| Budget Amount *help |
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
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| Research Abstract |
In this study we developed a novel synthetic method of C3 symmetric hexaphenylbenzene derivatives from hexaphenylbenzene in two steps. Applying this method, a C3 symmetric tris-monodentate ligand bearing three pyridyl groups was prepared, and was utilized for the construction of an octahedron-shaped self-assembled Zn(II)-capsule complex. The Zn(II)-capsule has anionic monodentate ligands inside the cavity, which were replaced with sulfonate ligands selectively, and thus the inner space of the resulting coordination capsule was easily modified with a variety of functional groups.
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