SynthesisandMetalCoordinationofN-ConfusedCorrole
| Project/Area Number |
22350020
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TOGANOH Motoki 九州大学, 工学研究院, 助教 (80372754)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2012: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2010: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
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| Keywords | ポルフィリン / N-混乱ポルフィリン / コロール / Nー混乱ポルフィリン / Nー混乱コロール / ノロール / ビラン / 二量体 / 混乱異性体 / 複核錯体 / ヘキサフィリン / 異性体 / 混乱コロール / 互変異性 / 銅錯体 |
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| Research Abstract |
Three types of N-confused corrole isomers (NCC) were synthesized using oxidative cyclization of confusedtetrapyrrole (bilanes), and the structures of these isomers were revealed by single-crystal X-ray crystallography. Theposition of the confused pyrrole ring in the NCC has a pronounced effect on optical and anion binding properties.
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Report
(4 results)
Research Products
(132 results)
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[Journal Article]2012
Author(s)
Toganoh, M.; Kawabe, Y.; Uno, H.; Furuta,H
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Journal Title
Angew. Chem. Int. Ed.
Volume: 51
Pages: 8753-8756
Related Report
Peer Reviewed
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[Journal Article]2012
Author(s)
Fasciotti, M.; Gomes, A. F.; Gozzo, F. C.;Iglesias, B. A.; de Sa, G. F.; Daroda, R. J.;Toganoh, M.; Furuta, H.; Araki, K.; Eberlin, M.
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Journal Title
N. Org. Biomol. Chem.
Volume: 10
Pages: 8396-8402
Related Report
Peer Reviewed
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[Journal Article]2012
Author(s)
Toganoh, M.; Gokulnath, S.; Kawabe, Y.;Furuta, H
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Journal Title
Chem. Eur. J.
Volume: 18
Pages: 4380-4391
Related Report
Peer Reviewed
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[Journal Article] Deprotonation-Induced Aromaticity Enhancement and New Conjugated Networks in meso-Hexakis(pentafluorophenyl)[26]hexaphyrin2012
Author(s)
W.-Y. Cha, J. M. Lim, M.-C. Yoon, Y. M. Sung, B. S. Lee, S. Katsumata, M. Suzuki, H. Mori, A. Osuka, Y. Ikawa, H. Furuta, and D. Kim
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Journal Title
Chem. Eur. J
Volume: 18
Issue: 49
Pages: 15838-15844
DOI
Related Report
Peer Reviewed
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[Journal Article]2011
Author(s)
Fujino, K.; Hirata, Y.; Kawabe, Y.;Morimoto, T.; Srinivasan, A.; Toganoh, M.;Miseki, Y.; Kudo, A.; Furuta, H.
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Journal Title
Angew. Chem.Int. Ed.
Volume: 50
Pages: 6855-6859
Related Report
Peer Reviewed
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