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Production and high-functionability of biodegradable bio-based plastics synthesized from non-edible biomass

Research Project

Project/Area Number 22245026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

IWATA Tadahisa  東京大学, 農学生命科学研究科, 教授 (30281661)

Project Period (FY) 2010-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥47,840,000 (Direct Cost: ¥36,800,000、Indirect Cost: ¥11,040,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2012: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2011: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2010: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Keywordsバイオベースプラスチック / 生分解性プラスチック / フィルム / 繊維 / 酵素分解性 / キシラン / ポリ乳酸 / 微生物産生ポリエステル / バイオマス / ヘミセルロース / 天然多糖類 / プラスチック / 機械的物性 / 生分解性 / バイオマスプラスチック / 多糖類 / エステル誘導体 / キシラン誘導体 / 結晶核剤 / 大型放射光 / バイオベース高分子 / 生分解性高分子 / ナノファイバー / 化学修飾 / 球晶観察
Outline of Final Research Achievements

The aims of this study are the production of new bio-based plastics from non-edible biomass and the high-functionability of biodegradable plastics. Xylan, one of hemicelluloses extracted from wood, was esterified to add the thermos-plasticity and we succeed to process the flexible films and nanofibers. And also, it was found that xylan ester derivatives became a good nucleate agent for poly(lactic acid) that is the most important bio-based and biodegradable plastic. On the other hand, ultra-high-molecular-weight microbial polyesters have been synthesized and succeeded to process the high tensile strength films and fibers. The molecular and crystals structures were analyzed by the X-ray diffraction at synchrotron radiation. Furthermore, it was revealed that the rate of enzymatic degradation can be controlled by the crystallinity and molecular structures.

Report

(5 results)
  • 2014 Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (53 results)

All 2015 2014 2012 2011 2010 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results,  Acknowledgement Compliant: 1 results) Presentation (29 results) (of which Invited: 14 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Syntheses of Glucomannan Esters and Their Thermal and Mechanical Properties2014

    • Author(s)
      Yukiko Enomoto-Rogors, Yusuko Ohmomo, Akio Takomura, Tadahisa Iwata
    • Journal Title

      Carbohydrate Polymers

      Volume: 101 Pages: 592-599

    • DOI

      10.1016/j.carbpol.2013.09.103

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of Mechanical Reinforcement Effects of Surface-Modified Cellulose Nanofibrils and Carbon Nanotubes in PLLA Composites2014

    • Author(s)
      Fujisawa, et al.
    • Journal Title

      Composites Science and Technology

      Volume: 90 Pages: 96-101

    • DOI

      10.1016/j.compscitech.2013.10.021

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and characterization of polychloroprene nanocomposite with cellulose nanofibers from oil palm empty fruit bunches (OPEFBs) as nanofiller2014

    • Author(s)
      Farah Fahma, Naruhito Hori, Tadahisa Iwata, and Akio Takemura
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 131 Issue: 8 Pages: 40159-40164

    • DOI

      10.1002/app.40159

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Curdlan Ester Derivatives : Synthesis, Structure, and Properties2014

    • Author(s)
      Hironori Marubayashi, Kazuyori Yukinaka, Yukiko Enomoto-Rogers, Takemura A, Iwata T
    • Journal Title

      Carbohydrate Polymers

      Volume: 103 Pages: 427-433

    • DOI

      10.1016/j.carbpol.2013.12.015

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and properties of glucomannan acetate butyrate mixed esters2014

    • Author(s)
      Takahiro Danjo, Yukiko Enomoto-Rogers, Akio Takemura, Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 109 Pages: 373-378

    • DOI

      10.1016/j.polymdegradstab.2014.05.023

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Acetylation and characterization of xylan from hardwood kraft pulp2012

    • Author(s)
      Noreen G. Fundador, Yukiko Enomoto-Rogers, Akio Takemura and Tadahisa Iwata
    • Journal Title

      Carbohydrate Polymers

      Volume: 87 Issue: 1 Pages: 170-176

    • DOI

      10.1016/j.carbpol.2011.07.034

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of xylan-graft-poly(Llactide) copolymers via click chemistry and their thermal properties2012

    • Author(s)
      Yukiko Enomoto-Rogers and Tadahisa Iwata
    • Journal Title

      Carbohydrate Polymers

      Volume: 87 Issue: 3 Pages: 1933-1940

    • DOI

      10.1016/j.carbpol.2011.09.092

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical and structural effects of adding ultrahigh- molecular-weight poly[(R)-3-hydroxybutyrate] to wild-type poly[(R)-3-hydroxybutyrate]2012

    • Author(s)
      Taizo Kabe, Takeharu Tsuge, Ken-ichi Kasuya, Akio takemura, Takaaki Hikima, Masaki Takata and Tadahisa Iwata
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 4 Pages: 1858-1865

    • DOI

      10.1021/ma202285c

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and characterization of xylan esters2012

    • Author(s)
      Fundador N. G. V, Enomoto-Rogers Y, Takemura A, Iwata T,
    • Journal Title

      Polymer

      Volume: 58 Issue: 18 Pages: 3885-3893

    • DOI

      10.1016/j.polymer.2012.06.038

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Processing, mechanical properties and structure analysis of melt-spun fibers of P(3HB)/UHMW-P(3HB) identical blend2012

    • Author(s)
      Taizo Kabe, Takeharu Tsuge, Takaaki Hikima, Masaki Takata, Akio takemura, and Tadahisa Iwata
    • Journal Title

      ACS Symposium Series, Vol. 1105, Biobased Monomers, Polymers and Materials

      Volume: Chapter 5 Pages: 63-75

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and mechanical properties of wet-spun fibers made from natural cellulose nanofibers2011

    • Author(s)
      Sinichiro Iwamoto, Akira Isogai and Tadahisa Iwata
    • Journal Title

      Biomacromolecules

      Volume: 12 Issue: 3 Pages: 831-836

    • DOI

      10.1021/bm101510r

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of pre-acid-hydrolysis treatment on morphology and properties of cellulose nanowhiskers from coconut hust2011

    • Author(s)
      Fahma Farar, Shinichiro Iwamoto, Naruhito hori, Tadahisa Iwata and Akio Takemura
    • Journal Title

      Cellulose

      Volume: 18 Issue: 2 Pages: 443-450

    • DOI

      10.1007/s10570-010-9480-0

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties, structure analysis and enzymatic degradation of poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate] uniaxially cold-drawn films2011

    • Author(s)
      Jiaqi Zhang, Kenichi Kasuya, Takaaki Hikima, Masaki Takada, Akio Takemura, and Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 96 Issue: 12 Pages: 2130-2138

    • DOI

      10.1016/j.polymdegradstab.2011.09.011

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison study of TEMPO-analogous compounds on oxidation efficiency of wood cellulose for preparation of cellulose nanofibers2010

    • Author(s)
      Shinichiro Iwamoto, Weihua Kai, Takuya Isogai, Tsuguyuki Saito, Akira Isogai, Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 95 Pages: 1394-1398

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved synthesis of P(3HB-co-3HV-co-3HHx) terpolymers by mutant Cupriavidus necator using the PHA synthase gene of Chromobacterium sp.USM2 with high affinity towards 3HV2010

    • Author(s)
      Kesaven Bhubalan, Devi-Nair Rathi, Hideki Abe, Tadahisa Iwata, Kumar Sudesh
    • Journal Title

      Polymer Degradation and Stability

      Volume: 95 Pages: 1436-1442

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced interlayer interaction in cellulose single nanofibers and poly (L-lactic acid) films by plasma-initiated surface grafting of poly (acryl acid) onto poly (L-lactic acid) films2010

    • Author(s)
      Weihua Kai, Shinichiro Iwamoto, Kazuki Akamatsu, Shinichi Nakao, Akira Isogai, Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 95 Pages: 1004-1010

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 生分解性バイオポリエステルの高性能化2010

    • Author(s)
      岩田忠久
    • Journal Title

      SPring-8利用者情報

      Volume: 8 Pages: 150-156

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural properties and enzymatic degradation behavior of PLLA and stereocomplexed PLA nanofibers2010

    • Author(s)
      Noreen G.V.Fundador, Akio Takemura, Tadahisa Iwata
    • Journal Title

      Macromolecular Materials and Engineering

      Volume: 295 Pages: 865-871

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ポリ[(R)-3-ヒドロキシブチレート-co-(R)-3-ヒドロキシヘキサノエート]のゲルフィルム作製,高次構造解析および酵素分解性2010

    • Author(s)
      加部泰三、竹村彰夫、岩田忠久、田中稔久、粕谷健一、伊藤和輝、高田昌樹
    • Journal Title

      繊維学会誌

      Volume: 66 Pages: 253-260

    • NAID

      10026685254

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Syntheses of chitosan acylates and their properties2015

    • Author(s)
      Takahiro Danjo, Yukiko Enomoto-Rogers, Akio Takemura and Tadahisa Iwata
    • Organizer
      International Symposium on Wood Science and Technology 2015 (IAWPS2015)
    • Place of Presentation
      Funabori, Tokyo
    • Year and Date
      2015-03-16 – 2015-03-18
    • Related Report
      2013 Annual Research Report
  • [Presentation] 天然多糖類エステル誘導体の合成と高性能化2014

    • Author(s)
      岩田忠久
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎
    • Year and Date
      2014-09-25 – 2014-09-27
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Properties of Environmentally Benign Polymers from Polysaccharides;2014

    • Author(s)
      Tadahisa Iwata
    • Organizer
      IUPAC World Polymer Congress Macro2014
    • Place of Presentation
      Chiang Mai, Thailand
    • Year and Date
      2014-07-06 – 2014-07-10
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] カードランエステル誘導体の合成,基礎物性解析および繊維化2014

    • Author(s)
      若本一敏, 加部泰三, 岩田忠久, 丸林弘典
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      船堀、東京
    • Year and Date
      2014-06-10 – 2014-06-12
    • Related Report
      2013 Annual Research Report
  • [Presentation] 微生物産生ポリエステルの物性および球晶形成に対する分子量効果2014

    • Author(s)
      杉浦高士, 加部泰三, 竹村彰夫, 岩田忠久, 大竹勝人
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      船堀、東京
    • Year and Date
      2014-06-10 – 2014-06-12
    • Related Report
      2013 Annual Research Report
  • [Presentation] 糖質を利用したバイオマスプラスチックの新展開2014

    • Author(s)
      岩田忠久
    • Organizer
      第54回澱粉研究懇談会
    • Place of Presentation
      伊東
    • Year and Date
      2014-06-05 – 2014-06-07
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] プルランエステル誘導体の合成と基礎物性解析2014

    • Author(s)
      飯尾成博, ロジャース有希子, 信川省吾, 山口政之, 岩田忠久
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-27 – 2014-05-29
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルギン酸エステル誘導体の合成とその性質2014

    • Author(s)
      小田史彦, 石井大輔, 竹村彰夫, 岩田忠久
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-27 – 2014-05-29
    • Related Report
      2013 Annual Research Report
  • [Presentation] グルコマンナンアシルエステルの合成とアシル鎖長による物性制御2014

    • Author(s)
      檀上隆寛, ロジャース有希子, 加部泰三, 丸林弘典, 信川省吾, 山口政之, 竹村彰夫, 岩田忠久
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-27 – 2014-05-29
    • Related Report
      2013 Annual Research Report
  • [Presentation] High-functionability of Biodegradable and Bio-based Plastics2012

    • Author(s)
      Tadahisa Iwata
    • Organizer
      日中バイオテクノロジー国際シンポジウム2012
    • Place of Presentation
      東京大学(東京)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthesis and characterization of xylan and glucomannan ester derivatives and their application2012

    • Author(s)
      Tadahisa Iwata
    • Organizer
      The 3rd International Cellulose Conference
    • Place of Presentation
      ガトーキングダム札幌(北海道)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Synthesis and Characterization of Xylan and Glucomannan Ester Derivatives2012

    • Author(s)
      Tadahisa Iwata
    • Organizer
      The 4th International Symposium of IWoRS
    • Place of Presentation
      マカッサル(インドネシア)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Mechanical properties and structure analysis of micro-porous fibers processed from polyhydroxyalkanoate2011

    • Author(s)
      Tadahisa IWATA
    • Organizer
      ACS229
    • Place of Presentation
      アメリカ、アナハイム
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation and characterization of di-O-(6-azidohexanoyl) xylan-graft-poly (L-lactide)2011

    • Author(s)
      Yukiko Enomoto-Rogers, Tadahisa Iwata
    • Organizer
      ACS229
    • Place of Presentation
      アメリカ、アナハイム
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mechanical properties, structure analysis and enzymatic degradation of microbial polyester fibers2011

    • Author(s)
      Tadahisa IWATA
    • Organizer
      MoDeSt
    • Place of Presentation
      プラハ(チェコ)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Characterization of Xylan Ester Derivatives and Their Crystallization Effects2011

    • Author(s)
      Tadahisa Iwata, Noreen G. Fundador and Yukiko Enomoto-Rogers
    • Organizer
      International Conference on Bio-based Polymers 2011
    • Place of Presentation
      北京(中国)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] STRUCTURE ANALYSIS AND ENZYMATIC DEGRADATION OF BIO-BASED POLYESTER FIBERS2011

    • Author(s)
      Tadahisa Iwata
    • Organizer
      Pacific Polymer Conference
    • Place of Presentation
      済州島(韓国)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 生分解性バイオマスプラスチックの現状2011

    • Author(s)
      岩田 忠久
    • Organizer
      第20回ポリマー材料フォーラム
    • Place of Presentation
      タワーホル船堀(東京)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Structure analysis and enzymatic degradation of β-form in poly [(R)-3-hydroxybutyrate] fibers and films2010

    • Author(s)
      Tadahisa IWATA
    • Organizer
      Pacifichem2010
    • Place of Presentation
      アメリカ、ハワイ
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and characterization of xylan ester derivatives2010

    • Author(s)
      Noreen Fundador, Yukiko Enomoto-Rogers, Tadahisa IWATA
    • Organizer
      Pacifichem2010
    • Place of Presentation
      アメリカ、ハワイ
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structure and properties of bio-based polyester fibers2010

    • Author(s)
      Tadahisa IWATA
    • Organizer
      ISBP2010
    • Place of Presentation
      ドイツ、シュツットガルト
    • Year and Date
      2010-10-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 植物由来資源からの微生物による新規バイオベースポリマーの開発と実用材料化2010

    • Author(s)
      岩田忠久
    • Organizer
      第5回バイオ材料プロジェクト「次世代のライフスタイルを支えるバイオ材料の飛躍開発を目指して」
    • Place of Presentation
      京都
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Progress of Japanese Bioplastics Industry and Scientific Research

    • Author(s)
      Tadahisa Iwata
    • Organizer
      Special Symposium on Hanyang University
    • Place of Presentation
      ソウル(韓国)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] High-functionability of Biodegradable Biomass-based Plastics

    • Author(s)
      Tadahisa Iwata
    • Organizer
      先端材料科学セミナー
    • Place of Presentation
      北陸先端大学院大学(石川)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 微生物産生ポリエスエステルの現状と展望

    • Author(s)
      岩田忠久
    • Organizer
      持続社会構築のためのバイオマス由来高分子材料
    • Place of Presentation
      東京大学生産技術研究所(東京)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] バイオマスプラスチックの高性能化を目指して

    • Author(s)
      岩田忠久
    • Organizer
      FAMCO先端機能材料特別講演会
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ナノ構造制御による生分解性バイオポリエステルの高性能化を目指して

    • Author(s)
      岩田忠久
    • Organizer
      第80回千葉地域活動高分子研究交流講演会
    • Place of Presentation
      出光会館(千葉)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 未来を拓け!環境にやさしいプラスチック

    • Author(s)
      岩田 忠久
    • Organizer
      国際プラスチックフェア
    • Place of Presentation
      幕張メッセ(千葉)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] 生分解性バイオベースポリマーの高性能化と構造解析

    • Author(s)
      岩田 忠久
    • Organizer
      高分子学会中国四国支部 平成23年度高分子講演会
    • Place of Presentation
      広島大学(広島)
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Book] 高機能性繊維の最前線 〜医療、ヘルスケア分野への挑戦〜、第四編医療用機能性繊維、第6章 微生物産生ポリエステルの医療用繊維としての応用を目指して2014

    • Author(s)
      岩田忠久
    • Total Pages
      241
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report
  • [Book] Chapter 10 : Nanofibrous scaffolds of bio-polyesters : In vitro and in vivo characterizations and tissue response, Nanofibers2010

    • Author(s)
      Hui Ying Tang, Daisuke Ishii, Kumar Sudesh, Tetsuji Yamamoka, Tadahisa Iwata
    • Total Pages
      358
    • Publisher
      Intech, Olajnica 19/2, 32000 Vulovar, Croatia
    • Related Report
      2010 Annual Research Report
  • [Remarks] 東京大学 大学院農学生命科学研究科 生物材料科学専攻 高分子材料学研究室 HP

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東京大学高分子材料学研究室HP

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 高分子材料学研究室HP

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/index.html

    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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