| Budget Amount *help |
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2011: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2010: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
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| Research Abstract |
In quest of novel electronic-/magnetic materials based on open-shell graphene fragments, design and synthesis of trioxotriangulene (TOT) derivatives, air-stable organic neutral radicals with three oxygen atoms on a triangulene skeleton, and disclosure of their properties in the solution and solid state have been carried out. We have successfully controlled molecular stability, π-stacking mode by SOMO-SOMO interaction, redox ability in terms of modification of the frontier molecular orbitals and the electronic-spin density distribution by substituent effect in a controlled manner
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