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Development of onsite measurement system of atmospheric nitrous acid

Research Project

Project/Area Number 22310007
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionThe University of Tokyo

Principal Investigator

TONOKURA Kenichi  東京大学, 大学院・新領域創成科学研究科, 教授 (00260034)

Co-Investigator(Kenkyū-buntansha) HAYASHI Rumiko  東京大学, 環境安全本部, 助教 (50508421)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Keywords亜硝酸 / オンサイト計測 / 分光計測 / 環境計測 / レーザー分光 / 大気化学
Research Abstract

Nitrous acid (HONO) is a significant source of hydroxyl (OH) radicals and an indoor pollutant. HONO is difficult to accurately measure since the species is prone to losses due to its high reactivity and solubility. Thus, this research concentrates on the development of a measurement system utilizing cavity ring down spectroscopy (CRDS) and differential optical absorption spectroscopy (DOAS). The former is used to provide a basic detection limit of HONO and to determine HONO’s absorption cross-section in the mid-IR region while the latter is used to increase the sensitivity of the system and improve on the detection limit. The study also includes examination of the effects of temperature, carrier gas flow rate and reactant amount on the HONO synthesis. Current results show an encouraging detection limit and that the reaction synthesis yields HONO of satisfactory purity.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (5 results)

All 2013 2012 2011 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) Remarks (1 results)

  • [Journal Article] Monitoring of atmospheric nitrogen dioxide by pulsed differential optical absorption spectroscopy with two different light paths2012

    • Author(s)
      Y. Kambe, Y. Yoshii, K. Takahashi, K. Tonokura
    • Journal Title

      J. Environ. Monitor.

      Volume: 14 Pages: 944-950

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Presentation] 連続発振レーザーキャビティリングダウン吸収分光法による亜酸化窒素および亜硝酸の大気計測2013

    • Author(s)
      高橋遼、戸野倉賢一
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-23
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Measurement of atmospheric NO2using mid-infrared cavity ring-down spectroscopy2011

    • Author(s)
      コリントー、高橋遼、林瑠美子、山本征生、戸野倉賢一
    • Organizer
      第17回大気化学討論会
    • Place of Presentation
      京都大学
    • Year and Date
      2011-10-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Measurement of atmospheric NO2 using mid-infrared cavity ring-down spectroscopy2011

    • Author(s)
      コリントー、高橋遼、林瑠美子、山本征生、戸野倉賢一
    • Organizer
      第17回大気化学討論会
    • Place of Presentation
      京都大学生存圏研究所
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.tonokura-lab.k.u-tokyo.ac.jp/

    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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