| Budget Amount *help |
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2012: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2011: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2010: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
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| Research Abstract |
To explore the chemistry of planar chiral heterocycles, we achieved the following: 1) stereoselective multimodal transformations of planar chiral nine-membered diallylic amides; 2) a unique functional group transformation of planar chiral nine-membered diallylic amides by using PtCl2 (2,4,6-trimethylpyridine) complexes; 3) enantioselective synthesis of planar chiral nine-membered diallylic amides; 4) synthesis and application of planar chiral (E)-5-cyclononen-1-one and its enolate; and 5) synthesis and application of planar chiral [7]orthocyclophanes
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