Structural Characterization and Inhomogeneity Control of Polymer Network toward Realization of Ideal Polymer Network

• Project/Area Number: 22245018
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: The University of Tokyo
• Principal Investigator: SHIBAYAMA Mitsuhiro 東京大学, 物性研究所, 教授 (00175390)
• Co-Investigator(Kenkyū-buntansha): SAKAI Takamasa 東京大学, 工学系研究科, 助教 (70456151)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥48,880,000 (Direct Cost: ¥37,600,000、Indirect Cost: ¥11,280,000); Fiscal Year 2012: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000); Fiscal Year 2011: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000); Fiscal Year 2010: ¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
• Keywords: 高分子物性 / ゲル / ゴム弾性 / 理想網目 / 不均一性 / ゲル化 / 中性子散乱 / 小角中性子散乱 / Tetra-PEG / 理想ポリマーネットワーク / イオンゲル / 動的光散乱 / フェノール樹脂 / トポロジカル欠陥 / テトラペグゲル / 古典ゴム弾性論 / 動的粘弾性 / モジュールカップリング法 / 古典ゴム弾生論

Research Abstract

We focused on precisely-controlled “ideal” polymer networks prepared by the “module building” method, and investigated the structure-property relationship on fundamental problems of rubber elasticity as well as polymer physics. With the aid of various kinds of experimental methods, such as small-angle neutron scattering (SANS), dynamic light scattering (DLS), small-angle X-ray scattering (SAXS), tensile measurements, rheology, swelling/shrining measurements, differential scanning calorimetry (DSC), infrared spectroscopy (IR), and computer simulation, we carried out intensive studies to elucidate the structure-property relationship of not only Tetra-PEG gels but also natural rubbers, phenol resins, threadlike micelles, and other systems. We succeeded in formation of precisely-controlled polymer network science.

Research Products

• [Journal Article] Mechanical propert ies of a polymer network of Tetra-PEG gel (2013)
  • Author(s): Asumi Sugimura, et al.
  • Journal Title: Polymer Journal Volume: 45 Issue: 3 Pages: 300-306
  • DOI: 10.1038/pj.2012.149
  • Peer Reviewed
• [Journal Article] High-performance ion gel with tetra-PEG network (2012)
  • Author(s): K.Fujii, H.Asai, T.Ueki (equally contributed), T.Sakai, S.Imaizumi, U.-I.Chung, M.Watanabe, M.Shibayama
  • Journal Title: Soft Matter Volume: 8 Issue: 6 Pages: 1756-1759
  • DOI: 10.1039/c2sm07119c
  • Peer Reviewed
• [Journal Article] Effect of swelling and deswelling on the elasticity of polymer networks in the dilute to semi-dilute region (2012)
  • Author(s): Sakai, T., Kurakazu, M., Akagi, Y., Shibayama, M., Chung, U.
  • Journal Title: Soft Matter Volume: 8 Issue: 9 Pages: 2730-2736
  • DOI: 10.1039/c2sm07043j
  • Peer Reviewed
• [Journal Article] Atomistic molecular dynamics study of cross-linked phenolic resins (2012)
  • Author(s): Izumi, A., Nakao, T., Shibayama, M.
  • Journal Title: Soft Matter Volume: 8 Issue: 19 Pages: 5283-5292
  • DOI: 10.1039/c2sm25067e
  • Peer Reviewed
• [Journal Article] Anomalous volume phase transition in a polymer gel with alternativehydrophilic-amphiphilic sequence (2012)
  • Author(s): Kamata, H., Chung, U., Shibayama, M., Sakai, T.,
  • Journal Title: Soft Matter Volume: 8 Issue: 26 Pages: 2876-2879
  • DOI: 10.1039/c2sm25168j
  • Peer Reviewed
• [Journal Article] Structure-mechanical property relationship of tough hydrogels (2012)
  • Author(s): Shibayama, M.
  • Journal Title: Soft Matter Volume: 8 Issue: 31 Pages: 8030-8038
  • DOI: 10.1039/c2sm25325a
  • Peer Reviewed
• [Journal Article] Kinetic Study for AB-Type Coupling Reaction of Tetra-Arm Polymers (2012)
  • Author(s): Nishi, K., Fujii, K., Chijiishi, M., Katsumoto, Y., Chung, U., Sakai, T., Shibayama, M.
  • Journal Title: Macromolecules Volume: 45 Issue: 2 Pages: 1031-1036
  • DOI: 10.1021/ma202386k
  • Peer Reviewed
• [Journal Article] Stress Relaxation and Hysteresis of Nanocomposite Gel Investigated by SAXS and SANS Measurement (2012)
  • Author(s): Nishida, T., Obayashi, A., Haraguchi, K., Shibayama, M.
  • Journal Title: Polymer Volume: 53 Issue: 20 Pages: 4533-4538
  • DOI: 10.1016/j.polymer.2012.07.038
  • Peer Reviewed
• [Journal Article] Rubber Elasticity for Incomplete Polymer Networks (2012)
  • Author(s): Nishi, K., Chijiishi, M., Katsumoto, Y., Nakao, T., Fujii, K., Chung, U., Noguchi, H., Sakai, T., Shibayama, M., J.Chem.
  • Journal Title: Phys Volume: 137 Issue: 22 Pages: 224903-224903
  • DOI: 10.1063/1.4769829
  • Peer Reviewed
• [Journal Article] Structural analysis of high performance ion gel comprising tetra-PEG network (2012)
  • Author(s): H. Asai, K. Fujii, T. Ueki, T. Sakai, U. Chung, M. Watanabe, Y. S. Han, T. H. Kim, M. Shibayama
  • Journal Title: Macromolecules Volume: 45 Issue: 9 Pages: 3902-3909
  • DOI: 10.1021/ma300244u
  • Peer Reviewed
• [Journal Article] Optimization of the thickness of a ZnS/(LiF)-Li-6 scintillator for a high-resolution detector installed on a focusing small-angle neutron scattering spectrometer (SANS-U) (2012)
  • Author(s): Iwase, H., Katagiri, M., Shibayama, M.
  • Journal Title: J. Appl. Cryst Volume: 45 Issue: 3 Pages: 507-512
  • DOI: 10.1107/s0021889812008928
  • Peer Reviewed
• [Journal Article] Star-Shaped Trimeric Quaternary Ammonium Bromide Surfactants: Adsorption and Aggregation Properties (2012)
  • Author(s): Yoshimura, T., Kusano, T., Iwase, H., Shibayama, M.
  • Journal Title: Langmuir Volume: 28 Issue: 25 Pages: 9322-9331
  • DOI: 10.1021/la301220y
  • Peer Reviewed
• [Journal Article] Small-angle neutron scattering on polymer gels: phase behavior, inhomogeneities and deformation mechanisms (2011)
  • Author(s): Shibayama, M.
  • Journal Title: Polym. J. Volume: 43 Issue: 1 Pages: 155-163
  • DOI: 10.1038/pj.2010.110
  • NAID: 10027623590
  • Peer Reviewed
• [Journal Article] SANS Studies on Tetra-PEG Gel under Uniaxial Deformation (2011)
  • Author(s): Matsunaga, T., Asai, H., Akagi, Y., Sakai, T., Chung, U., Shibayama, M.
  • Journal Title: Macromolecules Volume: 44 Issue: 5 Pages: 1203-1210
  • DOI: 10.1021/ma102658e
  • Peer Reviewed
• [Journal Article] Precise Control and Prediction of Hydrogel Degradation Behavior (2011)
  • Author(s): Li, X., Tsutsui, Y., Matsunaga, T., Shibayama, M., Chung, U., Sakai, T.
  • Journal Title: Macromolecules Volume: 44 Issue: 9 Pages: 3567-3571
  • DOI: 10.1021/ma2004234
  • Peer Reviewed
• [Journal Article] Examination of the Theories of Rubber Elasticity Using an Ideal Polymer Network (2011)
  • Author(s): Akagi, Y., Katashima, T., Katsumoto, Y., Fujii, K., Matsunaga, T., Chung, U., Shibayama, M., Sakai, T.
  • Journal Title: Macromolecules Volume: 44 Issue: 14 Pages: 5817-5821
  • DOI: 10.1021/ma201088r
  • Peer Reviewed
• [Journal Article] Structure and physical properties of dried Tetra-PEG gel (2011)
  • Author(s): Nomoto, Y., Matsunaga, T., Sakai, T., Tosaka, M., Shibayama
  • Journal Title: M., Polymer Volume: 52 Issue: 18 Pages: 4123-4128
  • DOI: 10.1016/j.polymer.2011.06.053
  • Peer Reviewed
• [Journal Article] Dynamic light scattering and small-angle neutron scattering studies on phenolic (2011)
  • Author(s): Izumi, A., Takeuchi, T., Nakao, T., Shibayama, M.
  • Journal Title: Polymer Volume: 52 Issue: 19 Pages: 4355-4361
  • DOI: 10.1016/j.polymer.2011.06.059
  • Peer Reviewed
• [Journal Article] Static Structure of Polyrotaxane in Solution Investigated by Contrast Variation Small-Angle Neutron Scattering (2011)
  • Author(s): H.Endoh, M.Shibayama, et al.
  • Journal Title: Polym.J. Volume: 43 Issue: 2 Pages: 155-163
  • DOI: 10.1038/pj.2009.325
  • NAID: 10027788941
  • Peer Reviewed
• [Journal Article] Structural aspects of the LCST phase behavior of poly(benzyl methacrylate) in room temperature ionic liquid (2011)
  • Author(s): K.Fujii, T.Uekl (equally contributed), K.Niitsuma, T.Matsunaga, M.Watanabe, M.Shibayama
  • Journal Title: Polymer Volume: 52 Issue: 7 Pages: 1589-1595
  • DOI: 10.1016/j.polymer.2011.01.037
  • Peer Reviewed
• [Journal Article] Modernization of the small-angle neutron scattering spectrometer SANS-U by upgrade to a focusing SANS spectrometer (2011)
  • Author(s): H.Iwase, M.Shibayama, et al.
  • Journal Title: J.Appl.Cryst. Volume: 44 Issue: 3 Pages: 558-568
  • DOI: 10.1107/s0021889811007527
  • Peer Reviewed
• [Journal Article] Common Origin of Dynamics Heterogeneity and Cooperatively Rearranging Region in Polymer Melts (2011)
  • Author(s): M.Asai, M.Shibayama, Y.Koike
  • Journal Title: Macromolecules Volume: 44 Issue: 16 Pages: 6615-6624
  • DOI: 10.1021/ma201341d
  • Peer Reviewed
• [Journal Article] Synthesis and Properties of a Deuterated Phenolic Resin (2011)
  • Author(s): A.Izumi, T.Nakao, M.Shibayama
  • Journal Title: Polym.Sci. ; Polym.Chem.Ed. Volume: 49 Issue: 23 Pages: 4914-4917
  • DOI: 10.1002/pola.24948
  • Peer Reviewed
• [Journal Article] Experimental Evidences for Molecular Origin of low-Q peak in Neutron/ X-ray Scattering of 1-Alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide Ionic Liquids (2011)
  • Author(s): K. Fujii, T. Takamuku
  • Journal Title: J. Chem. Phys Volume: 135 Issue: 24 Pages: 244502-244502
  • DOI: 10.1063/1.3672097
  • Peer Reviewed
• [Journal Article] 高分子水溶液の圧力誘起相分離・相転移 (2011)
  • Author(s): 柴山充弘
  • Journal Title: 日本高圧力学会誌「高圧力の科学と技術」 Volume: 21 Pages: 11-17
  • NAID: 10028049262
• [Journal Article] ソフトマテリアルの中性子散乱 (2011)
  • Author(s): 柴山充弘
  • Journal Title: ゴム協会誌 Volume: 84 Pages: 14-20
  • NAID: 10027416105
• [Journal Article] 3号炉における小角散乱研究 (2011)
  • Author(s): 岩瀬裕希、柴山充弘
  • Journal Title: 波紋 Volume: 21 Pages: 23-28
  • NAID: 130007516756
• [Journal Article] Evaluation of Topological Defects inTetra-PEG Gels (2010)
  • Author(s): Akagi, Y., Matsunaga, T., Shibayama, M., Chung, U., Sakai, T.
  • Journal Title: Macromolecules Volume: 430 Issue: 1 Pages: 488-493
  • DOI: 10.1021/ma9019009
  • Peer Reviewed
• [Journal Article] Nonuniformity in Cross-Linked Natural Rubber as Revealed by Contrast-Variation Small-Angle Neutron Scattering (2010)
  • Author(s): Suzuki, T., Osaka, N., Endo, H., Shibayama, M., Ikeda, Y., Asai, H., Higashitani, N., Kokubo, Y., Kohjiya, S.
  • Journal Title: Macromolecules Volume: 43 Issue: 3 Pages: 488-493
  • DOI: 10.1021/ma9019416
  • Peer Reviewed
• [Journal Article] Highly Elastic and Deformable Hydrogel Formed from Tetra-arm Polymers (2010)
  • Author(s): Sakai, T., Akagi, Y., Matsunaga, T., Kurakazu, M., Chung, U., Shibayama, M.
  • Journal Title: Macromol. Rapid Commun. Volume: 31 Issue: 22 Pages: 1954-1959
  • DOI: 10.1002/marc.201000286
  • Peer Reviewed
• [Journal Article] Rheo-SANS Studies on Shear Thickening in Clay-Poly(ethylene oxide) Mixed Solutions (2010)
  • Author(s): Takeda, M., Matsunaga, T., Nishida, T., Endo, H., Takahashi, T., Shibayama, M.
  • Journal Title: Macromolecules. Volume: 43 Issue: 18 Pages: 7793-7799
  • DOI: 10.1021/ma101319j
  • Peer Reviewed
• [Journal Article] Microscopic Structure Analysis ofClay-Poly(ethylene oxide) Mixed Solution in a Flow Field by Contrast-Variation Small-Angle Neutron Scattering (2010)
  • Author(s): Matsunaga, T., Endo, H., Takeda, M.,Shibayama, M.
  • Journal Title: Macromolecules Volume: 43 Issue: 8 Pages: 5075-5082
  • DOI: 10.1021/ma100176f
  • Peer Reviewed
• [Journal Article] Evaluation of Topological Defects in Tetra-PEG Gels (2010)
  • Author(s): Y.Akagi, M.Shibayama, et al.
  • Journal Title: Macromolecules Volume: 43 Pages: 488-493
  • Peer Reviewed
• [Journal Article] Nonuniformity in Cross-Linked Natural Rubber as Revealed by Contrast-Variation Small-Angle Neutron Scattering (2010)
  • Author(s): T.Suzuki, M.Shibayama, et al.
  • Journal Title: Macromolecules Volume: 43 Pages: 1556-1563
• [Journal Article] Static partial scattering functions for linear and ring random copolymers (2010)
  • Author(s): H.Endo, M.Shibayama, et al.
  • Journal Title: Polym.J. Volume: 42 Pages: 157-160
  • NAID: 10026364119
  • Peer Reviewed
• [Journal Article] Evaluation of Gelation Kinetics of Tetra-PEG Gel (2010)
  • Author(s): M.Kutakazu, M.Shibayama, et al.
  • Journal Title: Macromolecules Volume: 43 Pages: 3935-3940
  • Peer Reviewed
• [Journal Article] Microscopic Structure Analysis of Clay-Poly(ethylene oxide) Mixed Solution in a Flow Field by Contrast-Variation Small-Angle Neutron Scatterings (2010)
  • Author(s): T.Matsunaga, M.Shibayama, et al.
  • Journal Title: Macromolecules Volume: 43 Pages: 5075-5082
  • Peer Reviewed
• [Journal Article] Highly Elastic and Deformable Hydrogel Formed from Tetra-arm Polymers (2010)
  • Author(s): T.Sakai, M.Shibayama, et al.
  • Journal Title: Macromol.Rapid Commun. Volume: 31 Pages: 1954-1959
  • Peer Reviewed
• [Journal Article] Microscopic Structure Analysis of Clay-Poly(ethylene oxide) Mixed Solution in a Flow Field by Contrast-Variation Small-Angle Neutron Scattering (2010)
  • Author(s): T.Matsunaga, M.Shibayama, et al.
  • Journal Title: Macromolecules Volume: 43 Pages: 5075-5082
  • Peer Reviewed
• [Journal Article] ダイヤモンド格子状構造をもつ高分子ゲルの構造とダイナミクス (2010)
  • Author(s): 松永拓郎、柴山充弘
  • Journal Title: 機能材料 Volume: 30 Pages: 6-13
• [Journal Article] 中性子散乱で観た高強力ゲルの構造 (2010)
  • Author(s): 柴山充弘
  • Journal Title: 高分子 Volume: 59 Pages: 701-704
  • NAID: 10026584790
• [Journal Article] Rheo-SANS : 流動場での中性子散乱実験によるソフトマターの構造研究 (2010)
  • Author(s): 柴山充弘
  • Journal Title: ながれ(流体力学会誌) Volume: 29 Pages: 337-344
  • NAID: 110007880605
• [Presentation] Structure and Gelation Dynamics ofTetra-PEG Ion Gels (2012)
  • Author(s): Shibayama, M., Tutzing
  • Organizer: Workshop on "Trends and Perspectives in Neutron Scattering for Soft Mater and Biophysics
  • Place of Presentation: Germany
• [Presentation] Structure and Properties ofConnectivity-Controlled Tetra-PEG Gels (2012)
  • Author(s): Shibayama, M.
  • Organizer: Polymeric and Self-assembling Hydrogels' From Fundamental Understanding to Applications
  • Place of Presentation: King's College, London, UK
• [Presentation] Structure and properties of tetra-PEG ion gels (2012)
  • Author(s): Shibayama, M., Jackson Hole, Wyoming
  • Organizer: Polymer Network Group Meeting2012
  • Place of Presentation: USA
• [Presentation] Preparation and Structural Characterization of High-Strength Ion Gels MACRO2012 (2012)
  • Author(s): Shibayama, M.
  • Organizer: Virginia Tech in Blacksburg
  • Place of Presentation: Virginia, USA,
• [Presentation] Structure and Properties of Tetra-PEG Ion Gels (2012)
  • Author(s): Shibayama, M.
  • Place of Presentation: Chengdu, China
• [Presentation] Structure and properties of tetra-PEG ion gels (2012)
  • Author(s): Shibayama, M.
  • Organizer: Polymer Network Group Meeting 2012
  • Place of Presentation: Jackson Hole
  • Invited
• [Presentation] Preparation and Structural Characterization of High-Strength Ion Gels (2012)
  • Author(s): Shibayama, M.
  • Organizer: MACRO2012
  • Place of Presentation: Virginia, USA
  • Invited
• [Presentation] Structure and Properties of Connectivity-Controlled Tetra-PEG Gels (2012)
  • Author(s): Shibayama, M.
  • Organizer: 'Polymeric and Self-assembling Hydrogels - From Fundamental Understanding to Applications
  • Place of Presentation: London, UK
  • Invited
• [Presentation] Structure and Gelation Dynamics of Tetra-PEG Ion Gels (2012)
  • Author(s): Shibayama, M.
  • Organizer: Workshop on "Trends and Perspectives in Neutron Scattering for Soft Mater and Biophysics"
  • Place of Presentation: Tutzing, Germany
  • Invited
• [Presentation] 結合欠陥を有するTetra-PEGゲルの中性子散乱法による構造解析 (2012)
  • Author(s): 西健吾、千々石雅志、藤井健太、勝本之晶、酒井崇匡、鄭雄一、柴山充弘
  • Organizer: 第23回高分子ゲル研究討論会
  • Place of Presentation: 東京大学本郷キャンパス
• [Presentation] Tetra-PEG網目を用いた高強度イオンゲルの構造解析 (2012)
  • Author(s): 浅井華子、藤井健太、柴山充弘、上木岳士、酒井崇匡、渡邉正義
  • Organizer: 第23回高分子ゲル研究討論会
  • Place of Presentation: 東京大学本郷キャンパス
• [Presentation] ミクロ相分離したナノコンホシットケルの力学物性と微視的構造 (2012)
  • Author(s): 西田理彦
  • Organizer: 第23回高分子ゲル研究討論会
  • Place of Presentation: 東京大学本郷キャンパス
• [Presentation] せん断場における紐状ミセルの構造解析 (2012)
  • Author(s): 草野巧巳、竹田麻希子、松永拓郎、柴山充弘、阪大院理四方俊幸
  • Organizer: 第23回高分子ゲル研究討論会
  • Place of Presentation: 東京大学本郷キャンパス
• [Presentation] イオン液体中におけるTetra-PEGケル化反応とその物性評価 (2012)
  • Author(s): 橋本慧、浅井華子、藤井健太、柴山充弘
  • Organizer: 第23回高分子ゲル研究討論会
  • Place of Presentation: 東京大学本郷キャンパス
• [Presentation] 反応速度論的観点から見たTetra-PEGゲルのゲル化過程の解析 (2011)
  • Author(s): 西健吾、千々石雅志、藤井健太、勝本之晶、酒井崇匡、鄭雄一、柴山充弘
  • Organizer: 第10回関東ソフトマター研究会
  • Place of Presentation: 東京大学駒場キャンパス
  • Year and Date: 2011-11-12
• [Presentation] Tetra-PEG網目を用いた高強度イオンゲルの構造と物性 (2011)
  • Author(s): 浅井華子、藤井健太、柴山充弘、上木岳士、酒井崇匡、渡邉正義
  • Organizer: 第10回関東ソフトマター研究会
  • Place of Presentation: 東京大学駒場キャンパス
  • Year and Date: 2011-11-12
• [Presentation] ナノコンポジットゲルの変形機構と力学物性 (2011)
  • Author(s): 西田理彦
  • Organizer: 第10回関東ソフトマター研究会
  • Place of Presentation: 東京大学駒場キャンパス
  • Year and Date: 2011-11-12
• [Presentation] Exploration of Advanced Polymer Gels bySmall-angle Neutron Scattering (2011)
  • Author(s): Shibayama, M.
  • Organizer: 2011MRS-J Meeting
  • Place of Presentation: Yokohama
• [Presentation] Structure and Properties of High Performance Gels Made by Module Assembling Method (2011)
  • Author(s): Shibayama, M., Boston, Massachusetts
  • Organizer: 2011 MRS Fall Meeting
  • Place of Presentation: USA
• [Presentation] Rheo-SANS Studies on Structure Evolution in Polymer-particle Aqueous Solutions (2011)
  • Author(s): Shibayama, M.
  • Organizer: 1st AOCNS
  • Place of Presentation: Tsukuba, Japan
• [Presentation] Small-Angle Neutron Scattering: a Powerful Tool for Nanostructure Characterization of Soft Materials (2011)
  • Author(s): Shibayama
  • Organizer: International Conference on Advanced Materials for Sustainable Development (ICAMN2011) Kathmandu
  • Place of Presentation: M., Nepal
• [Presentation] Tetra-PEGイオンゲルの力学物性 (2011)
  • Author(s): 浅井華子
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] Tetra-PEGゲルのゲル化過程の解析 (2011)
  • Author(s): 西健吾
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] せん断場における紐状ミセルの物性と構造解析 (2011)
  • Author(s): 草野巧巳
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] SANS/SAXS/SEMによるフェノール樹脂硬化物の構造解析 (2011)
  • Author(s): 和泉篤士、中尾俊夫、柴山充弘
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] MDによるフェノール樹脂架橋構造の応力歪解析 (2011)
  • Author(s): 和泉篤士、中尾俊夫、柴山充弘
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] ミクロ相分離構造を有するナノコンポジットゲルの延伸下構造変化 (2011)
  • Author(s): 西田理彦
  • Organizer: 高分子年次大会
  • Place of Presentation: 大阪国際会議場
• [Presentation] せん断場における紐状ミセルの構造解析 (2011)
  • Author(s): 草野巧巳、竹田麻希子、松永拓郎、四方俊幸、柴山充弘
  • Organizer: 第23年度繊維学会年次大会
  • Place of Presentation: タワーホール船堀
• [Presentation] ミクロ相分離したナノコンホシットケルの力学物性と微視的構造 (2011)
  • Author(s): 西田理彦、柴山充弘、王林明、原口和敏
  • Organizer: 第23年度繊維学会年次大会
  • Place of Presentation: タワーホール船堀
• [Presentation] Tetra-PEGゲルのゲル化過程の解析 (2011)
  • Author(s): 西健吾、千々石雅志、藤井健太、勝本之晶、酒井崇匡、鄭雄一、柴山充弘
  • Organizer: 第1回ソフトマター研究会
  • Place of Presentation: キャンパスプラザ京都
• [Presentation] Tetra-PEGイオンゲルの構造と物性 (2011)
  • Author(s): 浅井華子、藤井健太、柴山充弘、上木岳士、酒井崇匡、渡邉正義
  • Organizer: 第1回ソフトマター研究会
  • Place of Presentation: キャンパスプラザ京都
• [Presentation] 3鎖型界面活性剤会合体の濃度変化による構造転移 (2011)
  • Author(s): 草野巧巳、岩瀬裕希、吉村倫一, 柴山充弘
  • Organizer: 第63回コロイトおよひ界面化学討論会
  • Place of Presentation: 京都大学
• [Presentation] High Performance Ion-Gel with Tetra-PEG Network (2011)
  • Author(s): 浅井華子、藤井健太、柴山充弘、上木岳士、酒井崇匡、渡邉正義
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] Tetra-PEGゲルのゲル化過程の解析 (2011)
  • Author(s): 西健吾、千々石雅志、藤井健太、勝本之晶、酒井崇匡、鄭雄一、柴山充弘
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] 重水素化フェノール樹脂の合成と特性解析 (2011)
  • Author(s): 和泉篤士、中尾俊夫、柴山充弘
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] 小角中性子散乱と粘度測定を用いた3鎖型界面活性剤ミセルの構造解析 (2011)
  • Author(s): 草野巧巳、岩瀬裕希、吉村倫一, 柴山充弘
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] 重水素化フェノール樹脂の合成と特性解析 (2011)
  • Author(s): 和泉篤士、中尾俊夫、柴山充弘
  • Organizer: 第61回ネットワークポリマー講演討論会
  • Place of Presentation: 関西大学
• [Presentation] フェノール樹脂硬化物における密度揺らぎの検証 (2011)
  • Author(s): 和泉篤士、中尾俊夫、柴山充弘
  • Organizer: 第61回ネットワークポリマー講演討論会
  • Place of Presentation: 関西大学
• [Presentation] Structural and rheological studies of aggregation behavior of trimeric surfactants in aqueous solutions (2011)
  • Author(s): T.Kusanol, H.Iwase, T.Yoshimura, M.Shibayama
  • Organizer: 1st AONSA(第1回アジアオセアニア中性子散乱会議)
  • Place of Presentation: 筑波国際会議場
• [Presentation] Structure and Deformation Mechanism of Tetra-PEG Gels (2011)
  • Author(s): K Nishi, T.Matsunaga, T.Sakai, M.Shibayama
  • Organizer: 1st AONSA(第1回アジアオセアニア中性子散乱会議)
  • Place of Presentation: 筑波国際会議場
• [Presentation] Synthesis and Structural Analysis of Tetra-PEG Ion Gel (2011)
  • Author(s): H.Asai, K.Fujii, M.Shibayama, T.Ueki,T.Sakai, M.Watanabe
  • Organizer: 1st AONSA(第1回アジアオセアニア中性子散乱会議)
  • Place of Presentation: 筑波国際会議場
• [Presentation] SANS and SAXS studies of Phenolic Resins (2011)
  • Author(s): A.Izumi, T.Nakao, M.Shibayama
  • Organizer: 1st AONSA(第1回アジアオセアニア中性子散乱会議)
  • Place of Presentation: 筑波国際会議場
• [Presentation] Stress Relaxation and Hysteresis of Nanocomposite Gels Investigated by SAXS and SANS Measurements (2011)
  • Author(s): T.Nishida, A.Obayashi, K.Haraguchi, M.Shibayama
  • Organizer: 1st AONSA(第1回アジアオセアニア中性子散乱会議)
  • Place of Presentation: 筑波国際会議場
• [Presentation] Tetra-PEGゲルの乾燥状態における物性と構造 (2011)
  • Author(s): 野本祐作、柴山充弘
  • Organizer: 第22回高分子ゲル研究討論会
  • Place of Presentation: 東京大学
• [Presentation] Tetra・PEGゲルのゲル化過程の解析 (2011)
  • Author(s): 西健吾、柴山充弘
  • Organizer: 第22回高分子ゲル研究討論会
  • Place of Presentation: 東京大学
• [Presentation] イオン液体を溶媒としたtetra-PEGゲルの調製 (2011)
  • Author(s): 浅井華子、柴山充弘
  • Organizer: 第22回高分子ゲル研究討論会
  • Place of Presentation: 東京大学
• [Presentation] 均一ネットワークゲルの一軸延伸下における構造解析 (2011)
  • Author(s): 松永拓郎
  • Organizer: 小角・反射率・高分解能装置研究会
  • Place of Presentation: 東京大学物性研究所
• [Presentation] 超均一網目構造を有するTetra-PEGゲルの構造と物性 (2011)
  • Author(s): 赤木友紀、酒井崇匡、柴山充弘
  • Organizer: つくばソフトマター研究会2011
  • Place of Presentation: 東京大学物性研究所
• [Presentation] 小角中性子散乱による高分子ゲル・エラストマーの構造研究 (2010)
  • Author(s): 柴山充弘
  • Organizer: KITゴム・エラストマー研究会第2回例会
  • Place of Presentation: 京都工芸繊維大(招待)
  • Year and Date: 2010-06-25
• [Presentation] Recent Development of Neutron Scattering Methods for Structural Characterization of Polymeric Systems (Invited) (2010)
  • Author(s): M.Shibayama
  • Organizer: ISPAC-2010
  • Place of Presentation: Pohang, Korea
  • Year and Date: 2010-06-01
• [Presentation] 中性子散乱による高分子ゲルの精密構造解 (2010)
  • Author(s): Shibayama, M.
  • Organizer: Precision Analyses of Polymer Gels by Neutron Scattering Award LecturAnnual Meeting of the Society of Polymer Science
  • Place of Presentation: Yokohama, Japan
• [Presentation] 中性子散乱による高分子ゲルの精密構造解析 (2010)
  • Author(s): 柴山充弘
  • Organizer: 高分子年次大会
  • Place of Presentation: パシフィコ横浜(招待)
• [Presentation] Tetra-PEG Gelの弾性に対する架橋点間分子量の効果 (2010)
  • Author(s): 赤木友紀、柴山充弘
  • Organizer: 高分子年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] Tetra・PEGゲルネットワークにおける高分子鎖の広がり (2010)
  • Author(s): 松永拓郎、柴山充弘
  • Organizer: 高分子年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] Structure and Mechanical Properties of Tetra-PEG Gels (2010)
  • Author(s): M.Shibayama
  • Organizer: International Symposium on Polymer Physics
  • Place of Presentation: Ji'nan, China(Invitde)
• [Presentation] Structural analysis and physical properties of Tetra-PEG gel (2010)
  • Author(s): T.Matsunaga, M.Shibayama, et al.
  • Organizer: International Soft Matter Conference 2010 (ISMC2010)
  • Place of Presentation: Granada, Spain
• [Presentation] 四官能性ポリマーからなるTetra-PEGゲルの構造と物性 (2010)
  • Author(s): 酒井崇匡
  • Organizer: 日本化学会第4回関東支部大会
  • Place of Presentation: 筑波大学(招待)
• [Presentation] Evaluation of network structure and physical properties of Tetra-PEG gel (2010)
  • Author(s): Takamasa Sakai
  • Organizer: P2010 14^<th> International Scientific Conference on Polymeric Materials
  • Place of Presentation: Halle, Germany(Invited)
• [Presentation] Evaluation of network structure and physical properties of Tetra-PEG gel (2010)
  • Author(s): Takamasa Sakai
  • Organizer: Trilateral Symposium on NanoBio Integration
  • Place of Presentation: Berlin, Germany(Invited)
• [Presentation] ゲルの乾燥状態における構造と物性 (2010)
  • Author(s): 野本祐作、柴山充弘
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
• [Presentation] Tetra-PEGの伸長による複屈折 (2010)
  • Author(s): 登阪雅聡、柴山充弘
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
• [Presentation] Tetra-PEGゲルの結合不均一性・トポロジカル不均一性の評価 (2010)
  • Author(s): 赤木友紀、柴山充弘
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
• [Presentation] Tetra-PEGゲルの延伸下小角中性子散乱による構造解析 (2010)
  • Author(s): 松永拓郎、柴山充弘
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
• [Presentation] Small-angle Neutron Scattering on Tetra-PEG gels (2010)
  • Author(s): M.Shibayama
  • Organizer: PACIFICHEM2010
  • Place of Presentation: Honolulu, Hawaii, USA
• [Presentation] Structural analysis of homogeneous network gel (2010)
  • Author(s): T.Matsunaga, M.Shibayama, et al.
  • Organizer: PACIFICHEM2010
  • Place of Presentation: Honolulu, Hawaii, USA
• [Presentation] Gelation mechanism and physical properties of Tetra-PEG gel (2010)
  • Author(s): T.Sakai, M.Shibayama, et al.
  • Organizer: PACIFICHEM2010
  • Place of Presentation: Honolulu, Hawaii, USA
• [Book] Polymeric and Self Assembled Hydrogels:Fundamentals to Applications, Chapt. 2,Fabrication Structure, Mechanical Properties, and Application of Tetra-PEG Hydrogels Oren Scherman and Xian Jun Loh, Eds. (2012)
  • Author(s): Shibayama, M., Sakai, T.
  • Publisher: RSC Publishing
• [Book] Fabrication, Structure, Mechanical Properties, and Application of Tetra-PEG Hydrogels Oren Scherman and Xian Jun Loh, Eds (2012)
  • Author(s): Shibayama, M., Sakai, T.
  • Publisher: Polymeric and Self Assembled Hydrogels: Fundamentals to Applications
• [Book] Inhomogeneous Structure and Dynamics of Condensed Soft Matter Edited by Imae (2011)
  • Author(s): T,. Kanaya, T., Furusaka, M., and Torikai, N.Shibayama, M.
  • Publisher: Neutrons in Soft Matter, Wiley
• [Book] Neutrons in Soft Matter (2011)
  • Author(s): M.Shibayama
  • Total Pages: 654
  • Publisher: Edited by T.Imae, T.Kanaya, M.Furusaka, N.Torikai
• [Book] 驚異のソフトマター-機能性ゲル「ゲル構造解析(第I部2章)」 (2010)
  • Author(s): 柴山充弘
  • Total Pages: 9
  • Publisher: 化学同人
• [Book] 驚異のソフトマター-機能性ゲル「ゲル構造解析(第II部1章)」 (2010)
  • Author(s): 柴山充弘
  • Total Pages: 7
  • Publisher: 化学同人
• [Remarks]
  • URL: http://shibayama.issp.u-tokyo.ac.jp/
• [Remarks] 東京大学柴山研究室
  • URL: http://shibayama.issp.u-tokyo.ac.jp/mitsu/Publication/Publication.html
• [Patent(Industrial Property Rights)] イオン液体含有ゲルの製造方法 (2012)
  • Inventor(s): 鄭雄一・酒井崇匡・柴山充弘・藤井健太
  • Industrial Property Rights Holder: 国立大学法人 東京大学
  • Filing Date: 2012-03-30
  • Overseas
• [Patent(Industrial Property Rights)] ULTRA-HIGH STRENGTH INJECTABLE HYDROGEL AND PROCESSFO (2011)
  • Inventor(s): 鄭雄一、鈴木茂樹、酒井崇匡、柴山 充弘、佐々木伸雄
  • Industrial Property Rights Holder: 国立大学法人東京大学、国立大学法 人横浜国立大学
  • Industrial Property Number: 2011-198851
  • Acquisition Date: 2011-09-12
  • Overseas