| Budget Amount *help |
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2012: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2011: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2010: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
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| Research Abstract |
In this project, we studied how the reactivity and selectivity of high-valent metal-oxo complexes are controlled to provide a new concept fordeveloping functional catalysts.We succeeded in revealing a new unique molecular mechanisms that the axial ligand controls the reactivity of oxoiron(IV) porphyrin π-cation radical complex by stability of the iron(III) porphyrin complex, not by instability of itself. In addition, we succeeded in solving the crystal structure of a chiral manganese(IV) salen iodosylarene adduct, which provide a new mechanism for controlling its enantioselectivity
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