| Budget Amount *help |
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2012: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2011: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2010: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
|
|---|
| Research Abstract |
Self- -conjugated oligomers with open-shell electronic structure has been intnsively investigated as models of corresponding conducting polymers, but the details about the phenomena remains to be elucidated. In addition, recent years have witnessed a growing interest in supramolecular chemistry using such self-associations. In this study, based on our originally designed oligothiophenes, we have revealed relationship between structure and factors driving the self-association and have succeeded in the observations of redox-switching via gold nanoparticles and biradical character of dications.
|
