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Development of new catalytic reactions by materials design and kinetics measurements

Research Project

Project/Area Number 22350005
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

SASAKI Takehiko  東京大学, 新領域創成科学研究科, 准教授 (90242099)

Project Period (FY) 2010-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywordsナノ結晶 / 反応性 / 構造 / 電子状態 / 触媒反応 / 酸化セリウム / パラジウム / 固定化イオン液体触媒 / TAP / 密度汎関数法計算 / 電子構造 / 白金クラスター / 金ナノ粒子 / EXAFS / TEM / 物質設計 / ナノ粒子 / 酸化コバルト / 固体触媒反応 / 炭酸マンガン / 形状制御 / 計算化学 / 階層性 / ナノベルト / ベンズイミダゾール誘導体
Research Abstract

Co(OH)3 was synthesized first and characterized with SEM, TEM and XRD. Shape of nanocrystals of Co3O4 can be controlled by using different types of surfactants and organic solvents. Co oxides and hydroxides were used to catalyze o-phenylenediamine and benzaldehyde to yield benzimidazole. Copper, platinum, gold and hydrodesulfurization catalysts were characterized by EXAFS, TEM and XPS, giving the information of correlation between reactivity and structure. Pd containing immobilized ionic liquid catalyst was found to be effective and reusable catalyst for carbonylation reactions and carbonylative Suzuki coupling reactions.

Report

(5 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (12 results) (of which Invited: 4 results) Remarks (1 results)

  • [Journal Article] Efficient, recyclable and phosphine-free carbonylative Suzuki coupling reaction using immobilized palladium ion-containing ionic liquid : Synthesis of aryl ketones and heteroaryl ketones2013

    • Author(s)
      M.V. Khedkar, T. Sasaki, B.M. Bhanage
    • Journal Title

      RSC Advances

      Volume: 3 Issue: 21 Pages: 7791-7797

    • DOI

      10.1039/c3ra40730f

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Immobilized Palladium Metal-Containing Ionic Liquid-Catalyzed Alkoxycarbonylation, Phenoxycarbonylation, and Aminocarbonylation Reactions2013

    • Author(s)
      M.V. Khedkar, T. Sasaki, B.M. Bhanage
    • Journal Title

      ACS Catal

      Volume: 3 Issue: 3 Pages: 287-293

    • DOI

      10.1021/cs300719r

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultradeep hydrodesulfurization of diesel fuels using highly efficient nanoalumina-supported catalysts : Impact of support, phosphorus, and/or boron on the structure and catalytic activity2013

    • Author(s)
      F. Rashidi, T. Sasaki, A.M. Rashidi, A.N. Kharat, K. J. Jozani
    • Journal Title

      J. Catal

      Volume: 299 Pages: 321-335

    • DOI

      10.1016/j.jcat.2012.11.012

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold nanoparticles stabilized on nanocrystalline magnesium oxide as an active catalyst for reduction of nitroarenes in aqueous medium at room temperature2012

    • Author(s)
      K. Layek, M.L. Kantam, M. Shirai, D. Nishio-Hamane, T. Sasaki and H. Maheswaran
    • Journal Title

      Green Chemistry

      Volume: 14 Issue: 11 Pages: 3164-3174

    • DOI

      10.1039/c2gc35917k

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aqueous phase reforming of glycerol to 1,2-propanediol over Pt-nanoparticles supported on hydrotalcite in the absence of hydrogen2012

    • Author(s)
      C. Pendem, P. Gupta, N. Chaudhary, S. Singh, J. Kumar, T. Sasaki, A. Datta, and R. Bal
    • Journal Title

      Green Chemistry

      Volume: 14 Issue: 11 Pages: 3107-3113

    • DOI

      10.1039/c2gc36019e

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room temperature selective oxidation of cyclohexane over Cu-nanoclusters supported on nanocrystalline Cr_2O_32012

    • Author(s)
      B. Sarkar, P. Prajapati, R. Tiwari, R. Tiwari, S. Ghosh, S. S. Acharyya, C. Pendem, R.K. Singha, L.N.S. Konathala, J. Kumar, T. Sasaki, and R. Bal
    • Journal Title

      Green Chemistry

      Volume: 14 Issue: 9 Pages: 2600-2606

    • DOI

      10.1039/c2gc35658a

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room temperature synthesis of benzimidazole derivatives using reusable cobalt hydroxide (II) and cobalt oxide (II) as efficient solid catalysts2011

    • Author(s)
      M.Adharvana Chari, D. Shobha, T. Sasaki
    • Journal Title

      Tetrahedron Letters

      Volume: 52 Issue: 43 Pages: 5575-5580

    • DOI

      10.1016/j.tetlet.2011.08.047

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphological Control of Single Crystalline Co_3O_4 Polyhedrons : Selective and Non-selective Growth of Crystal Planes Directed by Differently Charged Surfactants and Solvents2010

    • Author(s)
      Jinhu Yang and Takehiko Sasaki
    • Journal Title

      Crystal Growth & Design

      Volume: 10 Issue: 3 Pages: 1233-1236

    • DOI

      10.1021/cg9012284

    • Related Report
      2013 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Co(OH)3 Nanobelts : Synthesis, Characterization and Shape-preserved Transformation to Pseudo-single-crystalline Co_3O_4 Nanobelts2010

    • Author(s)
      Jinhu Yang, Hiroshi Hyodo, Kaoru Kimura and Takehiko Sasaki
    • Journal Title

      Nanotechnology

      Volume: 21 Issue: 4 Pages: 45605-11

    • DOI

      10.1088/0957-4484/21/4/045605

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Co(OH)_3 Nanobelts : Synthesis, Characterization and Shape-preserved Transformation to Pseudo-single-crystalline Co_3O_4 Nanobelts2010

    • Author(s)
      Jinhu Yang, Hiroshi Hyodo, Kaoru Kimura, Takehiko Sasaki
    • Journal Title

      Nanotechnology

      Volume: 21 Pages: 45605-11

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO_2-Supported Ru-Monomer Complex Catalyst2010

    • Author(s)
      M.Tada, S.Muratsugu, M.Kinoshita, T.Sasaki, Y.Iwasawa
    • Journal Title

      J Am.Chem.Soc.

      Volume: 132 Pages: 713-724

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Pd 含有固定化イオン液体触媒によるカルボニル化を伴うSuzuki カップリング反応2014

    • Author(s)
      M.V. Khedkar, 佐々木岳彦, B.M. Bhanage
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-30
    • Related Report
      2013 Final Research Report
  • [Presentation] パラジウム含有固定化イオン液体触媒によるカルボニレーション反応2013

    • Author(s)
      M.V. Khedkar, 佐々木岳彦, B.M. Bhanage
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学
    • Year and Date
      2013-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Materials development for catalytic reactions : nanocrystals and ionic liquids2013

    • Author(s)
      Takehiko Sasaki
    • Organizer
      Indo-Japan Conference on Catalysis : A Green Chemistry Approach
    • Place of Presentation
      インド ムンバイICT
    • Year and Date
      2013-02-13
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Syntheses of benzimidazole derivatives using cobalt oxides2013

    • Author(s)
      Takehiko Sasaki
    • Organizer
      CoO in MCM-41 and ceria, Catsymp-21
    • Place of Presentation
      インド ハイデラバード IICT
    • Year and Date
      2013-02-11
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 金属酸化物による二酸化炭素の固定化 : 2-ヒドロキシベンゾイミダゾールの生成2012

    • Author(s)
      佐々木岳彦
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2012-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] 修飾銅電極表面を用いた二酸化炭素の変換2012

    • Author(s)
      佐々木岳彦, 野口将希
    • Organizer
      日本化学会春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-25
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] Shape and Size Control of Manganese Carbonate and Manganese Oxide Nano Particles2011

    • Author(s)
      Giuseppe Granata, 佐々木岳彦
    • Organizer
      日本表面科学会東北・北海道支部講演会
    • Place of Presentation
      東北大学
    • Year and Date
      2011-03-10
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] パラジウム含有固定化イオン液体触媒によるカルボニレーション反応

    • Author(s)
      M.V. Khedkar, 佐々木 岳彦、 B.M. Bhanage
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd含有固定化イオン液体触媒によるカルボニル化を伴うSuzukiカップリング反応

    • Author(s)
      M.V. Khedkar, 佐々木 岳彦、 B.M. Bhanage
    • Organizer
      日本化学会 第94回春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属酸化物による二酸化炭素の固定化:2-ヒドロキシベンゾイミダゾールの生成

    • Author(s)
      佐々木岳彦
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Syntheses of benzimidazole derivatives using cobalt oxides, CoO in MCM-41 and ceria

    • Author(s)
      佐々木岳彦
    • Organizer
      Catsymp-21
    • Place of Presentation
      インド ハイデラバード
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Materials development for catalytic reactions: nanocrystals and ionic liquids

    • Author(s)
      佐々木岳彦
    • Organizer
      Indo-Japan Conference on Catalysis: A Green Chemistry Approach
    • Place of Presentation
      インド ムンバイ
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Remarks]

    • URL

      http://sas.k.u-tokyo.ac.jp/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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