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Measurement of spatial propagation and synchronization of potential oscillation driven by charge transfers between two phases and evaluation their mechanisms

Research Project

Project/Area Number 22350033
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionKyoto Institute of Technology

Principal Investigator

MAEDA Kohji  京都工芸繊維大学, 工芸科学研究科, 教授 (00229303)

Co-Investigator(Kenkyū-buntansha) YOSHIDA Yumi  京都工芸繊維大学, 工芸科学研究科, 准教授 (40314306)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Keywords膜電位振動 / 人工液膜系 / 振動の同期 / 電気信号の伝播 / 自律性 / 電位振動 / 伝播 / 同期 / 引き込み / 自律性と他律性 / 液膜 / イオン移動 / 電荷移動の共役
Research Abstract

Two liquid membrane oscillators composed of an aqueous solution containing cetyltrimethylammonium chloride (CTACl) and alcohol, W1 and W1', a nitrobenzene solution containing picric acid, O, and pure water phase, W2, were connected through O and W2 as common phases. The oscillations of two membrane potentials synchronized each other depending on the distance between the oscillators. The synchronization was attended by the propagation of potential pulse from one side to another with a velocity of 15 cm/s. It has been demonstrated that the propagation of oscillation pulse was dominated mainly by the interfacial conduction process and that the interfacial diffusion and distribution of Cl- played a crucial role.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (35 results)

All 2013 2012 2011 2010 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (24 results) (of which Invited: 1 results) Book (1 results) Remarks (4 results)

  • [Journal Article] Propagation and synchronization of potential oscillations in multiple liquid membrane systems2012

    • Author(s)
      Y. Tatsuno, T. Kozuru, Y. Yoshida and K. Maeda
    • Journal Title

      Analytical Sciences

      Volume: 28(12) Pages: 1145-1151

    • NAID

      10031136983

    • URL

      http://www.jsac.or.jp/analsci/toc.php/28/12/

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 銀電極における析出・溶出の2段階電解を利用する塩化物イオンのクーロメトリー定量2012

    • Author(s)
      福武弘明、奥村尚己、辰野吉英、吉田裕美、前田耕治
    • Journal Title

      分析化学

      Volume: 61巻 Pages: 1055-1061

    • NAID

      10031131690

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biomimetic charge transfer reactions at the aqueous/organic solution interface or through artificial membrane2012

    • Author(s)
      S. Kihara, M. Kasuno, T. Okugaki, O. Shirai, K. Maeda, Electrochemistry
    • Journal Title

      Electrochemistry

      Volume: 80(6) Pages: 390-400

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biomimetic Charge Transfer Reactions at the Aqueous/Organic Solution Interface or through Artificial Membrane2012

    • Author(s)
      Sorin Kihara, Mugumi Kasuno, Tomoyuki Okugaki, Osamu Shirai, Kohji Maeda
    • Journal Title

      Electrochemistry

      Volume: 80(6)(掲載確定)(6月掲載予定のため未定)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Standard Gibbs energies for transfer of actinyl ions at the aqueous/organic solution interface2011

    • Author(s)
      Y.Kitatsuji, T.Okugaki, M.Kasuno, H.Kubota, K.Maeda, T.Kimura, Z.Yoshida, S.Kihara
    • Journal Title

      J.Chem.Thermodynamics

      Volume: 43 Pages: 844-851

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 膜電位振動はどのように伝播するのか-細胞間の伝播と同期のモデル-2010

    • Author(s)
      辰野吉英、奥垣智彦、吉田裕美、前田耕治
    • Journal Title

      Review of Polarography

      Volume: 56 Pages: 155-155

    • NAID

      10027646326

    • Related Report
      2010 Annual Research Report
  • [Presentation] 液液界面を伝播する電位パルスの経路と速度2013

    • Author(s)
      小鶴拓海、山口祐哉、吉田裕美、前田耕治
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス
    • Year and Date
      2013-05-18
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 複数の液膜電位振動間の伝播と同期2013

    • Author(s)
      辰野吉英・小鶴拓海・吉田裕美・前田耕治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ草津キャンパス
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 電気化学振動子がシンクロするとき2013

    • Author(s)
      前田耕治
    • Organizer
      第59回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      沖縄県石垣市民会館
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 複数の連結液膜系を用いた電位振動の界面伝播の機構2012

    • Author(s)
      小鶴拓海、山口祐哉、辰野吉英、吉田裕美、前田耕治
    • Organizer
      第58回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      高尾の森わくわくビレッジ 東京都八王子
    • Year and Date
      2012-11-26
    • Related Report
      2012 Final Research Report
  • [Presentation] 3つの連結液膜系での電位振動の相互伝播-同期の抑制と促進-2012

    • Author(s)
      小鶴拓海、辰野吉英、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス
    • Year and Date
      2012-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] 同期中の液膜電位振動の自律性の解析2012

    • Author(s)
      小鶴拓海、辰野吉英、吉田裕美、前田耕治
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス・工学部
    • Year and Date
      2012-05-19
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] 3つの連結液膜系での電位振動の相互伝播-同期の抑制と促進-2012

    • Author(s)
      小鶴拓海、辰野吉英、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 複数の連結液膜系を用いた電位振動の界面伝播の機構2012

    • Author(s)
      小鶴拓海、山口祐哉、辰野吉英、吉田裕美、前田耕治
    • Organizer
      第58回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      高尾の森わくわくビレッジ 東京都八王子
    • Related Report
      2012 Annual Research Report
  • [Presentation] イオン移動ボルタンメトリーを用いる植物クチクラ膜のイオン透過性の評価2012

    • Author(s)
      杉本満、吉田裕美、前田耕治
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松・浜松市
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液膜電位振動の伝播機構-バルク伝導と界面伝導の競合-2011

    • Author(s)
      辰野吉英、杉本満、小鶴拓海、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学・名古屋市
    • Year and Date
      2011-09-14
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Mechanism of Propagation and Synchronization Of Potential Oscillations in Liquid Membrane Systems2011

    • Author(s)
      Kohji Maeda, Yoshihide Tatsuno, Yumi Yoshida
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center, Japan
    • Year and Date
      2011-03-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Mechanism of Propagation and Synchronization of Potential Oscillations in Liquid Membrane Systems2011

    • Author(s)
      Kohji Maeda, Yoshihide Tatsuno, Yumi Yoshida
    • Organizer
      IUPAC International Congress on Analytical Scien ces 2011
    • Place of Presentation
      Kyoto International Conference Center, Japan
    • Related Report
      2011 Annual Research Report
  • [Presentation] The Evaluation of Conductivity of Hydrophilic Polymer Film using Ion Transfer Voltammetry2011

    • Author(s)
      Kohji Maeda, Naoki Okumura, Mitsuru Sugimoto, Yumi Yoshida
    • Organizer
      Shikata Discussion 2011
    • Place of Presentation
      Awaji Ume-butai, Japan(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Ion Transfer Voltammetry using Thin Film of Water-absorbing Polymer2011

    • Author(s)
      Mitsuru Sugimoto, Naoki Okumura, Yumi Yoshida, Kohji Maeda
    • Organizer
      Shikata Discussion 2011
    • Place of Presentation
      Awaji Ume-butai, Japan
    • Related Report
      2011 Annual Research Report
  • [Presentation] リン脂質層の形成に及ぼすランタニドイオンの影響-平面単分子層とリポソームの比較-2011

    • Author(s)
      井関鈴鹿、熊田陽一、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学・名古屋市
    • Related Report
      2011 Annual Research Report
  • [Presentation] 混合溶媒中での電析・溶出反応を利用反応を利用した塩化物イオン定量2011

    • Author(s)
      福武弘明、辰野吉英、奥村尚己、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学・名古屋市
    • Related Report
      2011 Annual Research Report
  • [Presentation] クチクラ膜を介したイオン移動のボルタンメトリー2011

    • Author(s)
      杉本満、奥村尚己、吉田裕美、前田耕治、大河内武夫
    • Organizer
      第57回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」・那覇市
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液液界面リン脂質層とリポソームの比較-相転移に与える金属イオンの影響2011

    • Author(s)
      井関鈴鹿、熊田陽一、吉田裕美、前田耕治
    • Organizer
      第57回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」・那覇市
    • Related Report
      2011 Annual Research Report
  • [Presentation] 単・チューブ3電極式フローセルを利用した塩化物イオンのクーロメトリー定量2011

    • Author(s)
      福武弘明、吉田裕美、前田耕治
    • Organizer
      第57回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」・那覇市
    • Related Report
      2011 Annual Research Report
  • [Presentation] Mechanism of Propagation and Synchronization of Potential Oscillations in Liquid Membrane Systems2011

    • Author(s)
      Yoshihide Tatsuno, Yumi Yoshida, Kohji Maeda
    • Organizer
      International Congress on Analytical Sciences 2011
    • Place of Presentation
      京都国際会議場
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synchronization of multiple potential oscillations in liquid membrane systems2011

    • Author(s)
      Yoshihide Tatsuno, Yumi Yoshida, Kohji Maeda
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synchronization of multiple potential oscillations in liquid membrane systems2010

    • Author(s)
      Y. Tatsuno, Y. Yoshida, K. Maeda
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-15
    • Related Report
      2012 Final Research Report
  • [Presentation] 膜電位振動はどのように伝播するのか-細胞間の伝播と同期のモデル-2010

    • Author(s)
      辰野吉英、奥垣智彦、吉田裕美、前田耕治
    • Organizer
      第56回ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      秋田大学工学資源学部・秋田市
    • Year and Date
      2010-11-06
    • Related Report
      2012 Final Research Report
  • [Presentation] 複数の液膜系における電位振動の伝播と同期の機構2010

    • Author(s)
      辰野吉英、吉田裕美、前田耕治
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学・仙台市
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Book] 分析化学の基礎2012

    • Author(s)
      岡田哲男、垣内隆、前田耕治
    • Publisher
      化学同人
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Remarks]

    • URL

      http://www.cis.kit.ac.jp/~anallab/AnalChemHP/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 物質分析学研究室ホームページ

    • URL

      http://www.cis.kit.ac.jp/~anallab/AnalChemHP/index.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.cis.kit.ac.jp/~anallab/AnalChemHP/index.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.cis.kit.ac.jp/~anallab/AnalChemHP/index.html

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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