| Budget Amount *help |
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Research Abstract |
Transmetalation reactions of tritellurosilane, trisilylsilane and trisilylgermane afforded the corresponding monolithio species. Reinvestigation on the transmetalation reaction of trisilylstannane provided lithiostannane, which surprisingly reacted as a trianion equivalent. Germyldichlorophosphine derived from lithiogermane reacted with potassium t-butoxide to afford phosphagermavinylidene dimer, suggesting that formation of an intermediary germanium-phosphorus triple-bonded compound.
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