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Development of photoelectron diffraction of single oriented molecules

Research Project

Project/Area Number 22244051
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Atomic/Molecular/Quantum electronics
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

YAGISHITA Akira  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 教授 (80157966)

Co-Investigator(Kenkyū-buntansha) ADACHI Jun-ichi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 研究機関講師 (10322629)
FUJIKAWA Takashi  千葉大学, 融合科学研究科, 教授 (30114987)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥46,930,000 (Direct Cost: ¥36,100,000、Indirect Cost: ¥10,830,000)
Fiscal Year 2012: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2011: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Fiscal Year 2010: ¥27,820,000 (Direct Cost: ¥21,400,000、Indirect Cost: ¥6,420,000)
Keywords配向分子 / 光電子回折法 / 運動量画像測定 / 分子構造解析 / 干渉効果 / 形状共鳴 / X線光電子回折法 / 時間依存密度汎関数法 / 分子配向制御 / X線光電子回折理論 / 光電子回折像 / 光電子散乱理論
Research Abstract

We have developed a new molecular structure determination method, based on multiple-scattering x-ray photoelectron diffraction (XPD) calculations.This method has been applied to our XPD data of several molecules having differentequilibrium geometries. Then, it has been confirmed that by our method the parameters of molecular structure can be determined. We have constructed a new experimental scheme, which consists of a photoelectron velocity map imaging spectrometer and sample gas of oriented molecules. The molecular orientation was controlled by the strong laser field.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (41 results)

All 2013 2012 2011 2010 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (24 results) (of which Invited: 4 results) Remarks (4 results)

  • [Journal Article] Angular Correlation Between B K-VV Auger Electrons of BF3 Molecules and Coincident Fragment Ions: Manifestation of the Difference Between the Angular Correlation and Molecular Frame Auger Electron Angular Distribution2013

    • Author(s)
      T. Mizuno, J. Adachi, M. Kazama, M. Stener, P. Decleva, and A. Yagishita
    • Journal Title

      Phys. Rev. Lett

      Volume: 110巻 Issue: 4

    • DOI

      10.1103/physrevlett.110.043001

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiple-scattering calculations for 1sphotoelectron angular distributions from single oriented molecules in the energy region above 50eV2012

    • Author(s)
      M. Kazama, H. Shinotsuka, T. Fujikawa, M. Stener, P. Decleva, J. Adachi, T. Mizuno, and A. Yagishita
    • Journal Title

      J. Electron Spectrosc. And Relat. Phenom

      Volume: 185巻 Pages: 535-545

    • URL

      http://dx.doi.org/10.1016/j.elspec.2012.10.009

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] C Is photoelectron angular distributions from fixed-in-space CO molecules in the high-energy continuum >50 eV2012

    • Author(s)
      J. Adachi, M. Kazama. T. Teramoto, N. Miyauchi, T. Mizuno, M. Yamazaki, T. Fujikawa, A. Yagishita
    • Journal Title

      Journal of Physics B

      Volume: 45 Issue: 19 Pages: 194007-194007

    • DOI

      10.1088/0953-4075/45/19/194007

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions of BF3: A sensitive probe of the shape resonance in the F 1s continuum2012

    • Author(s)
      T. Mizuno, J. Adachi, N. Miyauchi, M. Kazama, M. Stener, P. Decleva, and A. Yagishita
    • Journal Title

      J. Chem. Phys

      Volume: 136巻

    • URL

      http://dx.doi.org/10.1063/1.3687006

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multipule-scattering calculations for 1s photoelectron angular distributions from single oriented molecules in the energy region above 50eV2012

    • Author(s)
      M. Kazama
    • Journal Title

      J. Electron Spectrosc. and Relat. Phenom.

      Volume: 185 Pages: 535-545

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions in core O 1s ionozation of H2CO2012

    • Author(s)
      M. Stener
    • Journal Title

      J. Phys. B: At. Mol. Opt. Phys.

      Volume: 45 Issue: 19 Pages: 194004-194004

    • DOI

      10.1088/0953-4075/45/19/194004

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recoil frame photoelectron angular distributions of BF_3 : A sensitive probe of the shape resonance in the F 1s continuum2012

    • Author(s)
      T.Mizuno
    • Journal Title

      The Journal of Chemical Physics

      Volume: 136 Issue: 7

    • DOI

      10.1063/1.3687006

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] O 1s photoionization dynamics in oriented NO_22011

    • Author(s)
      M.Stener, P.Decleva, M.Yamazaki, J.Adachi, A.Yagishita
    • Journal Title

      The Journal of Chemical Physics

      Volume: 134 Issue: 18

    • DOI

      10.1063/1.3584202

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N 1s photoelectron angular distributions from fixed-in-space NO2 molecules2010

    • Author(s)
      M. Yamazaki, J. Adachi, Y. Kimura, M. Stener, P. Decleva, and A. Yagishita
    • Journal Title

      Stereodynamics and symmetry considerations

      Volume: 133巻 Issue: 16 Pages: 164301-164301

    • DOI

      10.1063/1.3505549

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] N 1s photoelectron 'angular distributions from fixed-in-space NO_2 mole cules : Stereodynamics and symmetry considerations2010

    • Author(s)
      M.Yamazaki
    • Journal Title

      The Journal of Chemical Physics

      Volume: 133

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study of X-ray photoelectron diffraction for fixed-in-space CO molecules2010

    • Author(s)
      M.Kazama
    • Journal Title

      Chemical Physics

      Volume: 373 Pages: 261-266

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoemission dynamics in the molecular frame2010

    • Author(s)
      A.Yagishita
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 212

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 分子座標系で観測する孤立自由分子の光電離ダイナミクス2010

    • Author(s)
      足立純一
    • Journal Title

      日本物理学会誌

      Volume: 65 Pages: 416-424

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Interatomic resonance Auger in core-level photoemission from small molecules2013

    • Author(s)
      A. Yagishita
    • Organizer
      50 Years of Atomic Physics with Synchrotron Radiation (invited talk)
    • Place of Presentation
      NIST, Gaithersburg, MD, USA
    • Year and Date
      2013-06-18
    • Related Report
      2012 Final Research Report
  • [Presentation] Photoelectron Diffraction from Single Oriented Molecules2013

    • Author(s)
      A. Yagishita
    • Organizer
      CC3DMR 2013 (invited talk)
    • Place of Presentation
      Jeju Island, South Korea
    • Related Report
      2012 Final Research Report
  • [Presentation] Physics on photoemission from oriented molecules: past, present, and future2013

    • Author(s)
      A. Yagishita
    • Organizer
      第29回化学反応討論会(招待講演)
    • Place of Presentation
      東北大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Physics on photoemission from oriented molecules: past, present and future2013

    • Author(s)
      A. Yagishita
    • Organizer
      第29回化学反応討論会
    • Place of Presentation
      東北大学片平キャンパス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Interatomic resonance Auger in core-level photoemission from small molecules2013

    • Author(s)
      A. Yagishita
    • Organizer
      Work shop 5: 50 Years of Atomic Physics with Synchrotron Rafdiation
    • Place of Presentation
      NIST, Gaithersburg, MD, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Photoelectron Diffraction from Single Oriented Molecules2013

    • Author(s)
      A. Yagishita
    • Organizer
      CC3DMR 2013
    • Place of Presentation
      Jeju Island, South Korea
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 空間固定されたCH_3F分子におけるF1s光電子角度分布の軟X線の偏光と波長による制御2012

    • Author(s)
      水野智也
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学西宮上ケ原キャンパス(兵庫県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Molecular frame photoelectron angular distributions as a structural probe of single molecules2012

    • Author(s)
      A. Yagishita
    • Organizer
      Gordon Research Conference: Photions, Photoionization & Photodetachment (invited talk)
    • Place of Presentation
      Galveston, TX, USA
    • Related Report
      2012 Final Research Report
  • [Presentation] EUV-FELとYAGレーザーの同期システムの開発研究2012

    • Author(s)
      水野智也
    • Organizer
      原子衝突学会第37回年会
    • Place of Presentation
      電気通信大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 多重散乱理論による内殻光電離過程の研究2012

    • Author(s)
      風間美里
    • Organizer
      原子衝突学会第37回年会
    • Place of Presentation
      電気通信大学
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] C1s and F1s photoelectron angular distribution from oriented CH3F molecules: a combined theoretical TDDFT and experimental study2012

    • Author(s)
      M. Stener
    • Organizer
      MPS 2012
    • Place of Presentation
      Berlin, Germany
    • Related Report
      2012 Annual Research Report
  • [Presentation] EUV-FELとYAGレーザーの同期実験2012

    • Author(s)
      水野智也
    • Organizer
      日本物理学会 2012年秋季大会
    • Place of Presentation
      横浜国立大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Molecular frame photoelectron angular distributions as a structural probe of single molecules2012

    • Author(s)
      A.Yagishita
    • Organizer
      Gordon Research Conference ; Photoions, Photoionization & Photodetachment
    • Place of Presentation
      Galveston, TX, (USA)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分子座標系で観測する単一分子の光電離ダイナミクス研究の基礎と応用2011

    • Author(s)
      柳下明
    • Organizer
      理研シンポジウム第2回拡がる原子分子物理研究
    • Place of Presentation
      理化学研究所(埼玉県)(招待講演)
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分子座標系でのBF_3分子F1s光電子角度分布測定による光電離ダイナミクスの研究2011

    • Author(s)
      水野智也
    • Organizer
      分子科学討論会2011
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分子座標系で観測する孤立自由分子の光電離ダイナミクス2011

    • Author(s)
      柳下明
    • Organizer
      日本学術振興会第183委員会第4回定例研究会
    • Place of Presentation
      東京理科大学森戸記念館(東京都)(招待講演)
    • Year and Date
      2011-06-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光電子回折理論による超高速分子ダイナミクスの理解の試み2011

    • Author(s)
      風間美里
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Year and Date
      2011-03-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of photoelectron diffraction theory to ultrafast molecular dynamics2011

    • Author(s)
      M. Kazama
    • Organizer
      International Symposium on (e,2e), Double Photo-ionization & Related Topics (invited talk)
    • Place of Presentation
      Dublin, Ireland
    • Related Report
      2012 Final Research Report
  • [Presentation] Application of photoelectron diffraction theory to ultrafast molecular dynamics2011

    • Author(s)
      M.Kazama
    • Organizer
      ICPEAC2011 "Correlation and coherence" satellite
    • Place of Presentation
      University College of Dublin (Ireland)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] F 1s photoelectron angular distribution from fixed-in-space BF_3 molecules2011

    • Author(s)
      T.Mizuno
    • Organizer
      ICPEAC2011 "Correlation and coherence" satellite
    • Place of Presentation
      University College of Dublin (Ireland)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 多重散乱モデルで解き明かす配向分子の内殻光電離ダイナミクス2011

    • Author(s)
      柳下明
    • Organizer
      原子衝突研究協会第36回年会
    • Place of Presentation
      新潟大学(新潟県)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Application of photoelectron diffraction theory to ultrafast molecular Dynamics2011

    • Author(s)
      M.Kazama
    • Organizer
      International Symposium on (e,2e), Double Photo-ionization & Related Topics
    • Place of Presentation
      Dublin, Ireland(invited talk)
    • Related Report
      2010 Annual Research Report
  • [Presentation] F 1s photoelectron angular distribution from fixed-in-space BF_3 molecules2011

    • Author(s)
      T.Mizuno
    • Organizer
      International Symposium on (e,2e), Double Photo-ionization & Related Topics
    • Place of Presentation
      Dublin, Ireland
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of photoelectron diffraction theory to ultrafast molecular dynamics2010

    • Author(s)
      M.Kazama
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://molecule.kek.jp

    • Related Report
      2012 Final Research Report
  • [Remarks] 柳下・基礎光化学物理研究室

    • URL

      http://molecule.kek.jp

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://molecule.kek.jp

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://molecule.kek.jp

    • Related Report
      2010 Annual Research Report

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Published: 2010-11-30   Modified: 2019-07-29  

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