| Budget Amount *help |
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2011: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
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| Research Abstract |
Synthesis of functional solids for the efficient use of energy and material is an important task. In this work, complexation of nano-sized metal-oxide clusters with macrocations and mononuclear metal cations was attempted. Ionic crystals (complexes) with controlled pore sizes, volumes, dimensionalities, and guest affinities were synthesized. Guest sorption properties were investigated with in situ spectroscopy, X-ray diffraction, quantum mechanics, and the compounds were applied as separation materials and catalysts.
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