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Heterogeneous reactions with HOx radicals and property changes in organic aerosol particles

Research Project

Project/Area Number 22310018
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionJapan Agency for Marine-Earth Science and Technology

Principal Investigator

KANAYA Yugo  独立行政法人海洋研究開発機構, 地球環境変動領域, チームリーダー (60344305)

Co-Investigator(Renkei-kenkyūsha) TAKETANI Fumikazu  独立行政法人海洋研究開発機構, 地球環境変動領域, 研究員 (50377785)
KOMAZAKI Yuichi  独立行政法人海洋研究開発機構, 地球環境変動領域, 主任研究員 (80286640)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2011: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywords有機エアロゾル / 大気中酸化 / 光学特性 / 不均一反応 / 吸湿特性 / 環境質定量化・予測 / 地球変動予測 / 大気現象
Research Abstract

Changes in the optical properties of organic aerosol particles upon exposure to HOx radicals, major atmospheric oxidants, were measured in the laboratory. Dependence of the scattering coefficient on the relative humidity was measured with an integrating nephelometer equipped with a humidifier. In addition to aging, presence of organics originally having large hygroscopicity could control the optical properties of the atmospheric organic aerosols. These findings were used to interpret the roles of organics in determining the humidity dependence of the aerosol scattering coefficient as observed in China and Fukue Island.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (15 results)

All 2013 2012 2011

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (11 results)

  • [Journal Article] Kinetic studies of heterogeneous reaction of HO2 radical by dicarboxylic acid particles2013

    • Author(s)
      Taketani, F. et al
    • Journal Title

      Int. J. Chem. Kinet

      Volume: (in press)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic studies of heterogeneous reaction of HO2 radical by dicarboxylic acid particles2013

    • Author(s)
      Fumikazu Taketani
    • Journal Title

      Int. J. Chem. Kinet.

      Volume: 印刷中

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of overall uptake coefficients for HO2 radicals by aerosol particles sampled from ambient air at Mts. Tai and Mang (China)2012

    • Author(s)
      Taketani, F. et al
    • Journal Title

      Atmos. Chem. Phys

      Volume: 12 Issue: 24 Pages: 11907-11916

    • DOI

      10.5194/acp-12-11907-2012

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparisons of observed and modeled OH and HO2 concentrations during the ambient measurement period of the HOxComp field campaign2012

    • Author(s)
      Kanaya, Y. et al
    • Journal Title

      Atmos. Chem. Phys

      Volume: 12 Issue: 5 Pages: 2567-2585

    • DOI

      10.5194/acp-12-2567-2012

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] Isoprene chemical mechanism evaluation using ensemble observations of ambient HOx concentrations during the HOxComp field campaign2012

    • Author(s)
      金谷有剛ほか
    • Organizer
      IGAC International Science Conference 2012
    • Place of Presentation
      北京市(国家会議センター)、中国
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Comparisons of observed and modeled OH and HO2 concentrations during the ambient measurement period of the HOxComp field campaign2012

    • Author(s)
      金谷有剛ほか
    • Organizer
      EGU General Assembly 2012
    • Place of Presentation
      ウィーン市(ウィーン国際会議場)、オーストリア
    • Year and Date
      2012-04-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 大気中イソプレン新規気相反応のHOxラジカル濃度への影響2012

    • Author(s)
      金谷有剛ほか
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜市(慶応大学)
    • Year and Date
      2012-03-26
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Comparisons of observed and modeled OH and HO2 concentrations during the ambient measurement period of the HOxComp field campaign2012

    • Author(s)
      金谷有剛
    • Organizer
      EGU General Assembly 2012
    • Place of Presentation
      ウィーン市(ウィーン国際会議場)、オーストリア
    • Related Report
      2012 Annual Research Report
  • [Presentation] Isoprene chemical mechanism evaluation using ensemble observations of ambient HOx concentrations during the HOxComp field campaign2012

    • Author(s)
      金谷有剛
    • Organizer
      IGAC International Science Conference 2012
    • Place of Presentation
      北京市(国家会議センター)、中国
    • Related Report
      2012 Annual Research Report
  • [Presentation] Dependence of aerosol scattering coefficients on relative humidity observed at two coastal sites on the East China Sea: Comparison to remote observations and influence of chemical composition2011

    • Author(s)
      金谷有剛ほか
    • Organizer
      AGU fall meeting 2011
    • Place of Presentation
      サンフランシスコ市(モスコーニ会議場)、米国
    • Year and Date
      2011-12-09
    • Related Report
      2012 Final Research Report
  • [Presentation] Dependence of aerosol scattering coefficients on relative humidity observed at two coastal sites on the East China Sea : Comparison to remote observations and influence of chemical composition2011

    • Author(s)
      金谷有剛
    • Organizer
      AGU fall meeting 2011
    • Place of Presentation
      サンフランシスコ市(モスコーニ会議場)
    • Year and Date
      2011-12-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] イソプレン大気化学反応はHOxラジカルを効率的に再生するか:HOxCOMP観測による検証2011

    • Author(s)
      金谷有剛ほか
    • Organizer
      第17回大気化学討論会
    • Place of Presentation
      宇治市(京都大学)
    • Year and Date
      2011-10-18
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] 2010年春季中国江蘇省Rudongにおける大気成分総合集中観測:目的と初期成果2011

    • Author(s)
      金谷有剛ほか
    • Organizer
      日本地球惑星科学連合2011年大会
    • Place of Presentation
      千葉市(幕張メッセ)
    • Year and Date
      2011-05-23
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] 野外大気およびシミュレーションチャンバーSAPHIRにおける大気中OH,HO2ラジカル濃度測定の公式相互比較:HOxComp2011

    • Author(s)
      金谷有剛ほか
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜市(神奈川大)
    • Year and Date
      2011-03-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 野外大気およびシミュレーションチャンバーSAPHIRにおける大気中OH, HO2ラジカル濃度測定の公式相互比較:HOxComp2011

    • Author(s)
      金谷有剛
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜市(神奈川大)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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