Syntheses of functional molecules using highly strained sp-carbon atoms in unsaturated cyclic organometallic compounds

• Project/Area Number: 22350022
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Sophia University
• Principal Investigator: SUZUKI Noriyuki 上智大学, 理工学部, 准教授 (90241231)
• Project Period (FY): 2010-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000); Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2010: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
• Keywords: ジルコニウム / 環状アレン / カルベン / エンイン / 複素環 / イオウ / 窒素 / 環状アルキン / 有機金属化合物 / アルキニルイミン / クムレン / 炭素-炭素結合生成

Research Abstract

We studied on the synthesis, structure and reactivity on conjugated five-membered alkyne complexes derived from group 4 metals and cumulene derivatives. We also investigated five-membered cyclic allenes that are formed from conjugated enynes on the property of highly strained sp carbon in the cyclic unsaturated compounds. It is difficult to isolate one of the isomers of E/Z-[5]cumulenes because of low barrier for isomerization. We succeeded in isolation of the E-isomer and trapping the Z-isomer as a metal complex. Haptotropic interconversion between cyclic structure and eta2-coordination was also examined and the effect of steric environment of the substituents were found. We have found facile preparative method of five-membered cyclic allene from conjugated enyne.

Research Products

• [Journal Article] Improved Negishi Cross-Coupling Reactions of an Organozinc Reagent Derived from L-Aspartic Acid with Monohalopyridines (2014)
  • Author(s): Toyonobu Usuki, Hiroto Yanuma, Takahiro Hayashi, Haruka Yamada, Noriyuki Suzuki, Yoshiro Masuyama
  • Journal Title: J. Heterocycl. Chem. Volume: 51 Issue: 1 Pages: 269-273
  • DOI: 10.1002/jhet.1807
  • Peer Reviewed
• [Journal Article] Synthesis and structure of seven-membered metallacycloalkynes (2013)
  • Author(s): Noriyuki Suzuki, Takashi Tsuchiya, Naoto Aihara, Masakazu Iwasaki, Masahiko Saburi, Teiji Chihara, Yoshiro Masuyama
  • Journal Title: Eur. J. Inorg. Chem Pages: 347-356
  • Peer Reviewed
• [Journal Article] Synthesis of Seven-membered Cyclic Allenes, 1-Zirconacyclohepta-2,3,6-trienes, from Alkynes and 1-En-3-ynes (2013)
  • Author(s): Noriyuki Suzuki, Takashi Tsuchiya, Yoshiro Masuyama
  • Journal Title: J. Organomet. Chem
  • Peer Reviewed
• [Journal Article] Synthesis of Seven-membered Cyclic Allenes, 1-Zirconacyclohepta-2,3,6-trienes, from Alkynes and 1-En-3-ynes (2013)
  • Author(s): Noriyuki Suzuki, Takashi Tsuchiya, Yoshiro Masuyama
  • Journal Title: J. Organomet. Chem. Volume: 741-742 Pages: 91-96
  • DOI: 10.1016/j.jorganchem.2013.05.023
  • Peer Reviewed
• [Journal Article] Cyclotrimerization of Terminal Alkynes Catalyzed by a Phosphine-Free Chloro(1,5-cyclooctadiene)iridium(I) Dimer and Induced by Tin(II) Chloride (2013)
  • Author(s): Yoshiro Masuyama, Kana Miyazaki, Noriyuki Suzuki
  • Journal Title: Asian J. Org. Chem. Volume: 2 Issue: 9 Pages: 750-754
  • DOI: 10.1002/ajoc.201300132
  • Peer Reviewed
• [Journal Article] Tin(II) Chloride-Mediated Coupling Reaction between Alkynes and Aldehydes (2013)
  • Author(s): Yoshiro Masuyama, Wataru Takamura, Noriyuki Suzuki
  • Journal Title: Eur. J. Org. Chem. Volume: 2013 Issue: 35 Pages: 8033-8038
  • DOI: 10.1002/ejoc.201301189
  • Peer Reviewed
• [Journal Article] Asymmetric Aldol Reaction on Water Using an Organocatalyst Tethered on a Thermoresponsive Block Copolymer (2013)
  • Author(s): Noriyuki Suzuki, Takahiro Inoue, Takumi Asada, Ryuji Akebi, Go Kobayashi, Masahiro Rikukawa, Yoshiro Masuyama, Masamichi Ogasawara, Tamotsu Takahashi, San H. Thang
  • Journal Title: Chemistry Letters Volume: 42 Issue: 12 Pages: 1493-1495
  • DOI: 10.1246/cl.130711
  • NAID: 130004867826
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Ene reactions of (Z)-1,4-Bis(trimethylsilyl)buta-1,2,3-triene with a,b-Unsaturated Carbonyl Compounds (2013)
  • Author(s): Noriyuki Suzuki,* Masahiro Kaneko, Yasushi Kuroda, Amane Sasaki, Yoshiro Masuyama
  • Journal Title: Tetrahedron Letters Volume: 54 Issue: 22 Pages: 2813-2816
  • DOI: 10.1016/j.tetlet.2013.03.079
  • Peer Reviewed
• [Journal Article] SnCl2-Catalyzed propargylic substitution of propargylic alcohols with carbon and nitrogen nucleophiles (2013)
  • Author(s): Yoshiro Masuyama, Miki Hayashi, Noriyuki Suzuki
  • Journal Title: Eur. J. Org. Chem. Volume: 2013 Issue: 14 Pages: 2914-2921
  • DOI: 10.1002/ejoc.201201673
  • Peer Reviewed
• [Journal Article] Studies on The Mechanism for Stereoisomerization of 1-Zirconacyclopent-3-yne Compounds (2012)
  • Author(s): Noriyuki Suzuki, Kosuke Nishimura, Nozomu Ohara, Masayoshi Nishiura, Yoshiro Masuyama
  • Journal Title: J. Organomet. Chem Volume: 696 Pages: 4321-4326
  • Peer Reviewed
• [Journal Article] Facile Formation of Five-membered N-heterocyclic Zirconacycloallenoids (2012)
  • Author(s): Santhosh Kumar Podiyanachari, Roland Fröhlich, Constantin G. Daniliuc, Jeffrey L. Petersen, Gerald Kehr, Gerhard Erker, Noriyuki Suzuki, Shin Yuasa, Keita Hagimori, Shota Inoue, Takumi Asada, Takahiko Takemoto, Yoshiro Masuyama
  • Journal Title: Dalton. Trans Volume: 41 Pages: 10811-10816
  • Peer Reviewed
• [Journal Article] Syntheses and Structures of Titanium Complexes Having O,N,O-Tridentate Ligands And Their Catalytic Ability for Ethylene Polymerization (2012)
  • Author(s): Noriyuki Suzuki, Go Kobayashi, Takeshi Hasegawa, Yoshiro Masuyama
  • Journal Title: J. Organomet. Chem. Volume: 717 Pages: 23-28
  • DOI: 10.1016/j.jorganchem.2012.07.030
  • Peer Reviewed
• [Journal Article] Facile Formation of Five-membered N-heterocyclic Zirconacycloallenoids (2012)
  • Author(s): S. K. Podiyanachari, R. Froehlich, C. G. Daniliuc, J. L. Petersen, G. Kehr, Gerhard Erker, Noriyuki Suzuki, S. Yuasa, K. Hagimori, S. Inoue, T. Asada, T. Takemoto, Y. Masuyama
  • Journal Title: Dalton. Trans. Volume: 41 Issue: 35 Pages: 10811-10816
  • DOI: 10.1039/c2dt31343j
  • Peer Reviewed
• [Journal Article] Studies on The Mechanism for Stereoisomerization of 1-Zirconacyclopent-3-yne Compounds (2012)
  • Author(s): Noriyuki Suzuki, Kosuke Nishimura, Nozomu Ohara, Masayoshi Nishiura, Yoshiro Masuyama
  • Journal Title: Journal of Organometallic Chemistry Volume: 696 Issue: 26 Pages: 4321-4326
  • DOI: 10.1016/j.jorganchem.2011.10.009
  • Peer Reviewed
• [Journal Article] Palladium (II)-exchanged hydroxyapatite-catalyzed Suzuki-Miyaura-type cross-coupling reactions with potassiumaryltrifluoroborates (2012)
  • Author(s): Yoshiro Masuyama, Yutaka Sugioka, Shiori Chonan, Masahiro Fujita, Noriyuki Suzuki, Kenji Hara, Atsushi Fukuoka
  • Journal Title: Journal of Molecular Catalysis, A.Chemical Volume: 352 Pages: 81-85
  • DOI: 10.1016/j.molcata.2011.10.017
  • Peer Reviewed
• [Journal Article] Total synthesis of COPD biomarker desmosine that crosslinks elastin (2012)
  • Author(s): Toyonobu Usuki, Haruka Yamada, Takahiro Hayashi, Hiroto Yanuma, Yohei Koseki, Noriyuki Suzuki, Yoshiro Masuyama, Yong Y.Lin
  • Journal Title: Chemical Communications Volume: 48 Issue: 26 Pages: 3233-3235
  • DOI: 10.1039/c2cc17958j
  • Peer Reviewed
• [Journal Article] Straightforward Synthesis of Five-Membered Metallacycloallenes; 1-Zirconacyclopenta-2,3-diene Compounds Derived from 1,3-Enynes (2011)
  • Author(s): Noriyuki Suzuki, Taichiro Shimura, Yoshio Sakaguchi, Yoshiro Masuyama
  • Journal Title: Pure Appl. Chem Volume: 83(9) Pages: 1781-1788
  • Peer Reviewed
• [Journal Article] Characterization of the E Isomer of Tetrasubstituted [5]Cumulene and Trapping of the Z Isomer as a Zirconocene Complex (2011)
  • Author(s): Noriyuki Suzuki, Nozomu Ohara, Kosuke Nishimura, Yoshio Sakaguchi, Shinkoh Nanbu, Sohei Fukui, Hirotaka Nagao, Yoshiro Masuyama
  • Journal Title: Organometallics Volume: 30 Pages: 3544-3548
  • Peer Reviewed
• [Journal Article] Straightforward Synthesis of Five-Membered Metallacycloallenes ; 1-Zirconacyclopenta-2,3-diene Compounds Derived from 1,3-Enynes (2011)
  • Author(s): Noriyuki Suzuki, Taichiro Shimura, Yoshio Sakaguchi, Yoshiro Masuyama
  • Journal Title: Pure and Applied Chemistry Volume: 83 Issue: 9 Pages: 1781-1788
  • DOI: 10.1351/pac-con-11-01-14
  • Peer Reviewed
• [Journal Article] Syntheses and Characterization of Ethylbis (2-pyridylethyl) amineruthenium Complexes and Two Different Types of C-H Bond Cleavage at an Ethylene Arm (2011)
  • Author(s): Sohei Fukui, Akari Kajiwara, Toshiyuki Hirano, Fumitoshi Sato, Noriyuki Suzuki, Hirotaka Nagao
  • Journal Title: Inorganic Chemistry Volume: 50 Issue: 11 Pages: 4713-4724
  • DOI: 10.1021/ic101940f
  • Peer Reviewed
• [Journal Article] Characterization of the E Isomer of Tetrasubstituted [5] Cumulene and Trapping of the Z Isomer as a Zirconocene Complex (2011)
  • Author(s): Noriyuki Suzuki, Nozomu Ohara, Kosuke Nishimura, Yoshio Sakaguchi, Shinkoh Nanbu, Sohei Fukui, Hirotaka Nagao, Yoshiro Masuyama
  • Journal Title: Organometallics Volume: 30 Issue: 13 Pages: 3544-3548
  • DOI: 10.1021/om2002427
  • Peer Reviewed
• [Journal Article] Hydroxyapatite-supported copper (II)-catalyzed azide-alkyne [3+2] cycloaddition with neither reducing agents nor bases in water (2011)
  • Author(s): Yoshiro Masuyama, Kazuki Yoshikawa, Noriyuki Suzuki, Kenji Hara, Atsushi Fukuoka
  • Journal Title: Tetrahedron Letters Volume: 52 Issue: 51 Pages: 6916-6918
  • DOI: 10.1016/j.tetlet.2011.10.060
  • Peer Reviewed
• [Journal Article] Five-membered metallacycloalkynes formed from group 4 metals and [n]cumulene(n=3,5) ligands (2010)
  • Author(s): Noriyuki Suzuki, Daisuke Hashizume
  • Journal Title: Coordination Chemistry Reviews Volume: 254 Pages: 1307-1326
  • NAID: 120005880479
  • Peer Reviewed
• [Journal Article] Formation and Structure of an (Iminium ion)ruthenium Complex and Reaction of the Iminium Ion Moiety with Alcohols (2010)
  • Author(s): Sohei Fukui, Noriyuki Suzuki, Tohru Wada, Koji Tanaka, Hirotaka Nagao
  • Journal Title: Organometallics Volume: 29 Pages: 1534-1536
  • Peer Reviewed
• [Presentation] 金属を含む環状アレン錯体の合成 (2014)
  • Author(s): 栗田理華子, 浅田拓海, 鈴木教之, 増山芳郎
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 日名古屋大学(名古屋)(2PB-034)
  • Year and Date: 2014-03-28
• [Presentation] 金属を含む環状アレン錯体の合成 (2014)
  • Author(s): 栗田理華子・浅田拓海・鈴木教之・増山芳郎
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] 有機触媒固定化ポリマーを用いる水中不斉アルドール反応 (2014)
  • Author(s): 明比龍史・井上貴裕・浅田拓海・鈴木教之・増山芳郎
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学
• [Presentation] 遷移金属と N, S 原子を含む 5 員環アレンの合成 (2013)
  • Author(s): 浅田拓海, 湯浅 伸, 鈴木教之, 増山芳郎
  • Organizer: 日本化学会秋季事業-第3回CSJ 化学フェスタ
  • Place of Presentation: 船堀ホール(東京)(P1-86)
  • Year and Date: 2013-10-21
• [Presentation] アルキンと 1,3-エンインからの安定な七員環アレン化合物の合成 (2013)
  • Author(s): 土屋貴志, 鈴木教之, 増山芳郎
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学(東京)(P1A-06)
  • Year and Date: 2013-09-12
• [Presentation] Five- and Seven-membered Metallacycloallenes (2013)
  • Author(s): Noriyuki Suzuki
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2013
  • Place of Presentation: Beijing, China
• [Presentation] Synthesis of Seven-membered Cyclic Allenes That Consist of Organometallic Compounds (2013)
  • Author(s): Noriyuki Suzuki, Takashi Tsuchiya, Yoshiro Masuyama
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Singapore
• [Presentation] Synthesis and Structure of Heterobimetallic Complexes Bearing O,N,O-N,N-Multidentate Ligands (2013)
  • Author(s): Kenji Haraga, Noriyuki Suzuki, Yoshiro Masuyama
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Singapore
• [Presentation] Synthesis and Structure of Small Cyclic Allenes That Contain Nitrogen and Zirconium Atoms (2013)
  • Author(s): Takumi Asada, Noriyuki Suzuki, Yoshiro Masuyama
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Singapore
• [Presentation] アルキンと1,3-エンインからの安定な七員環アレン化合物の合成 (2013)
  • Author(s): 土屋貴志・鈴木教之・増山芳郎
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学(東京)
• [Presentation] 塩化スズ(II)により誘発された、電子豊富アレーン類のアルキン類への金(I)触媒求核付加反応 (2013)
  • Author(s): 栃木淳志・小倉智史・三村真理奈・鈴木教之・増山芳郎
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学(東京)
• [Presentation] ヒドロキシアパタイト固定化パラジウム触媒を用いる水溶液中での鈴木-宮浦クロスカップリング反応 (2013)
  • Author(s): 野村由佳・細谷晃・鈴木教之・増山芳郎
  • Organizer: 日本化学会秋季事業－第3回CSJ化学フェスタ2013
  • Place of Presentation: 船堀ホール(東京)
• [Presentation] 遷移金属と N, S 原子を含む五員環アレンの合成 (2013)
  • Author(s): 浅田拓海・湯浅伸・鈴木教之・増山芳郎
  • Organizer: 日本化学会秋季事業－第3回CSJ化学フェスタ2013
  • Place of Presentation: 船堀ホール(東京)
• [Presentation] Organocatalyst Tethered on Thermosensitive Polymer for Asymmetric Aldol Reactions (2013)
  • Author(s): Takahiro Inoue, Takumi Asada, Go Kobayashi, Noriyuki Suzuki, Yoshiro Masuyama, Masahiro Rikukawa, Masamichi Ogasawara, San H. Thang
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Singapore
• [Presentation] Five- and Seven-membered Metallacycloallenes (2013)
  • Author(s): Noriyuki Suzuki
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2013
  • Place of Presentation: Beijing
  • Invited
• [Presentation] ジルコニウムと窒素原子を含む 5 員環アレン化合物の合成 (2012)
  • Author(s): 湯淺 伸, 萩森圭太, 井上翔太, 浅田拓海, 竹元貴彦, 鈴木教之, 増山芳郎
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学(吹田)(P3A-03)
  • Year and Date: 2012-09-15
• [Presentation] ブタトリエンと共役エノンのエン反応 (2012)
  • Author(s): 黒田康司, 金子真弘, 鈴木教之, 増山芳郎
  • Organizer: 日本化学会第92回春季年会
  • Place of Presentation: 慶應義塾大学(神奈川)(1K5-58)
  • Year and Date: 2012-03-25
• [Presentation] [5]クムレン類のジルコニウム錯体におけるハプトトロピックな配位挙動 (2012)
  • Author(s): 吉谷孝雄, 鈴木教之, 増山芳郎
  • Organizer: 日本化学会第92回春季年会
  • Place of Presentation: 慶應義塾大学(神奈川)(1PB-32)
  • Year and Date: 2012-03-25
• [Presentation] [5]クムレン類のジルコニウム錯体におけるハプトトロピックな配位挙動 (2012)
  • Author(s): 吉谷孝雄・鈴木教之・増山芳郎
  • Organizer: 日本化学会第92回春季年会
  • Place of Presentation: 慶応義塾大学矢上キャンパス
  • Year and Date: 2012-03-25
• [Presentation] (Z)-1,4-ビス(トリメチルシリル)ブタトリエンと共役エノンのエン反応 (2012)
  • Author(s): 黒田康司・金子真弘・鈴木教之・増山芳郎
  • Organizer: 日本化学会第92回春季年会
  • Place of Presentation: 慶応義塾大学矢上キャンパス
  • Year and Date: 2012-03-25
• [Presentation] O,N,O-三座配位子を有するチタン錯体の合成とオレフィン重合触媒活性 (2012)
  • Author(s): 小林剛・長谷川剛士・鈴木教之・増山芳郎
  • Organizer: 日本化学会第92回春季年会
  • Place of Presentation: 慶応義塾大学矢上キャンパス
  • Year and Date: 2012-03-25
• [Presentation] Synthesis of Five-membered Cycloallenes with Organometallics (2012)
  • Author(s): Noriyuki Suzuki
  • Organizer: Cambodian Malaysian Chemical Conference 2012
  • Place of Presentation: Siem Reap, Cambodia
  • Invited
• [Presentation] Steric Effects On Haptotropic Shift in Zirconocene Complexes Of [5]Cumulene Derivatives (2012)
  • Author(s): Noriyuki Suzuki, Shota Inoue, Takao Yoshitani, Yoshiro Masuyama
  • Organizer: XXV International Conference on Organometallic Chemistry
  • Place of Presentation: Lisbon, Portugal
• [Presentation] 異種複核触媒を指向したO,N,O-多座配位子を有するチタン錯体の合成 (2012)
  • Author(s): 原賀健史、鈴木教之、増山芳郎
  • Organizer: 第62回錯体化学討論会
  • Place of Presentation: 富山大学(富山)
• [Presentation] ジルコニウムと窒素原子を含む五員環アレン化合物の合成 (2012)
  • Author(s): 湯淺 伸、萩森圭太、井上翔太、浅田拓海、竹元貴彦、鈴木教之、増山芳郎
  • Organizer: 第59回有機金属化学討論会
  • Place of Presentation: 大阪大学(吹田)
• [Presentation] Transition metal complexes of cumulene derivatives (2011)
  • Author(s): Noriyuki Suzuki
  • Organizer: 14th Asian Chemical Congress
  • Place of Presentation: Bangkok, Thailand(招待講演)
  • Year and Date: 2011-09-07
• [Presentation] 4C8-19 塩化スズ(II)を触媒とする1-置換プロパルギルアルコールと炭素求核剤の反応 (2011)
  • Author(s): 林美樹・鈴木教之・増山芳郎
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 神奈川大学(横浜)
  • Year and Date: 2011-03-29
• [Presentation] 3C9-33パラジウム(II)交換ヒドロキシアパタイト触媒を用いるアルキンのブロモアルキニル化反応 (2011)
  • Author(s): 森田麻依子・鈴木教之・増山芳郎
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 神奈川大学(横浜)
  • Year and Date: 2011-03-28
• [Presentation] 3A5-19 ルテニウム錯体に配位したエチルビス(2-ピリジルエチル)アミンのエチレンアームにおけるC-H活性化反応 (2011)
  • Author(s): 福井宗平・鈴木教之・長尾宏隆
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 神奈川大学(横浜)
  • Year and Date: 2011-03-28
• [Presentation] 5員環アルキン錯体におけるcis/trans異性化反応の機構 (2011)
  • Author(s): 西村公佑, 大原 望, 鈴木教之, 増山芳郎
  • Organizer: 日本化学会第91回春季年会1PB-204
  • Place of Presentation: 日神奈川大学(横浜)(震災のため中止)
  • Year and Date: 2011-03-26
• [Presentation] 1PB-204五員環アルキン錯体におけるcis/trans異性化反応の機構 (2011)
  • Author(s): 西村公佑・大原望・鈴木教之・増山芳郎
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 神奈川大学(横浜)
  • Year and Date: 2011-03-26
• [Presentation] Transition metal complexes of cumulene derivatives (2011)
  • Author(s): Noriyuki Suzuki
  • Organizer: 14th Asian Chemical Congress
  • Place of Presentation: Bangkok, Thailand
  • Invited
• [Presentation] Zirconium complex of (Z)-substituted [5]culumene (2010)
  • Author(s): Nozomu Ohara, Kosuke Nishimura, Yoshiro Masuyama, Noriyuki Suzuki
  • Organizer: Pacifichem 2010環太平洋国際化学会議
  • Place of Presentation: ホノルル、アメリカ合衆国
  • Year and Date: 2010-12-17
• [Presentation] Synthesis and reactivity of seven-membered cycloalkyne complexes (2010)
  • Author(s): Takashi Tsuchiya, Yoshiro Masuyama, Noriyuki Suzuki
  • Organizer: Pacifichem 2010環太平洋国際化学会議
  • Place of Presentation: ホノルル、アメリカ合衆国
  • Year and Date: 2010-12-17
• [Presentation] Five-membered Metallacycloallene Compounds Derived from 1,3-Enynes (2010)
  • Author(s): Taichiro Shimura, Yoshiro Masuyama, Noriyuki Suzuki
  • Organizer: Pacifichem 2010環太平洋国際化学会議
  • Place of Presentation: ホノルル、アメリカ合衆国
  • Year and Date: 2010-12-17
• [Presentation] Five-Membered Metallacycloalkynes and Metallacycloallenes (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: Pacifichem 2010環太平洋国際化学会議
  • Place of Presentation: ホノルル、アメリカ合衆国(invited)
  • Year and Date: 2010-12-16
• [Presentation] Synthesis of Five-Membered Metallacycloallenes And Their Reactivity (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: The 11th Eurasia Conference for Chemical Science
  • Place of Presentation: Dead Sea, ョルダン(invited lecture)
  • Year and Date: 2010-10-07
• [Presentation] P3A-11 ヒドロキシアパタイト固定化銅触媒を用いるアルキン-アジド[3+2]環化付加反応 (2010)
  • Author(s): 吉川一貴・鈴木教之・増山芳郎
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(八王子)
  • Year and Date: 2010-09-18
• [Presentation] (E)-置換[5]クムレンの単離と Z-異性体のジルコニウム錯体形成 (2010)
  • Author(s): 大原 望, 西村公佑, 増山芳郎, 鈴木教之
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(八王子)(P1B-19)
  • Year and Date: 2010-09-16
• [Presentation] PIB-19 (E)-置換[5]クムレンの単離とZ-異性体のジルコニウム錯体形成 (2010)
  • Author(s): 大原望・西村公佑・増山芳郎・鈴木教之
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(八王子)
  • Year and Date: 2010-09-16
• [Presentation] P1C-01塩化スズ(II)が促進するイリジウム触媒による末端アルキンの環化三量化反応 (2010)
  • Author(s): 宮崎佳奈・鈴木教之・増山芳郎
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(八王子)
  • Year and Date: 2010-09-16
• [Presentation] P1-155 クロスカップリングを基軸としたエラスチン架橋分子の合成研究 (2010)
  • Author(s): 矢沼裕人・小関洋平・林貴広・山田はるか・鈴木教之・増山芳郎・臼杵豊展
  • Organizer: 日本化学会第4回関東支部大会
  • Place of Presentation: 筑波大学(つくば)
  • Year and Date: 2010-08-30
• [Presentation] Metallacyclic Compounds Derived from Group 4 Metals and [n]Cumulenes (n = 3, 5) (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: The 27th Congress of Chinese Chemical Society
  • Place of Presentation: Xiamen
  • Year and Date: 2010-06-20
  • Invited
• [Presentation] Metallacyclic Compounds Derived from Group 4 Metals and [n]Cumulenes (n=3,5) (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: The 27th Congress of Chemical Chemical Society
  • Place of Presentation: アモイ、中国(invited lecture)
  • Year and Date: 2010-06-20
• [Presentation] Five-Membered Metallacycloalkynes and Metallacycloallenes (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA
• [Presentation] Zirconium complex of (Z)-substituted [5]culumene (2010)
  • Author(s): Nozomu Ohara, Kosuke Nishimura, Yoshiro Masuyama, Noriyuki Suzuki
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA
• [Presentation] Five-membered Metallacycloallene Compounds Derived from 1,3-Enynes (2010)
  • Author(s): Taichiro Shimura, Yoshiro Masuyama, Noriyuki Suzuki
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA
• [Presentation] Synthesis of Five-Membered Metallacycloallenes And Their Reactivity (2010)
  • Author(s): Noriyuki Suzuki
  • Organizer: The 11th Eurasia Conference for Chemical Science
  • Place of Presentation: The Dead Sea, Jordan
  • Invited
• [Presentation] Formation of Ethylbis(2-pyridylethyl)amineruthenium Complexes Containing an Iminium-ion or a Nitroso Moiety" (2010)
  • Author(s): S.Fukui, N.Suzuki, T.Wada, K.Tanaka, H.Nagao
  • Organizer: 39^<th> International Conference on Coordination Chemistry
  • Place of Presentation: Adelaide, Australia
• [Remarks] ホームページ
  • URL: http://www.mls.sophia.ac.jp/~orgsynth/publications.html