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Atmospheric-pressure plasma processes for high-rate film formation applicable for thin crystalline Si solar cells

Research Project

Project/Area Number 22246017
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Production engineering/Processing studies
Research InstitutionOsaka University

Principal Investigator

KIYOSHI Yasutake  大阪大学, 工学(系)研究科(研究院), 教授 (80166503)

Co-Investigator(Kenkyū-buntansha) KAKIUCHI Hiroaki  大阪大学, 大学院工学研究科, 准教授 (10233660)
OHMI Hiromasa  大阪大学, 大学院工学研究科, 助教 (00335382)
Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥32,630,000 (Direct Cost: ¥25,100,000、Indirect Cost: ¥7,530,000)
Fiscal Year 2013: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2011: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Keywordsシリコン / 大気圧プラズマCVD / 大気圧プラズマ酸化 / エピタキシャル成長 / 表面パッシベーション / 太陽電池 / 超薄型Si結晶太陽電池 / 多結晶Si / 高速成膜 / ポーラスSi
Research Abstract

Atmospheric pressure (AP) plasma processes applicable for the formation of thin crystalline Si solar cells have been developed.
For the stable growth of Si epitaxial films at 600 C by AP plasma chemical vapor deposition, a new water cooled electrode system was developed. By using this system, 2 times higher utilization efficiency of SiH4 than the previous one, the high-rate growth with the suppressed input power using a smaller plasma gap, and the precise control of in-situ doping epitaxy were achievable.
SiO2 films with good electrical properties were grown at 400 C by AP He plasma oxidation of Si, and a good surface passivation quality was demonstrated. AP Ar plasma oxidation process under an open air condition has also been developed to form high quality SiO2 films.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (44 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (28 results) (of which Invited: 7 results) Book (7 results) Remarks (2 results)

  • [Journal Article] Atmospheric-pressure low-temperature plasma processes for thin film deposition2014

    • Author(s)
      H. Kakiuchi, H. Ohmi and K. Yasutake
    • Journal Title

      J. Vac. Sci. Technol. A

      Volume: vol.32 (published online 31 October 2013) Issue: 3

    • DOI

      10.1116/1.4828369

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Journal Article] Voltage distribution over capacitively coupled plasma electrode for atmosphericpressure plasma generation2013

    • Author(s)
      M. Shuto, F. Tomino, H. Ohmi, H. Kakiuchi and K. Yasutake
    • Journal Title

      Nanoscale Research Letters

      Volume: 8 Issue: 1 Pages: 202-202

    • DOI

      10.1186/1556-276x-8-202

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface properties of SiOxNy layer on Si prepared by atmospheric-pressure plasma oxidationnitridation2013

    • Author(s)
      Z. Zhuo, Y. Sannomiya, Y. Kanetani, T. Yamada, H. Ohmi, H. Kakiuchi and K. Yasutake
    • Journal Title

      Nanoscale Research Letters

      Volume: 8 Issue: 1 Pages: 201-201

    • DOI

      10.1186/1556-276x-8-201

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interface properties of SiOxNy layer on Si prepared by atmospheric-pressure plasma oxidation-nitridation2013

    • Author(s)
      Zeteng Zhuo
    • Journal Title

      Nanoscale Research Letters

      Volume: 掲載確定

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of SiO2/Si structure with low interface state density by atmospheric-pressure VHF plasma oxidation2012

    • Author(s)
      Z. Zhuo, Y. Sannomiya, K. Goto, T. Yamada, H. Ohmi, H. Kakiuchi and K. Yasutake
    • Journal Title

      Current Appl. Phys

      Volume: vol.12 Pages: S57-S62

    • DOI

      10.1016/j.cap.2012.04.015

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An atomically controlled Si film formation process at low temperatures using atmospheric-pressure VHF plasma2011

    • Author(s)
      K. Yasutake, H. Kakiuchi, H. Ohmi, K. Inagaki, Y. Oshikane and M. Nakano
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: vol.23 Issue: 39 Pages: 1-22

    • DOI

      10.1088/0953-8984/23/39/394205

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An atomically controlled Si film formation process at low temperatures using atmospheric-pressure VHF plasma2011

    • Author(s)
      K.Yasutake, H.Kakiuchi, H.Ohmi, K.Inagaki, Y.Oshikane, M.Nakano
    • Journal Title

      J.Phys. : Condens. Matter

      Volume: 23 Pages: 1-22

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大気圧プラズマを用いたSi 薄膜形成プロセスの開発2014

    • Author(s)
      安武潔
    • Organizer
      第67回マテリアルズ・テーラリング研究会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2014-04-12
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Development of Open Air Plasma Oxidation Process for Crystalline Si Solar Cells2014

    • Author(s)
      Y. Fujiwara, Y. Kanetani, T. Yamada, H. Ohmi, H. Kakiuchi and K. Yasutake
    • Organizer
      International Workshop on Atomically Controlled Fabrication Technology
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 大気圧プラズマ酸化によるAlOx/SiO2/Siスタック構造の形成と評価2014

    • Author(s)
      藤原裕平,金谷優樹,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      2014年度 精密工学会春季大会学術講演会
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 大気開放プラズマ酸化による太陽電池用Si表面パッシベーョン技術の開発2013

    • Author(s)
      藤原裕平,金谷優樹,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      2013年度 精密工学会秋季大会学術講演会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 大気圧VHFプラズマによるシリコン表面パッシベーションプロセスの開発2012

    • Author(s)
      三宮佑太, 後藤一磨, 卓澤騰, 金谷優樹, 山田高寛, 大参宏昌, 垣内弘章, 安武潔
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] エピタキシャルSi 太陽電池形成のための大気圧プラズマCVD 技術の開発2012

    • Author(s)
      金谷優樹,後藤一磨,三宮佑太,卓澤騰,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      2012年度 精密工学会春季大会学術講演会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2012-03-14
    • Related Report
      2013 Final Research Report
  • [Presentation] エピタキシャルSi太陽電池形成のための大気圧プラズマCVD技術の開発2012

    • Author(s)
      金谷優樹, 後藤一磨, 三宮佑太, 卓澤騰, 山田高寛, 大参宏昌, 垣内弘章, 安武潔
    • Organizer
      2012年度精密工学会春季大会学術講演会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2012-03-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Surface passivation of Si by atmospheric-pressure plasma oxidation at low temperatures2012

    • Author(s)
      卓澤騰, 三宮佑太, 後藤一磨, 山田高寛, 大参宏昌, 垣内弘章, 安武潔
    • Organizer
      2012年度精密工学会春季大会学術講演会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2012-03-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Atmospheric Pressure Plasma Processes for Preparation of Si-Based Thin Films2012

    • Author(s)
      K. Yasutake, H. Ohmi, T. Yamada, H. Kakiuchi
    • Organizer
      59th AVS International Symposium
    • Place of Presentation
      Tampa (USA)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Atmospheric Pressure Plasma Processing for Si Photovoltaics2012

    • Author(s)
      K. Yasutake, H. Ohmi, T. Yamada and H. Kakiuchi
    • Organizer
      2012 Kyrgyz-Japan Solar Energy Workshop
    • Place of Presentation
      Bishkek (Kyrgyz)
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Atmospheric Pressure Plasma Processes for Preparation of Si-Based Thin Films2012

    • Author(s)
      K. Yasutake
    • Organizer
      59th AVS International Symposium
    • Place of Presentation
      Tampa, USA
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Atmosperic-Pressure Plasma Processing for Si Photovoltaics2012

    • Author(s)
      K. Yasutake
    • Organizer
      5th Int. Sym. on Atomically Controlled Fabrication Technology (ACFT-5)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Formation of Passivation Films for Si Surfaces by Atmospheric-Pressure VHF Plasma Oxidation2012

    • Author(s)
      Z. Zhuo (K. Yasutake)
    • Organizer
      5th Int. Sym. on Atomically Controlled Fabrication Technology (ACFT-5)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Atmospheric Pressure Plasma Processing for Si Photovoltaics2012

    • Author(s)
      K. Yasutake
    • Organizer
      2012 Kyrgyz-Japan Solar Energy Workshop
    • Place of Presentation
      Bishkek, Kyrgyz
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 大気圧プラズマ酸化による太陽電池用Si表面パッシベーション技術の開発―大気圧プラズマ酸化によるSiO2の低温高速形成―2012

    • Author(s)
      金谷優樹(安武潔)
    • Organizer
      2012年度 精密工学会秋季大会学術講演会
    • Place of Presentation
      九州工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 大気圧プラズマ酸化によるSiO2の低温形成2012

    • Author(s)
      三宮佑太(安武潔)
    • Organizer
      2012年秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Atmospheric-Pressure VHF Plasma Oxidation Process for Passivation of Si Surface2012

    • Author(s)
      Z. Zhuo (K. Yasutake)
    • Organizer
      精密工学会 2012年度関西地方定期学術講演会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Atmospheric-Pressure Plasma Oxidation Process for Si Surface Passivation2011

    • Author(s)
      Y.Sannnomiya, K.Goto, ZT.Zhuo, Y.Kanetani, T.Yamada, H.Ohmi, H.Kakiuchi, K.Yasutake
    • Organizer
      15th International Conference on Thin Films
    • Place of Presentation
      京都
    • Year and Date
      2011-11-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] Atmospheric-Pressure Plasma Processes for Efficient Formation of Functional Thin Films at Low-Temperatures2011

    • Author(s)
      K.Yasutake, H.Ohmi, T.Yamada, H.Kakiuchi
    • Organizer
      4th Int.Symp.on Atomically Controlled Fabrication Technology
    • Place of Presentation
      大阪
    • Year and Date
      2011-11-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Formation of SiO_xN_y Films for Passivation of Si Surfaces by Atmospheric-Pressure Plasma Oxidation2011

    • Author(s)
      ZT.Zhuo, K.Goto, Y.Sannomiya, Y.Kanetani, T.Yamada, H.Ohmi, H.Kakiuchi, K.Yasutake
    • Organizer
      4th Int.Symp.on Atomically Controlled Fabrication Technology
    • Place of Presentation
      大阪
    • Year and Date
      2011-11-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] 大気圧プラズマ酸化による太陽電池用Si表面パッシベーション技術の開発2011

    • Author(s)
      後藤一磨, 卓澤騰, 三宮佑太, 金谷優樹, 山田高寛, 大参宏昌, 垣内弘章, 安武潔
    • Organizer
      2011年度精密工学会秋季大会学術講演会
    • Place of Presentation
      金沢大学
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 大気圧プラズマを用いたシリコン表面パッシベーションプロセスの開発2011

    • Author(s)
      三宮佑太, 後藤一磨, 卓澤騰, 金谷優樹, 山田高寛, 大参宏昌, 垣内弘章, 安武潔
    • Organizer
      精密工学会2011年度関西地方定期学術講演会
    • Place of Presentation
      兵庫県立大学
    • Year and Date
      2011-06-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 大気圧・超高周波プラズマの生成とSiおよびその化合物の低温・高速成膜2010

    • Author(s)
      垣内弘章
    • Organizer
      表面技術協会 材料機能ドライプロセス部会および関西支部 表面物性研究会合同研究会
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2010-11-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 大気圧プラズマを用いたSi 薄膜形成2010

    • Author(s)
      安武潔,大参宏昌,山田髙寛,垣内弘章
    • Organizer
      日本学術振興会プラズマ材料科学第153委員会第98回研究会「高速・高品質化を実現する先端プラズマ技術 (シリコン薄膜形成)
    • Place of Presentation
      弘済会館(東京)
    • Year and Date
      2010-09-10
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 大気圧プラズマを用いたSi薄膜形成2010

    • Author(s)
      安武潔, 大参宏昌, 山田高寛, 垣内弘章
    • Organizer
      日本学術振興会プラズマ材料科学第153委員会第98回研究会「高速・高品質化を実現する先端プラズマ技術(シリコン薄膜形成)」
    • Place of Presentation
      弘済会館(東京)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] プラズマCVDの基礎~大気圧プラズマによる薄膜形成~2010

    • Author(s)
      垣内弘章
    • Organizer
      第4回プラズマエレクトロニクスインキュベーションホール
    • Place of Presentation
      国立中央青少年交流の家(静岡県御殿場市)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 薄型結晶Si太陽電池のための大気開放プラズマ酸化プロセスの開発

    • Author(s)
      藤原裕平,金谷優樹,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2013年度関西地方定期学術講演会
    • Place of Presentation
      大阪工業大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 大気圧プラズマを用いたSi薄膜形成プロセスの開発

    • Author(s)
      安武 潔
    • Organizer
      第67回マテリアルズ・テーラリング研究会
    • Place of Presentation
      早稲田大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 超精密加工と表面科学 -原子レベルの生産技術-(大阪大学グローバルCOE プログラム高機能化原子制御製造プロセス教育研究拠点/精密工学会超精密加工専門委員会編), 半導体表面パッシベーション2014

    • Author(s)
      安武潔
    • Publisher
      大阪大学出版会
    • Related Report
      2013 Final Research Report
  • [Book] 超精密加工と表面科学 第2部1章2 「半導体表面パッシベーション」2014

    • Author(s)
      安武潔
    • Total Pages
      10
    • Publisher
      大阪大学出版会
    • Related Report
      2013 Annual Research Report
  • [Book] 大気圧プラズマの生成制御と応用技術(監修 小駒益弘),大気圧プラズマCVD によるシリコン薄膜の形成2012

    • Author(s)
      安武潔,垣内弘章,大参宏昌
    • Publisher
      サイエンス & テクノロジー, 改訂版
    • Related Report
      2013 Final Research Report
  • [Book] 改訂版「大気圧プラズマの生成制御と応用技術」(監修 小駒益弘)第5章 第1節2012

    • Author(s)
      安武潔
    • Total Pages
      23
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2012 Annual Research Report
  • [Book] 改訂版「大気圧プラズマの生成制御と応用技術」第5章第1節"大気圧プラズマCVDによるシリコン薄膜の形成"(監修小駒益弘)2012

    • Author(s)
      安武潔, 垣内弘章, 大参宏昌
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2011 Annual Research Report
  • [Book] in Generation and Applications of Atmospheric Pressure Plasmas (eds. M. Kogoma et al.), Preparation of Si-based thin films using atmospheric pressure plasma chemical vapor deposition2011

    • Author(s)
      K. Yasutake, H. Kakiuchi and H. Ohmi
    • Publisher
      Nova Science Publishers
    • Related Report
      2013 Final Research Report
  • [Book] "Preparation of Si-based thin films using atmospheric pressure plasma chemical vapour deposition" in Generation and Applications of Atmospheric Pressure Plasmas Eds : M.Kogoma, M.Kusano, Y.Kusano2011

    • Author(s)
      Kiyoshi Yasutake, Hiroaki Kakiuchi, Hiromasa Ohmi
    • Total Pages
      22
    • Publisher
      Nova Science Publishers, Inc.
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www-ms.prec.eng.osaka-u.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 低温・高速で高品質を実現する大気圧プラズマCVD法の開発

    • URL

      http://www-ms.prec.eng.osaka-u.ac.jp/jpn/study/APPCVD.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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