation] A new vanadate oxide with quasi-one-dimensionalspin chains2012

    • Author(s)
      Yaoqing Zhang
    • Organizer
      日本物理学会2012秋季大会
    • Place of Presentation
      横浜国立大学常盤台キャンパス(横浜)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 遷移金属混合原子価酸化物の磁性と伝導性2012

    • Author(s)
      上田 寛
    • Organizer
      名古屋大学ベンチャー・ビジネス・ラボラトリー第16回VBLシンポジウム
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Hollandites : novel metal-insulator transitions2011

    • Author(s)
      上田寛
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス(大阪)
    • Year and Date
      2011-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Cr-Hollandite の圧力効果II2011

    • Author(s)
      山内徹
    • Organizer
      日本物理学会 2011 年秋季大会
    • Place of Presentation
      富山大学五福キャンパス(富山)
    • Year and Date
      2011-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] クロムホランダイトの強磁性金 属絶縁体転移における構造変化と相転移機構2011

    • Author(s)
      上田寛
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学五福キャンパス(富山)
    • Year and Date
      2011-09-23
    • Related Report
      2012 Final Research Report
  • [Presentation] K2M8O16 (M = Ti, V, Cr, Mn) ? a novel class of oxides with unusual properties -2011

    • Author(s)
      Y. Ueda, Hollandites
    • Organizer
      Tokyo-Cologne Workshop on Strongly Correlated Transition-Metal Compounds,
    • Place of Presentation
      Cologne, Germany
    • Year and Date
      2011-09-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Electronic States of Half-Metallic Chromium Oxides Proved by 53Cr NMR2011

    • Author(s)
      H. Takeda
    • Organizer
      26th International Conference on Low Temperature Physics
    • Place of Presentation
      Beijing, China
    • Year and Date
      2011-08-14
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Ferromagnetic and Metal-Insulator Transitions in Chromium Hollandite2011

    • Author(s)
      Y. Ueda
    • Organizer
      Advances in Applied Physics & Materials Science Congress
    • Place of Presentation
      Antalya, Turkey
    • Year and Date
      2011-05-13
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Hidden frustration behind the unique ferromagnetic metal-insulator transition of K2Cr8O162011

    • Author(s)
      M. Isobe
    • Organizer
      International Conference on Frustration in Condensed Matter (ICFCM)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2011-01-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Hollandites: K2M8O16 (M = Ti, V, Cr, Mn) -a novel class of oxides with unusual properties-2011

    • Author(s)
      Yutaka Ueda
    • Organizer
      Tokyo-Cologne Workshop on Strongly Correlated Transition-Metal Compounds
    • Place of Presentation
      Cologne, Germany
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Cr-Hollanditeの圧力効果II2011

    • Author(s)
      山内 徹
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学 五福キャンパス (富山)
    • Related Report
      2011 Annual Research Report
  • [Presentation] クロムホランダイトの強磁性金属絶縁体転移における構造変化と相転移機構2011

    • Author(s)
      上田 寛
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学 五福キャンパス (富山)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 強磁性型クロム酸化物CrO2およびK2Cr8O16における局所磁性と電子状態-53Cr核NMR-2011

    • Author(s)
      武田 晃
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学 五福キャンパス (富山)
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.issp.u-tokyo.ac.jp/maincontents/news.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2020-05-15  

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