Construction and Search for the Function of Novel Phosphole-Based π-Conjugated Molecules
| Project/Area Number |
22350016
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
|
|---|
| Keywords | ホスホール / チタナサイクル / クロスカップリング / 多量体 / キャリヤ移動度 / 有機太陽電池 / 光活性層 / 光電変換特性 / 有機薄膜太陽電池 / バッファ層 / キャリア移動度 / Time-Of-Flight法 / 酸化還元 / 電荷移動特性 / 縮環 / X線結晶構造解析 / 電子受容能 / 電子輸送能 |
|---|
| Research Abstract |
New efficient methodsfor the synthesis of phosphole-containing π-conjugated molecules were established, and their structure-property relationships were unveiled by various spectroscopy and X-ray crystallography. In addition, some derivatives with high electron-transporting and/or visible-light absorbing abilities were utilized for organic photovoltaics. All the results represent high potential of the newly constructed phosphole derivatives as functional organic materials.
|
Report
(4 results)
Research Products
(28 results)
-
-
-
-
-
-
-
[Journal Article] Fusion of Phosphole and 1,1'-Biacenaphthene : Phosphorus(V)-Containing Extended p-Systems with High Electron Affinity and Electron Mobility2011
Author(s)
Y.Matano, A.Saito, T.Fukushima, Y.Tokudome, F.Suzuki, D.Sakamaki, H.Kaji, A.Ito, K.Tanaka, H.Imahori
-
Journal Title
Angew.Chem.Int.Ed.
Volume: 50
Issue: 35
Pages: 8016-8020
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
