Budget Amount *help |
¥47,840,000 (Direct Cost: ¥36,800,000、Indirect Cost: ¥11,040,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2012: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2011: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2010: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
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Outline of Final Research Achievements |
The aims of this study are the production of new bio-based plastics from non-edible biomass and the high-functionability of biodegradable plastics. Xylan, one of hemicelluloses extracted from wood, was esterified to add the thermos-plasticity and we succeed to process the flexible films and nanofibers. And also, it was found that xylan ester derivatives became a good nucleate agent for poly(lactic acid) that is the most important bio-based and biodegradable plastic. On the other hand, ultra-high-molecular-weight microbial polyesters have been synthesized and succeeded to process the high tensile strength films and fibers. The molecular and crystals structures were analyzed by the X-ray diffraction at synchrotron radiation. Furthermore, it was revealed that the rate of enzymatic degradation can be controlled by the crystallinity and molecular structures.
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