| Budget Amount *help |
¥48,880,000 (Direct Cost: ¥37,600,000、Indirect Cost: ¥11,280,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2011: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000)
Fiscal Year 2010: ¥24,830,000 (Direct Cost: ¥19,100,000、Indirect Cost: ¥5,730,000)
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| Outline of Final Research Achievements |
Bowl-shaped π-conjugated molecule with a partial structure of fullerene (π bowls) could provide the third key materials in addition to fullerenes and carbon nanotubes in non-planar carbon materials. In this study, we focused on a π bowl sumanene, and conducted to reveal the potential for organic synthesis and materials as a carbon nanoscience and nanotechnology from Japan. More specifically, we studied the following subjects: 1. development of molecular transformation of sumanene, 2. synthesis of organometallic complexes using sumanene as a ligand, 3. development of synthetic method for the carbon materials utilizing the strain energy of sumanene, 4. dynamic behavior and molecular recognition on a surface of metal substrate.
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