Synthesis and Application of Planar Chiral Heterocycles
Project/Area Number |
22350019
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
|
Co-Investigator(Renkei-kenkyūsha) |
IGAWA Kazunobu 九州大学, 先導物質化学研究所, 助教 (80401529)
ITO Masato 九州大学, 先導物質化学研究所, 准教授 (20293037)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2012: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2011: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2010: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
|
Keywords | 有機化学 / 不斉合成 / 面不斉 / ヘテロ中員環分子 / 面不斉錯体 / 面不斉カルボニル化合物 |
Research Abstract |
To explore the chemistry of planar chiral heterocycles, we achieved the following: 1) stereoselective multimodal transformations of planar chiral nine-membered diallylic amides; 2) a unique functional group transformation of planar chiral nine-membered diallylic amides by using PtCl2 (2,4,6-trimethylpyridine) complexes; 3) enantioselective synthesis of planar chiral nine-membered diallylic amides; 4) synthesis and application of planar chiral (E)-5-cyclononen-1-one and its enolate; and 5) synthesis and application of planar chiral [7]orthocyclophanes
|
Report
(4 results)
Research Products
(70 results)
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[Journal Article] Igawa KazunobuPlanar-Chiral2012
Author(s)
Tomooka Katsuhiko, Iso Chisato, Uehara Kazuhiro, Suzuki Masaki, Nishikawa-Shimono Rie
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Journal Title
Orthocyclophanes Angew. Chem. Int. Ed
Volume: 51
Issue: 41
Pages: 10355-10358
DOI
Related Report
Peer Reviewed
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