Cataltytic CH coupling reactions of heteroaromatic compound and disign of advanced materials with extended ・-conjugation
| Project/Area Number |
22350042
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Kobe University |
|---|
Principal Investigator |
MORI Atsunori 神戸大学, 大学院・工学研究科, 教授 (90210111)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
|
|---|
| Keywords | 選択的合成 / 反応 / オリゴチオフェン / マグネシウムアミド / ニッケル触媒 / デンドリマー / カップリング反応 / ヘテロ芳香族化合物 / Grignard反応剤 / 多官能性 / チオフェン / チアゾール / ドナー・アクセプター / CHカップリング / 位置選択的 / グラジエント型オリゴチオフェン / リチウムtブトキシド / 塩化アリール / パラジウム触媒 |
|---|
| Research Abstract |
Catalytic CH coupling reactons forming thiophene-thiophene and thiophene-thiazole bond formation are carried out. Heteroaromatic oligomers of extended pai-conjugation are synthesized with the optimized reaction conditions. Diversity-oriented gradient and donor-acceptor-type oligomeric heteroaromatic compounds are developed directed toward solar cells, semi-conducting organic thin films.
|
Report
(4 results)
Research Products
(26 results)
